Synthesis, crystal structure and photoluminescence of a binuclear rhenium(I) carbonyl complex incorporated in a framework of a distorted salophen ligand
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Arnd Vogler
Abstract
Re(CO)5Cl reacts with salophenH2 to yield Re(I)2(salophenH)(CO)6Cl. A crystal structure determination has shown that this binuclear complex contains two Re(CO)3 fragments which are bridged by a chloride and a heavily constrained salophenH– anion as ligands. Under ambient conditions in solution and in the solid state, the complex displays an orange emission which originates from the lowest-energy IL/MLCT triplet. In solution, this phosphorescence is completely quenched by oxygen.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Evans, R. C., Douglas, P., Winscom, C. J. Coord. Chem. Rev. 2006, 250, 2093–2126; https://doi.org/10.1016/j.ccr.2006.02.007.Search in Google Scholar
2. Kalyanasundaram, K. Photochemistry of Polypyridine and Porphyrin Complexes; Academic Press: London, 1992; p. 321.Search in Google Scholar
3. Vogler, A., Kunkely, H. Coord. Chem. Rev. 2000, 200–202, 991–1008; https://doi.org/10.1016/s0010-8545(99)00241-6.Search in Google Scholar
4. CrysAlis Pro Software System. Intelligent Data Collection and Processing Software for Small Molecule and Protein Crystallography; Rigaku Oxford Diffraction: Yarnton, Oxfordshire (U. K.), 2015.Search in Google Scholar
5 . Sheldrick, G. M. Acta Crystallogr. 2015, A71, 3–8 https://doi.org/10.1107/s2053273314026370.Search in Google Scholar
6. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. J. Appl. Crystallogr. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Search in Google Scholar
7. Sheldrick, G. M. Acta Crystallogr. 2015, C71, 3–8.Search in Google Scholar
8. Czerwieniec, R., Kapturkiewicz, A., Anulewicz-Ostrowska, R., Nowacki, J. J. Chem. Soc., Dalton Trans. 2001, 2756–2761; https://doi.org/10.1039/b101357m.Search in Google Scholar
9. Stor, G. J., Hartl, F., van Outersterp, J. W. M., Stufkens, D. J. Organometallics 1995, 14, 1115–1131; https://doi.org/10.1021/om00003a013.Search in Google Scholar
10. Di Bella, S., Fragalà, I., Ledoux, I., Diaz-Garcia, M. A., Marks, T. J. J. Am. Chem. Soc. 1997, 119, 9550–9557; https://doi.org/10.1021/ja971349y.Search in Google Scholar
11. Kunkely, H., Vogler, A. Z. Naturforsch. 2002, 57b, 301–304; https://doi.org/10.1515/znb-2002-0307.Search in Google Scholar
12. Khan, T., Vaidya, S., Mhatre, D. S., Datta, A. J. Phys. Chem. B 2016, 120, 10319–10326; https://doi.org/10.1021/acs.jpcb.6b05854.Search in Google Scholar
13. Shen, Y.-Z., Pan, Y., Wang, L.-Y., Dong, G., Jin, X.-P., Huang, X.-Y., Hu, H. J. Organomet. Chem. 1999, 590, 242–247; https://doi.org/10.1016/s0022-328x(99)00466-0.Search in Google Scholar
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Articles in the same Issue
- Frontmatter
- In this issue
- Research Articles
- A zinc(II) coordination polymer based on a flexible bis(benzimidazole) ligand: synthesis, crystal structure and fluorescence study
- A study of antituberculosis activities and crystal structures of (E)-2-[2-(arylidene)hydrazinyl]pyrimidine and (E)-N1-(arylidene)pyrimidine-2-carbohydrazide derivatives
- Pt3Ni/C and Pt3Co/C cathodes as electrocatalysts for use in oxygen sensors and proton exchange membrane fuel cells
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- Die unerwartete Kristallstruktur des Cäsium-Dodekahydro-Monocarba-closo-Dodekaborats Cs[CB11H12]
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