Home Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
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Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)

  • Karlheinz Sünkel EMAIL logo , Dietmar Reimann and Patrick Nimax
Published/Copyright: November 24, 2018
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 74 Issue 1

Abstract

The reaction of the 3d transition metal dichlorides MCl2 (M=Mn, Fe, Co, Ni, Cu, Zn) with the silver salts of substituted tetracyanocyclopentadienides Ag+ [C5(CN)4X]− (X=CN, H, NH2 NO2) gives the complexes [M(MeOH/H2O)4{C5(CN)4)X}2]. Nine of these complexes were characterized by X-ray diffraction and it shows that they all are mononuclear with an octahedral M(N)2(O)4 coordination sphere. In the structures, extensive hydrogen bonding leads to dense three-dimensional network structures.

Keywords: 3d metals; crystal structures; cyanocyclopentadienides

Dedicated to: Professor Wolfgang Bensch on the occasion of his 65th birthday.

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Received: 2018-08-18
Accepted: 2018-10-31
Published Online: 2018-11-24
Published in Print: 2019-01-26

©2019 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Preface
  4. Congratulations to Professor Wolfgang Bensch on the occasion of his 65th birthday
  5. Orthorhombic sulfur from Cap Garonne, Mine du Pradet
  6. An unprecedented structural phase transition in struvite-type compounds: dimorphism of KMgAsO4(H2O)6
  7. ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGa
  8. Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
  9. Crystal structure of the high-temperature form of the trisulfide Cs2S3 and the (3+1)D modulated structure of the telluride K37Te28
  10. Synthesis, crystal structure and properties of Cd(NCS)2 coordination compounds with two different Cd coordination modes
  11. Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
  12. The role of synthesis conditions for structural defects and lattice strain in β-TaON and their effect on photo- and photoelectrocatalysis
  13. Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
  14. Electronic and magnetic properties of the 2H-NbS2 intercalated by 3d transition metal atoms
  15. CsTb3STe4 und CsTb5S2Te6: Zwei pseudo-ternäre Caesium-Terbium-Chalkogenide mit geordneten S2−- und Te2−-Anionen
  16. Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
  17. Crystal structures and FT-IR spectra of three N,N-dicyclohexylmethylammonium halides C13H26N+X− (X = Cl, Br, I)
  18. Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides RE14T3Al3 (RE = Y, Gd–Tm, Lu; T = Co, Ni)
  19. Modulated vacancy ordering in SrGe6−x (x≈0.45)
  20. Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis
https://doi.org/10.1515/znb-2018-0175
Keywords for this article
3d metals; crystal structures; cyanocyclopentadienides

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Preface
  4. Congratulations to Professor Wolfgang Bensch on the occasion of his 65th birthday
  5. Orthorhombic sulfur from Cap Garonne, Mine du Pradet
  6. An unprecedented structural phase transition in struvite-type compounds: dimorphism of KMgAsO4(H2O)6
  7. ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGa
  8. Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
  9. Crystal structure of the high-temperature form of the trisulfide Cs2S3 and the (3+1)D modulated structure of the telluride K37Te28
  10. Synthesis, crystal structure and properties of Cd(NCS)2 coordination compounds with two different Cd coordination modes
  11. Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
  12. The role of synthesis conditions for structural defects and lattice strain in β-TaON and their effect on photo- and photoelectrocatalysis
  13. Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
  14. Electronic and magnetic properties of the 2H-NbS2 intercalated by 3d transition metal atoms
  15. CsTb3STe4 und CsTb5S2Te6: Zwei pseudo-ternäre Caesium-Terbium-Chalkogenide mit geordneten S2−- und Te2−-Anionen
  16. Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
  17. Crystal structures and FT-IR spectra of three N,N-dicyclohexylmethylammonium halides C13H26N+X− (X = Cl, Br, I)
  18. Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides RE14T3Al3 (RE = Y, Gd–Tm, Lu; T = Co, Ni)
  19. Modulated vacancy ordering in SrGe6−x (x≈0.45)
  20. Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis
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