Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
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Marit Gudenschwager
Abstract
The reaction of Ni(OH)2 and methanetrisulfonic acid trihydrate CH(SO3H)3·3H2O (H3MTA·3H2O) in N-methyl-pyrrolidone (NMP) leads to the trinuclear complex {Ni3[MTA]2(NMP)8} (triclinic, P1̅, Z=1, a=946.25(3), b=1073.24(3), c=1518.27(4) pm, α=72.193(2), β=87.398(2), γ=89.389(2)°, V=1466.49(7)×106 pm3). The structural features of the methanetrisulfonate anions are tripodal as well as chelating coordination of the Ni2+ ions. The thermal analysis has shown that the compound is first losing NMP molecules and that the solvent-free methanetrisulfonate finally decomposes yielding Ni3S2.
Dediacted to: Professor Wolfgang Bensch on the occasion of his 65th birthday.
Acknowledgement
Financial support of the Deutsche Forschungsgemeinschaft is gratefully acknowledged.
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©2019 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Preface
- Congratulations to Professor Wolfgang Bensch on the occasion of his 65th birthday
- Orthorhombic sulfur from Cap Garonne, Mine du Pradet
- An unprecedented structural phase transition in struvite-type compounds: dimorphism of KMgAsO4(H2O)6
- ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGa
- Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
- Crystal structure of the high-temperature form of the trisulfide Cs2S3 and the (3+1)D modulated structure of the telluride K37Te28
- Synthesis, crystal structure and properties of Cd(NCS)2 coordination compounds with two different Cd coordination modes
- Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
- The role of synthesis conditions for structural defects and lattice strain in β-TaON and their effect on photo- and photoelectrocatalysis
- Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
- Electronic and magnetic properties of the 2H-NbS2 intercalated by 3d transition metal atoms
- CsTb3STe4 und CsTb5S2Te6: Zwei pseudo-ternäre Caesium-Terbium-Chalkogenide mit geordneten S2−- und Te2−-Anionen
- Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
- Crystal structures and FT-IR spectra of three N,N-dicyclohexylmethylammonium halides C13H26N+X− (X = Cl, Br, I)
- Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides RE14T3Al3 (RE = Y, Gd–Tm, Lu; T = Co, Ni)
- Modulated vacancy ordering in SrGe6−x (x≈0.45)
- Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Preface
- Congratulations to Professor Wolfgang Bensch on the occasion of his 65th birthday
- Orthorhombic sulfur from Cap Garonne, Mine du Pradet
- An unprecedented structural phase transition in struvite-type compounds: dimorphism of KMgAsO4(H2O)6
- ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGa
- Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
- Crystal structure of the high-temperature form of the trisulfide Cs2S3 and the (3+1)D modulated structure of the telluride K37Te28
- Synthesis, crystal structure and properties of Cd(NCS)2 coordination compounds with two different Cd coordination modes
- Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
- The role of synthesis conditions for structural defects and lattice strain in β-TaON and their effect on photo- and photoelectrocatalysis
- Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
- Electronic and magnetic properties of the 2H-NbS2 intercalated by 3d transition metal atoms
- CsTb3STe4 und CsTb5S2Te6: Zwei pseudo-ternäre Caesium-Terbium-Chalkogenide mit geordneten S2−- und Te2−-Anionen
- Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
- Crystal structures and FT-IR spectra of three N,N-dicyclohexylmethylammonium halides C13H26N+X− (X = Cl, Br, I)
- Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides RE14T3Al3 (RE = Y, Gd–Tm, Lu; T = Co, Ni)
- Modulated vacancy ordering in SrGe6−x (x≈0.45)
- Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis
