Startseite A zinc(II) coordination polymer based on a flexible bis(benzimidazole) ligand: synthesis, crystal structure and fluorescence study
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A zinc(II) coordination polymer based on a flexible bis(benzimidazole) ligand: synthesis, crystal structure and fluorescence study

  • Geng Zhang , Xinzhao Xia , Jianhua Xu , Lixian Xia , Cong Wang und Huilu Wu EMAIL logo
Veröffentlicht/Copyright: 3. November 2020
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 75 Heft 12

Abstract

A new one-dimensional Zn(II) coordination polymer, {[ZnCl2(BBM)]·CH3OH}n (2,2-(1,4-butanediyl)bis-1,3-benzimidazole [BBM]), has been obtained from the hydrothermal reaction of zinc chloride with the flexible bis-benzimidazole ligand BBM and characterized by single-crystal X-ray diffraction, elemental analysis, IR and UV–vis spectra. Structural analysis has revealed that the BBM ligand connects the Zn(II) atoms to form a square-wave chain, which is further extended into supramolecular layers through hydrogen bonds and π···π stacking interactions. Solid-state fluorescence investigations showed that the Zn(II) coordination polymer has an emission peak at 381 nm upon excitation at 330 nm, which is attributed to ligand-centered luminescence. It is only slightly red shifted as compared to the ligand but partially quenched due to the strong π···π stacking interactions.

Keywords: bis(benzimidazole) ligand; crystal structure; fluorescence property; zinc(II) coordination polymer
Corresponding author: Huilu Wu, School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu, 730070, P. R. China, E-mail:

Funding source: Foundation of A Hundred Youth Talents Training Program of Lanzhou Jiaotong University

Award Identifier / Grant number: 152022

Funding source: Natural Science Foundation of Gansu Province

Award Identifier / Grant number: 17JR5RA090

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The present research was supported by the Foundation of A Hundred Youth Talents Training Program of Lanzhou Jiaotong University (Grant No. 152022) and Natural Science Foundation of Gansu Province (Grant No. 17JR5RA090).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-06-05
Accepted: 2020-09-10
Published Online: 2020-11-03
Published in Print: 2020-12-16

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. A zinc(II) coordination polymer based on a flexible bis(benzimidazole) ligand: synthesis, crystal structure and fluorescence study
  5. A study of antituberculosis activities and crystal structures of (E)-2-[2-(arylidene)hydrazinyl]pyrimidine and (E)-N1-(arylidene)pyrimidine-2-carbohydrazide derivatives
  6. Pt3Ni/C and Pt3Co/C cathodes as electrocatalysts for use in oxygen sensors and proton exchange membrane fuel cells
  7. Selective cyclization modes of methyl 3′-heteroarylamino-2′-(2,5-dichlorothiophene-3-carbonyl)acrylates. Synthesis of model (thienyl)pyrazolo- and triazolo[1,5-α]pyrimidines
  8. Synthesis and crystal structures of two new lead(II) complexes with the pincer-type ligand 4′-(4-chlorophenyl)-2,2′:6′,2″-terpyridine (Cl-Ph-tpy): subtle interplay of weak intermolecular interactions
  9. Die unerwartete Kristallstruktur des Cäsium-Dodekahydro-Monocarba-closo-Dodekaborats Cs[CB11H12]
  10. Synthesis, crystal structure and photoluminescence of a binuclear rhenium(I) carbonyl complex incorporated in a framework of a distorted salophen ligand
  11. 1-Trifluoromethyl-prop-2-yne 1-iminium salts and 1-imines: reactions with the mesoionic „Nitron“
  12. Note
  13. YIrIn with ZrNiAl-type structure
https://doi.org/10.1515/znb-2020-0094
Schlagwörter für diesen Artikel
bis(benzimidazole) ligand; crystal structure; fluorescence property; zinc(II) coordination polymer

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. A zinc(II) coordination polymer based on a flexible bis(benzimidazole) ligand: synthesis, crystal structure and fluorescence study
  5. A study of antituberculosis activities and crystal structures of (E)-2-[2-(arylidene)hydrazinyl]pyrimidine and (E)-N1-(arylidene)pyrimidine-2-carbohydrazide derivatives
  6. Pt3Ni/C and Pt3Co/C cathodes as electrocatalysts for use in oxygen sensors and proton exchange membrane fuel cells
  7. Selective cyclization modes of methyl 3′-heteroarylamino-2′-(2,5-dichlorothiophene-3-carbonyl)acrylates. Synthesis of model (thienyl)pyrazolo- and triazolo[1,5-α]pyrimidines
  8. Synthesis and crystal structures of two new lead(II) complexes with the pincer-type ligand 4′-(4-chlorophenyl)-2,2′:6′,2″-terpyridine (Cl-Ph-tpy): subtle interplay of weak intermolecular interactions
  9. Die unerwartete Kristallstruktur des Cäsium-Dodekahydro-Monocarba-closo-Dodekaborats Cs[CB11H12]
  10. Synthesis, crystal structure and photoluminescence of a binuclear rhenium(I) carbonyl complex incorporated in a framework of a distorted salophen ligand
  11. 1-Trifluoromethyl-prop-2-yne 1-iminium salts and 1-imines: reactions with the mesoionic „Nitron“
  12. Note
  13. YIrIn with ZrNiAl-type structure
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