Abstract
Samples from well-known rhyolitic systems in the western USA were analyzed to determine trace-element partition coefficients between sanidine and coexisting melt. Both DSr and DEu correlate positively with An concentration in sanidine. Barium, not surprisingly, shows more correlation with Or in sanidine. All three show negative correlations with whole-rock Al2O3. Partition coefficients for REE show a decreasing trend with strong positive DEu. DLREE correlate negatively with the whole-rock Al2O3. In peraluminous rocks, Al2O3 in magma seems to exert a major influence on partition coefficients of trace elements. With increasing Al2O3 concentration, the melt composition becomes increasingly similar to that of feldspar. Incompatible trace elements (Rb, Y, Nb, and Zr) in sanidine show positive trends whereas compatible trace elements (Sr, Eu, and Ba) show negative correlations when plotted against whole-rock Al2O3. LREEs, which are expected to substitute for Ca in the sanidine structure, behave like Sr and Eu. Because trace-element partitioning is influenced by both crystal and magma compositions, multiple regression analysis has been used to predict trace-element partition coefficients. The equations will assist workers in the selection of partition coefficients used in petrogenetic models of silicic systems.
© 2015 by Walter de Gruyter Berlin/Boston
Artikel in diesem Heft
- Introductory overview: Hydrate knowledge development
- Scanning Electron Microscopy investigations of laboratory-grown gas clathrate hydrates formed from melting ice, and comparison to natural hydrates
- Dynamics of trimethylene oxide in a structure II clathrate hydrate
- The stability of methane hydrates in highly concentrated electrolyte solutions by differential scanning calorimetry and theoretical computation
- The effect of elevated methane pressure on methane hydrate dissociation
- Methane hydrate formation in partially water-saturated Ottawa sand
- Methanol—inhibitor or promoter of the formation of gas hydrates from deuterated ice?
- Investigating the performance of clathrate hydrate inhibitors using in situ Raman spectroscopy and differential scanning calorimetry
- Physical properties and rock physics models of sediment containing natural and laboratory-formed methane gas hydrate
- Experimental studies on the formation of porous gas hydrates
- Investigation of jet breakup and droplet size distribution of liquid CO2and water systems—implications for CO2hydrate formation for ocean carbon sequestration
- Measurement of clathrate hydrate precipitation from CO2solution by a nondestructive method
- Influence of water thermal history and overpressure on CO2-hydrate nucleation and morphology
- Growth-controlling processes of CO2gas hydrates
- Thermodynamic prediction of clathrate hydrate dissociation conditions in mesoporous media
- Modeling dynamic marine gas hydrate systems
- Late-stage, high-temperature processesing in the Allende meteorite: Record from Ca,Fe-rich silicate rims around dark inclusions
- Partitioning of Sr, Ba, Rb, Y, and LREE between alkali feldspar and peraluminous silicic magma
- Nondestructive three-dimensional element-concentration mapping of a Cs-doped partially molten granite by X-ray computed tomography using synchrotron radiation
- A theoretical study of structural factors correlated with 23Na NMR parameters
- Metamorphic formation of Sr-apatite and Sr-bearing monazite in a high-pressure rock from the Bohemian Massif
- Ultra-deep origin of garnet peridotite from the North Qaidam ultrahigh-pressure belt, Northern Tibetan Plateau, NW China
- Letter. Novel high-pressure behavior in chlorite: A synchrotron XRD study of clinochlore to 27 GPa
- Letter. Periodic precipitation pattern formation in hydrothermally treated metamict zircon
- A high pressure X-ray diffraction study of aragonite and the post-aragonite phase transition in CaCO3
Artikel in diesem Heft
- Introductory overview: Hydrate knowledge development
- Scanning Electron Microscopy investigations of laboratory-grown gas clathrate hydrates formed from melting ice, and comparison to natural hydrates
- Dynamics of trimethylene oxide in a structure II clathrate hydrate
- The stability of methane hydrates in highly concentrated electrolyte solutions by differential scanning calorimetry and theoretical computation
- The effect of elevated methane pressure on methane hydrate dissociation
- Methane hydrate formation in partially water-saturated Ottawa sand
- Methanol—inhibitor or promoter of the formation of gas hydrates from deuterated ice?
- Investigating the performance of clathrate hydrate inhibitors using in situ Raman spectroscopy and differential scanning calorimetry
- Physical properties and rock physics models of sediment containing natural and laboratory-formed methane gas hydrate
- Experimental studies on the formation of porous gas hydrates
- Investigation of jet breakup and droplet size distribution of liquid CO2and water systems—implications for CO2hydrate formation for ocean carbon sequestration
- Measurement of clathrate hydrate precipitation from CO2solution by a nondestructive method
- Influence of water thermal history and overpressure on CO2-hydrate nucleation and morphology
- Growth-controlling processes of CO2gas hydrates
- Thermodynamic prediction of clathrate hydrate dissociation conditions in mesoporous media
- Modeling dynamic marine gas hydrate systems
- Late-stage, high-temperature processesing in the Allende meteorite: Record from Ca,Fe-rich silicate rims around dark inclusions
- Partitioning of Sr, Ba, Rb, Y, and LREE between alkali feldspar and peraluminous silicic magma
- Nondestructive three-dimensional element-concentration mapping of a Cs-doped partially molten granite by X-ray computed tomography using synchrotron radiation
- A theoretical study of structural factors correlated with 23Na NMR parameters
- Metamorphic formation of Sr-apatite and Sr-bearing monazite in a high-pressure rock from the Bohemian Massif
- Ultra-deep origin of garnet peridotite from the North Qaidam ultrahigh-pressure belt, Northern Tibetan Plateau, NW China
- Letter. Novel high-pressure behavior in chlorite: A synchrotron XRD study of clinochlore to 27 GPa
- Letter. Periodic precipitation pattern formation in hydrothermally treated metamict zircon
- A high pressure X-ray diffraction study of aragonite and the post-aragonite phase transition in CaCO3