Orthorhombic sulfur from Cap Garonne, Mine du Pradet
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Jutta Kösters
Abstract
Natural orthorhombic sulfur (α-S8), grown on galena crystals from Cap Garonne, Mine du Pradet, France, were studied by single crystal X-ray diffraction at 150 K: Fddd, a=1036.75(5), b=1273.54(7), c=2437.85(13) pm, wR=0.0380, 1433 F2 values (all data) and 37 variables. Refinements of the occupancy parameters along with EDX data indicate pure sulfur.
Dedicated to: Professor Wolfgang Bensch on the occasion of his 65th birthday.
Acknowledgments
We thank M.Sc. Fabian Eustermann for the EDX analyses and Jérôme Gibert, Agent du Patrimoine du Musée de la Mine de Cap Garonne for support.
References
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©2019 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Preface
- Congratulations to Professor Wolfgang Bensch on the occasion of his 65th birthday
- Orthorhombic sulfur from Cap Garonne, Mine du Pradet
- An unprecedented structural phase transition in struvite-type compounds: dimorphism of KMgAsO4(H2O)6
- ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGa
- Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
- Crystal structure of the high-temperature form of the trisulfide Cs2S3 and the (3+1)D modulated structure of the telluride K37Te28
- Synthesis, crystal structure and properties of Cd(NCS)2 coordination compounds with two different Cd coordination modes
- Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
- The role of synthesis conditions for structural defects and lattice strain in β-TaON and their effect on photo- and photoelectrocatalysis
- Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
- Electronic and magnetic properties of the 2H-NbS2 intercalated by 3d transition metal atoms
- CsTb3STe4 und CsTb5S2Te6: Zwei pseudo-ternäre Caesium-Terbium-Chalkogenide mit geordneten S2−- und Te2−-Anionen
- Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
- Crystal structures and FT-IR spectra of three N,N-dicyclohexylmethylammonium halides C13H26N+X− (X = Cl, Br, I)
- Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides RE14T3Al3 (RE = Y, Gd–Tm, Lu; T = Co, Ni)
- Modulated vacancy ordering in SrGe6−x (x≈0.45)
- Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Preface
- Congratulations to Professor Wolfgang Bensch on the occasion of his 65th birthday
- Orthorhombic sulfur from Cap Garonne, Mine du Pradet
- An unprecedented structural phase transition in struvite-type compounds: dimorphism of KMgAsO4(H2O)6
- ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGa
- Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
- Crystal structure of the high-temperature form of the trisulfide Cs2S3 and the (3+1)D modulated structure of the telluride K37Te28
- Synthesis, crystal structure and properties of Cd(NCS)2 coordination compounds with two different Cd coordination modes
- Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
- The role of synthesis conditions for structural defects and lattice strain in β-TaON and their effect on photo- and photoelectrocatalysis
- Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
- Electronic and magnetic properties of the 2H-NbS2 intercalated by 3d transition metal atoms
- CsTb3STe4 und CsTb5S2Te6: Zwei pseudo-ternäre Caesium-Terbium-Chalkogenide mit geordneten S2−- und Te2−-Anionen
- Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
- Crystal structures and FT-IR spectra of three N,N-dicyclohexylmethylammonium halides C13H26N+X− (X = Cl, Br, I)
- Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides RE14T3Al3 (RE = Y, Gd–Tm, Lu; T = Co, Ni)
- Modulated vacancy ordering in SrGe6−x (x≈0.45)
- Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis
