Synthesis and crystal structures of two new lead(II) complexes with the pincer-type ligand 4′-(4-chlorophenyl)-2,2′:6′,2″-terpyridine (Cl-Ph-tpy): subtle interplay of weak intermolecular interactions
-
Farzin Marandi
and
Harald Krautscheid
Abstract
A dinuclear and a tetranuclear complex of lead(II) with the pincer-type ligand 4′-(4-chlorophenyl)-2,2′:6′,2″-terpyridine (Cl-Ph-tpy), [Pb2(Cl-Ph-tpy)2(μ-I)2I2] (1) and [Pb4(Cl-Ph-tpy)4(μ-Br)4(μ-OH2)Br4]·2CH3OH (2), have been synthesized and characterized by elemental analysis, FT-IR and 1H NMR spectroscopy, and by single-crystal X-ray diffraction. In the binuclear structure of 1, the Pb atom has a hemidirected PbN3I3 environment with a Pb(μ-I)2Pb central unit. In the tetranuclear structure of 2, two crystallographically independent Pb(II) centres having hemidirected PbN3Br3 and PbN3OBr2 environments are connected to Pb(μ-Br)Pb(μ-Br)2(μ-OH2)Pb(μ-Br)Pb chains. The supramolecular features in 1 and 2 are supported through weak but directional C–H···Cl, C–H···I and C–H···Br, C–H···O, O–H···Br, and O···Br interactions and aromatic π-π stacking.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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Articles in the same Issue
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- In this issue
- Research Articles
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