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YIrIn with ZrNiAl-type structure

  • Nataliya L. Gulay , Yaroslav M. Kalychak and Rainer Pöttgen EMAIL logo
Published/Copyright: November 23, 2020
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 75 Issue 12

Abstract

The indide YIrIn was synthesized from the elements in a sealed tantalum ampoule in a high-frequency furnace. YIrIn adopts the ZrNiAl type. The crystal structure was refined from single-crystal X-ray diffractometer data: P6–2m, a = 750.63(6), c = 392.04(3) pm, wR = 0.0346, 308 F2 values and 16 variables. Refinement of the occupancy parameters revealed a small degree of Ir/In mixing (0.912(9) Ir2/0.088(9) In1) on the 2d site. The YIrIn structure contains two crystallographically independent iridium sites, both with tri-capped trigonal prismatic coordination: Ir1@In6Y3 and Ir2@In3Y6.

Keywords: crystal structure; indide; intermetallics; iridium; yttrium
Corresponding author: Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail:

Acknowledgements

We thank Dr. R.-D. Hoffmann for the intensity data collection.

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-11-09
Accepted: 2020-11-11
Published Online: 2020-11-23
Published in Print: 2020-12-16

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/znb-2020-0181
Keywords for this article
crystal structure; indide; intermetallics; iridium; yttrium

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. A zinc(II) coordination polymer based on a flexible bis(benzimidazole) ligand: synthesis, crystal structure and fluorescence study
  5. A study of antituberculosis activities and crystal structures of (E)-2-[2-(arylidene)hydrazinyl]pyrimidine and (E)-N1-(arylidene)pyrimidine-2-carbohydrazide derivatives
  6. Pt3Ni/C and Pt3Co/C cathodes as electrocatalysts for use in oxygen sensors and proton exchange membrane fuel cells
  7. Selective cyclization modes of methyl 3′-heteroarylamino-2′-(2,5-dichlorothiophene-3-carbonyl)acrylates. Synthesis of model (thienyl)pyrazolo- and triazolo[1,5-α]pyrimidines
  8. Synthesis and crystal structures of two new lead(II) complexes with the pincer-type ligand 4′-(4-chlorophenyl)-2,2′:6′,2″-terpyridine (Cl-Ph-tpy): subtle interplay of weak intermolecular interactions
  9. Die unerwartete Kristallstruktur des Cäsium-Dodekahydro-Monocarba-closo-Dodekaborats Cs[CB11H12]
  10. Synthesis, crystal structure and photoluminescence of a binuclear rhenium(I) carbonyl complex incorporated in a framework of a distorted salophen ligand
  11. 1-Trifluoromethyl-prop-2-yne 1-iminium salts and 1-imines: reactions with the mesoionic „Nitron“
  12. Note
  13. YIrIn with ZrNiAl-type structure
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