Home Physical Sciences Crystal structure of bis(benzyltrimethylammonium) tetrathiotungstate(VI), {(C6H5CH2)(CH3)3N}2[WS4]
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Crystal structure of bis(benzyltrimethylammonium) tetrathiotungstate(VI), {(C6H5CH2)(CH3)3N}2[WS4]

  • Kang-Woo Kim ORCID logo EMAIL logo and Sunghyeon Kim
Published/Copyright: July 23, 2024
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 239 Issue 5

Abstract

C20H32N2S4W, monoclinic, C2/c (no. 15), a = 37.4033(15) Å, b = 17.2676(7) Å, c = 16.4860(6) Å, β = 109.319(1)°, V = 10,048.2(7) Å3, Z = 16, Rgt(F) = 0.0422, wRref(F2) = 0.0930, T = 223 K.

CCDC no.: 2367191

Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Yellow block
Size: 0.29 × 0.14 × 0.08 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 4.94 mm−1
Diffractometer, scan mode: Bruker APEX-II, φ and ω
θmax, completeness: 28.3°, >99 %
N(hkl)measured, N(hkl)unique, Rint: 118,320, 12,469, 0.079
Criterion for Iobs, N(hkl)gt: Iobs > 2σ(Iobs), 8,148
N(param)refined: 487
Programs: Bruker, 1 SHELX, 2 WinGX/ORTEP, 3 Diamond 4
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
W1 0.40044 (2) 0.07851 (2) 0.31167 (2) 0.03921 (7)
W2 0.30181 (2) 0.42727 (2) 0.53104 (2) 0.03924 (7)
S1 0.37581 (4) 0.14333 (9) 0.19157 (9) 0.0482 (4)
S2 0.44472 (5) −0.00035 (10) 0.30061 (10) 0.0577 (4)
S3 0.42301 (6) 0.15726 (11) 0.41950 (12) 0.0724 (6)
S4 0.35799 (6) 0.01174 (14) 0.34256 (14) 0.0849 (7)
S5 0.28045 (5) 0.35198 (9) 0.41808 (9) 0.0501 (4)
S6 0.32216 (6) 0.36055 (10) 0.64827 (11) 0.0640 (5)
S7 0.25639 (5) 0.50434 (10) 0.53929 (11) 0.0606 (5)
S8 0.34911 (6) 0.49463 (12) 0.51957 (13) 0.0726 (5)
N1 0.54509 (13) 0.1079 (3) 0.4435 (3) 0.0411 (11)
N2 0.25296 (13) 0.0984 (3) 0.2200 (3) 0.0389 (11)
N3 0.34829 (14) 0.1373 (3) 0.5970 (3) 0.0456 (12)
N4 0.35240 (16) 0.3709 (3) 0.2668 (3) 0.0529 (13)
C1 0.51817 (17) 0.1088 (4) 0.4924 (4) 0.0560 (16)
H1A 0.528449 0.078531 0.544479 0.084*
H1B 0.514271 0.161775 0.507228 0.084*
H1C 0.494168 0.086788 0.457349 0.084*
C2 0.52909 (18) 0.1545 (4) 0.3637 (4) 0.0570 (17)
H2A 0.546580 0.154052 0.331491 0.086*
H2B 0.505071 0.132353 0.328913 0.086*
H2C 0.525173 0.207340 0.378792 0.086*
C3 0.5496 (2) 0.0254 (4) 0.4186 (4) 0.0637 (19)
H3A 0.567207 0.023850 0.386570 0.096*
H3B 0.559408 −0.005931 0.470047 0.096*
H3C 0.525260 0.005357 0.383207 0.096*
C4 0.58430 (16) 0.1358 (4) 0.4973 (4) 0.0557 (17)
H4A 0.594399 0.101138 0.546652 0.067*
H4B 0.601084 0.132595 0.462657 0.067*
C5 0.58490 (18) 0.2164 (4) 0.5292 (4) 0.0588 (17)
C6 0.5800 (2) 0.2320 (5) 0.6079 (5) 0.076 (2)
H6 0.575546 0.190914 0.640704 0.091*
C7 0.5815 (3) 0.3065 (6) 0.6381 (6) 0.098 (3)
H7 0.578709 0.316376 0.691748 0.118*
C8 0.5873 (3) 0.3665 (6) 0.5890 (8) 0.113 (4)
H8 0.588073 0.417651 0.608971 0.136*
C9 0.5920 (3) 0.3526 (6) 0.5112 (8) 0.116 (4)
H9 0.595867 0.394045 0.478032 0.139*
C10 0.5910 (2) 0.2782 (5) 0.4821 (6) 0.085 (3)
H10 0.594457 0.268940 0.429017 0.102*
C11 0.27752 (17) 0.1071 (4) 0.1650 (4) 0.0547 (16)
H11A 0.268107 0.073990 0.114955 0.082*
H11B 0.277072 0.160633 0.146734 0.082*
H11C 0.303304 0.092477 0.197747 0.082*
C12 0.25487 (19) 0.0161 (4) 0.2510 (4) 0.0623 (18)
H12A 0.245376 −0.018275 0.202027 0.093*
H12B 0.280942 0.002908 0.282953 0.093*
H12C 0.239522 0.010687 0.287935 0.093*
C13 0.26774 (19) 0.1497 (4) 0.2968 (4) 0.0626 (19)
H13A 0.251972 0.144389 0.332830 0.094*
H13B 0.293545 0.134937 0.329238 0.094*
H13C 0.267313 0.203094 0.278225 0.094*
C14 0.21188 (16) 0.1156 (3) 0.1693 (4) 0.0443 (14)
H14A 0.202943 0.077273 0.123241 0.053*
H14B 0.196794 0.109334 0.207488 0.053*
C15 0.20474 (16) 0.1950 (3) 0.1303 (3) 0.0433 (14)
C16 0.1967 (2) 0.2563 (4) 0.1748 (5) 0.067 (2)
H16 0.196059 0.248840 0.230809 0.080*
C17 0.1896 (2) 0.3284 (4) 0.1374 (6) 0.081 (2)
H17 0.184593 0.370161 0.168596 0.097*
C18 0.1898 (2) 0.3402 (5) 0.0551 (6) 0.080 (3)
H18 0.185321 0.389832 0.030204 0.096*
C19 0.1965 (2) 0.2789 (5) 0.0100 (5) 0.080 (2)
H19 0.195945 0.286082 −0.046925 0.096*
C20 0.2041 (2) 0.2067 (4) 0.0468 (4) 0.0636 (19)
H20 0.208829 0.165052 0.015093 0.076*
C21 0.3644 (2) 0.0677 (4) 0.5685 (4) 0.0636 (19)
H21A 0.383477 0.083668 0.543771 0.095*
H21B 0.375961 0.034192 0.617421 0.095*
H21C 0.344408 0.039829 0.525672 0.095*
C22 0.3299 (2) 0.1870 (4) 0.5204 (4) 0.071 (2)
H22A 0.348767 0.203408 0.495309 0.106*
H22B 0.310259 0.157703 0.478338 0.106*
H22C 0.318849 0.232142 0.537837 0.106*
C23 0.3191 (2) 0.1126 (5) 0.6348 (5) 0.072 (2)
H23A 0.308570 0.157851 0.653468 0.108*
H23B 0.299120 0.084731 0.591999 0.108*
H23C 0.330673 0.079094 0.683747 0.108*
C24 0.37867 (17) 0.1810 (4) 0.6664 (4) 0.0496 (15)
H24A 0.366435 0.223068 0.687239 0.060*
H24B 0.389734 0.145583 0.714681 0.060*
C25 0.41024 (18) 0.2149 (4) 0.6408 (4) 0.0502 (15)
C26 0.4078 (2) 0.2886 (4) 0.6052 (5) 0.0678 (19)
H26 0.384965 0.316431 0.592366 0.081*
C27 0.4380 (3) 0.3216 (5) 0.5883 (5) 0.081 (2)
H27 0.435891 0.371960 0.565551 0.098*
C28 0.4717 (3) 0.2807 (6) 0.6049 (5) 0.087 (3)
H28 0.492283 0.302577 0.592199 0.104*
C29 0.4746 (2) 0.2089 (5) 0.6397 (5) 0.075 (2)
H29 0.497459 0.181497 0.651967 0.090*
C30 0.44418 (19) 0.1749 (4) 0.6578 (4) 0.0605 (18)
H30 0.446683 0.124810 0.681452 0.073*
C31 0.3472 (2) 0.4512 (4) 0.2919 (5) 0.067 (2)
H31A 0.338745 0.483464 0.240932 0.101*
H31B 0.328470 0.451978 0.320742 0.101*
H31C 0.371135 0.470773 0.330404 0.101*
C32 0.3654 (2) 0.3213 (4) 0.3446 (5) 0.079 (2)
H32A 0.368774 0.268648 0.328029 0.118*
H32B 0.389306 0.340858 0.383176 0.118*
H32C 0.346642 0.322062 0.373514 0.118*
C33 0.3151 (2) 0.3411 (4) 0.2097 (5) 0.083 (2)
H33A 0.318081 0.288356 0.192709 0.124*
H33B 0.296983 0.342123 0.240276 0.124*
H33C 0.306038 0.373499 0.158891 0.124*
C34 0.3807 (2) 0.3676 (4) 0.2183 (5) 0.075 (2)
H34A 0.383652 0.313478 0.203760 0.090*
H34B 0.370121 0.396124 0.164196 0.090*
C35 0.4187 (3) 0.3997 (5) 0.2656 (6) 0.082 (3)
C36 0.4465 (3) 0.3530 (6) 0.3212 (8) 0.113 (4)
H36 0.441648 0.300422 0.328305 0.135*
C37 0.4814 (3) 0.3853 (9) 0.3659 (9) 0.151 (5)
H37 0.500096 0.355636 0.406139 0.182*
C38 0.4887 (4) 0.4631 (9) 0.3505 (10) 0.152 (5)
H38 0.512694 0.484644 0.378909 0.183*
C39 0.4615 (4) 0.5067 (7) 0.2951 (9) 0.124 (4)
H39 0.466462 0.558812 0.286191 0.149*
C40 0.4267 (3) 0.4759 (5) 0.2520 (6) 0.088 (3)
H40 0.408121 0.506570 0.212903 0.106*

1 Source of material

(NH4)2WS4 (0.010 g, 0.029 mmol) and BenzylMe3NCl (0.016 g, 0.086 mmol) were charged to a Pyrex tube with diameter of 9 mm and about 0.5 mL 1:4 (v/v) H2O/MeOH mixture was added as a solvent. While the solvent was being frozen, the Pyrex tube was evacuated under vacuum and sealed with the use of a flame. The sealed tube was placed in an oven and heated at 80 °C for a day, then cooled to room temperature. Yellow orange crystals were isolated by filtration and washed with MeOH and diethyl ether several times. Crystals of (BenzylMe3N)2[WS4] were obtained in 57 % yield, based on the W used.

2 Experimental details

H atoms were positioned geometrically and treated as riding, with C–H = 0.94 (aromatic CH), 0.98 (CH2) and 0.97 (CH3) Å with Uiso(H) = 1.2 (1.5 for methyl) Ueq(C). H atoms of the CH3 were positioned to be staggered with respect to the shortest other bond to the atom to which the CH3 is attached.

3 Comment

The tetrathiotungstate [WS4]2− anion, along with the tetrathiomolybdate [MoS4]2−, is one of the most extensively studied and structurally characterized thiometallate anions. Cations used for the stabilization of the [WS4]2− anion include NH4+, 5 , 6 Rb+, 7 [Ni(tren)2]2+ (tren = tris(2-aminoethyl)amine), 8 Ph4P+, 9 tetraalkylammonium (Me4N+, Et4N+, Pr4N+), 10 alkylammonium with N–H bonds present (H3NCH2CH2NH32+, i–PrNH3+, etc.), 11 , 12 , 13 , 14 , 15 and mixed tetraalkylammonium (BuMe3N+). 16 The title compound, {(C6H5CH2)(CH3)3N}2[WS4], was prepared by the solvothermal reaction of (NH4)2WS4 and (C6H5CH2)(CH3)3NI in a 1:4 (v/v) H2O/MeOH mixture as the solvent, and it is composed of a [WS4]2− molecular anion and two charge-balancing BenzylMe3N+ cations. Besides BuMe3N+, BenzylMe3N+ is another unsymmetrical mixed tetraalkylammonium cation suitable for the stabilization of the [WS4]2− anion.

In the structure of (BenzylMe3N)2[WS4], there are four crystallographically independent cations and two crystallographically independent [WS4]2− anions. The tetrahedral coordination geometry around the W atoms in both [WS4]2− anions is slightly distorted, with S–W–S bond angles between 104.98(9)° and 111.34(7)° for W(1) and between 107.86(8)° and 111.41(7)° for W(2). The W–S bond distances range from 2.155(2) to 2.198(2) Å for W(1) and from 2.161(2) to 2.198(2) Å for W(2). Compared to other [WS4]2− compounds (BenzylMe3N)2[WS4] shows slightly greater Δ values for the difference between the longest and shortest W–S bond distances, which are 0.043 Å for W(1) and 0.037 Å for W(2). The shortest S⋯H distance of 2.685(2) Å occurs between S(7) and H(11A), and there are three additional S⋯H contacts less than 2.80 Å in the pairs of S(4)⋯H(12B), S(2)⋯H(1A), and S(6)⋯H(14B).

Corresponding author: Kang-Woo Kim, Department of Chemistry & Research Institute for Natural Sciences, Incheon National University, Incheon 22012, Korea, E-mail:

Acknowledgments

This work was supported by the Incheon National University Research Grant in 2021.

  1. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

  2. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  3. Research funding: Incheon National University Research Grant in 2021.

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Received: 2024-05-27
Accepted: 2024-07-02
Published Online: 2024-07-23
Published in Print: 2024-10-28

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  35. Crystal structure of (3S,3′S,4R,4′S)-3′-(furan-3-yl)-3-hydroxy-4′-methyl-3,5,6′,7′-tetrahydro-1H,3′H-4,5′-spirobi[isobenzofuran]-1,1′(4′H)-dione-methanol (1/1), C21H22O7
  36. Cocrystal structure of progesterone-isophthalic acid, C25H33O4
  37. The crystal structure of 3-(6-fluoro-1H-indol-3-yl)-1-methylquinoxalin-2(1H)-one, C17H12FN3O
  38. Crystal structure of S-(4-carboxybutyl)- l -cysteine
  39. The cocrystal of 2,2′-(hydrazine-1,1-diyl)bis(1H-imidazole-4,5-dicarbonitrile)– methanol (2/3)
  40. Crystal structure of (1′R,2′S,4′R,6′S)-4,6-dihydroxy-1′,8′,8′-trimethyl-3-(3-methylbutanoyl)-4′,8′,6′,1′,7,2′-hexahydro-1H-4′,6′-methanoxanthene-8-carbaldehyde, C23H30O5
  41. Crystal structure of (3,6-di(2-pyridyl)-4-methylphenyl pyridazine-k 2 N,N′)-bis(1-phenyl-pyrazole-κ 2 C,N) iridium(III) hexafluorophosphate, C39H29F6IrN8P
  42. Crystal structure of 1,5-bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide dimethyl sulfoxide monosolvate, C17H18N4O2S·C2H6OS
  43. Crystal structure of (S)-4-(2-(4-(2-acetyl-5-chlorophenyl)-3-methoxy-6-oxopyridazin-1(6H)-yl)-3-phenylpropanamido)benzoic acid monohydrate, C29H26ClN3O7
  44. The crystal structure of 1,3-bis(2,4-dinitro-1H-imidazol-1-yl)propane
  45. Crystal structure of 4-chlorobenzyl (S)-2-(6-methoxynaphthalen-2-yl)propanoate, C21H19ClO3
  46. Crystal structure of 1-(5-(benzo[d][1,3]dioxol-5-yl)-4-benzyl-1-(4-bromophenyl)-4,5-dihydro-1H-1,2,4-triazol-3-yl)ethan-1-one, C24H20BrN3O3
  47. The crystal structure of (Z)-3′-(2-(1-(3,4-dimethyl-phenyl)-3-methyl-5-oxo-1,5-dihydro-4H-pyrazol-4-ylidene)hydrazinyl)-2′-hydroxy-[1,1′-biphenyl]-3-carboxylicacid ─ methanol (1/1), C26H26N4O5
  48. Crystal structure of (S)-1-phenylpropan-1-aminium (S)-(1-phenylpropyl)carbamate C19H26N2O2
  49. Synthesis and crystal structure of methyl 2-((5-bromo-4-(4-cyclopropylnaphthalen-1-yl)-4H-1,2,4-triazol-3-yl)thio)acetate, C18H16BrN3O2S
  50. The crystal structure of trichlorobis(pyridine-2,6-dithio-κS-carbomethylamido)antimony(III), [SbCl3(C9H11N3S2)2]
  51. Crystal structure of 1,8-dihydroxy-3-{[(triphenylstannyl)oxy]carbonyl} anthracene-9,10-dione, C33H22O6Sn
  52. The crystal structure of (E)-4-(2-(pyridin-4-ylmethylene)hydrazine-1-carbonyl)pyridin-1-ium-2-olate dihydrate, C12H14N4O4
  53. The crystal structure of 6-amino-pyridinium-2-carboxylate, C6H6N2O2
  54. The crystal structure of catena-poly[aqua-nitrato-κ3O,O:O′′-(1,10-phenanthroline-κ2N,N′)sodium(I)], C24H18N6O7Na2
  55. Retractions
  56. Retraction of: Crystal structure of bis[diaquaisonicotinatosamarium(III)]-µ-isonicotinato-[diisonicotinatocopper(II)], CuSm2(C6H4NO2)8(H2O)4
  57. Retraction of: Crystal structure of aqua(2,2′-bipyridine-k 2 N:N′)(nitrato)-(4-aminobenzoato)cadmium(II) nitrate, [Cd(H2O)(NO3)(C10H8N2)(C7H7NO2)][NO3]
https://doi.org/10.1515/ncrs-2024-0228
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Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. Editorial 2024 – New developments and changes of Zeitschrift für Kristallographie – New Crystal Structures
  4. New Crystal Structures
  5. Hydrogen bonding and π⋅⋅⋅halogen interactions in the crystal structure of bis(theophyllinium) hexachloridoplatinate(IV) monohydrate
  6. The crystal structure of 6-amino-2-carboxypyridin-1-ium perchlorate, C6H7ClN2O6
  7. Crystal structure of poly[(μ4-(3-amino-1H-1,2,4-triazol-1-yl)benzene-1,3-dicarboxylato-κ 4 N:O:O':O')(1-methylpyrroldin-2-one-κ1O)dicopper(II)] – 1-methylpyrroldin-2-one (1/3), C40H48Cu2N12O12
  8. The crystal structure of 18-crown-6-k6O6(2,4,5-trinitroimidazol-1-ido-k1O)potassium(I)
  9. Crystal structure of poly[tetraaqua-bis(μ2-5-bromoisophthalato-κ3O,O′:O″)-(μ2-1,5-bis(imidazol-2-methyl)pentane-κ2N:N′)dicadmium(II)] dihydrate
  10. Crystal structure of (5R,6S,E)-5-acetoxy-2-methyl-6-((2aR,3R,5aS,5bS,11aR,12aS)-2a,5a,8,8-tetramethyl-9-oxotetradecahydro-1H,12H-cyclopenta[a]cyclopropa[e]phenanthren-3-yl)hept-2-enoic acid, C32H48O5
  11. The crystal structure of poly[diaqua-bis(μ2 -thiocyanato-κ2N:O)cobalt(II) monohydrate
  12. The crystal structure of 1,3,5-tri(1H-imidazol-1-yl)benzene–2,3,5,6-tetrachlorobenzene-1,4-dicarboxylic acid (1/1)
  13. Crystal structure of dichlorido-bis(1-[(2-ethyl-benzimidazole-1-yl)methyl]-1H–benzotriazole) cadmium(II), C32H32CdN10OCl2
  14. The crystal structure of N′-(tert-butyl)-N′-(3,5-dimethylbenzoyl)-3-methoxy-N,2-dimethylbenzohydrazide, C23H30N2O3
  15. Crystal stucture of 3-benzamido-N-(2-bromo-4-(perfluoropropan-2-yl)-6-(trifluoromethyl)phenyl)-2-fluorobenzamide
  16. Crystal structure of bis(μ-benzeneselenolato)-(tetracarbonyl)-{μ-[N-(diphenylphosphanyl)-N-(3-ethynylphenyl)-P,P-diphenylphosphinous amide]} diiron, C48H35Fe2NO4P2Se2
  17. The crystal structure of 2′-(p-tolyl)-4′H-spiro[isochromane-1,1′-naphthalene]-3,4′-dione, C25H18O3
  18. The crystal structure of poly[hexaqua-tetrakis(μ4-pyridine-2,4-dicarboxylate-κ5N: O: O′: O″: O‴)-bi(μ2-pyridine-2,4-dicarboxylate-κ3N: O: O′)-digadolinium(III)tricopper (II)], [Gd2Cu3(C7H3NO4)6(H2O)6] n
  19. Crystal structure of poly[bis(4-(4-(pyridin-4-yl)phenyl)pyridin-1-ium-κ1N)-(μ4-benzene-1,2,4,5-tetracarboxylato-κ5O:O′: O″:O‴:O⁗)-(μ2-2,5-dicarboxyterephthalato-κ2O:O′)dizinc(II)], C52H32N4O16Zn2
  20. The crystal structure of 4-(3-carboxy-1-ethyl-6-fluoro-4-oxo-1,4-dihydroquinolin-7-yl)piperazin-1-ium 2-carboxy-6-nitrobenzoate monohydrate, C24H25FN4O10
  21. Crystal structure of dichlorido-(1-((3,5-dimethyl-2,3-dihydro-1H-1,2,3-triazol-1-yl)methyl)-1H-benzo[d][1,2,3]triazole-k1N)zinc(II), C22H24ZnN12Cl2
  22. The crystal structure of (3-chlorothiophene-2-carboxylato-κ2O, O′)-(2,2′-dipyridyl-κ2N,N′)lead(II), C20H12Cl2N2O4S2Pb
  23. Synthesis and crystal structure of (Z)-4-((1-(3-fluorophenyl)-1H-1,2,3-triazol-4-yl)methylene)-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, C19H14FN5O
  24. The crystal structure of the coordination compound catena-poly[(18-crown-6-ether-κ6O6)(4,5-dinitroimidazolato-κ1O)potassium(I)]
  25. Crystal structure of 7-(diethylamino)-3-(trifluoroacetyl)-2H-chromen-2-one, C15H14F3NO3
  26. Crystal structure of dichlorido-1-[(2-ethylimidazole-1-yl)methyl]-1H–benzotriazole κ1N zinc(II), C24H26ZnN10Cl2
  27. Crystal and molecular structure of 5-bromopyridine-2,3-diamine
  28. Crystal structure of catena-poly[bis(μ2-1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine-3-carboxylato-k3-O,O′:O″)hexaqua-dicobalt tetrahydrate], C26H36N4O20Co2
  29. Crystal structure of thiocyanate-κ1N-bis(μ1-2,6-diformyl-4-methylphenol oxime-κ2N,O)-manganese(III) acetonitrile solvate, C21H21MnN6O6S
  30. The crystal structure of pyrrolidin-1-yl pivalate, C9H13NO4
  31. The crystal structure of 2,2′-(2,2-diphenylethene-1,1-diyl)bis(1,4-dimethoxybenzene), C30H28O4
  32. Crystal structure of bis(benzyltrimethylammonium) tetrathiotungstate(VI), {(C6H5CH2)(CH3)3N}2[WS4]
  33. The crystal structure of ethyl (Z)-2-(ethoxymethylene)-3-oxobutanoate, C9H14O4
  34. The crystal structure of (E)-6-bromo-3,5-dimethyl-2-(1-phenylprop-1-en-2-yl)-3Himidazo[4,5b]pyridine, C17H16BrN3
  35. Crystal structure of (3S,3′S,4R,4′S)-3′-(furan-3-yl)-3-hydroxy-4′-methyl-3,5,6′,7′-tetrahydro-1H,3′H-4,5′-spirobi[isobenzofuran]-1,1′(4′H)-dione-methanol (1/1), C21H22O7
  36. Cocrystal structure of progesterone-isophthalic acid, C25H33O4
  37. The crystal structure of 3-(6-fluoro-1H-indol-3-yl)-1-methylquinoxalin-2(1H)-one, C17H12FN3O
  38. Crystal structure of S-(4-carboxybutyl)- l -cysteine
  39. The cocrystal of 2,2′-(hydrazine-1,1-diyl)bis(1H-imidazole-4,5-dicarbonitrile)– methanol (2/3)
  40. Crystal structure of (1′R,2′S,4′R,6′S)-4,6-dihydroxy-1′,8′,8′-trimethyl-3-(3-methylbutanoyl)-4′,8′,6′,1′,7,2′-hexahydro-1H-4′,6′-methanoxanthene-8-carbaldehyde, C23H30O5
  41. Crystal structure of (3,6-di(2-pyridyl)-4-methylphenyl pyridazine-k 2 N,N′)-bis(1-phenyl-pyrazole-κ 2 C,N) iridium(III) hexafluorophosphate, C39H29F6IrN8P
  42. Crystal structure of 1,5-bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide dimethyl sulfoxide monosolvate, C17H18N4O2S·C2H6OS
  43. Crystal structure of (S)-4-(2-(4-(2-acetyl-5-chlorophenyl)-3-methoxy-6-oxopyridazin-1(6H)-yl)-3-phenylpropanamido)benzoic acid monohydrate, C29H26ClN3O7
  44. The crystal structure of 1,3-bis(2,4-dinitro-1H-imidazol-1-yl)propane
  45. Crystal structure of 4-chlorobenzyl (S)-2-(6-methoxynaphthalen-2-yl)propanoate, C21H19ClO3
  46. Crystal structure of 1-(5-(benzo[d][1,3]dioxol-5-yl)-4-benzyl-1-(4-bromophenyl)-4,5-dihydro-1H-1,2,4-triazol-3-yl)ethan-1-one, C24H20BrN3O3
  47. The crystal structure of (Z)-3′-(2-(1-(3,4-dimethyl-phenyl)-3-methyl-5-oxo-1,5-dihydro-4H-pyrazol-4-ylidene)hydrazinyl)-2′-hydroxy-[1,1′-biphenyl]-3-carboxylicacid ─ methanol (1/1), C26H26N4O5
  48. Crystal structure of (S)-1-phenylpropan-1-aminium (S)-(1-phenylpropyl)carbamate C19H26N2O2
  49. Synthesis and crystal structure of methyl 2-((5-bromo-4-(4-cyclopropylnaphthalen-1-yl)-4H-1,2,4-triazol-3-yl)thio)acetate, C18H16BrN3O2S
  50. The crystal structure of trichlorobis(pyridine-2,6-dithio-κS-carbomethylamido)antimony(III), [SbCl3(C9H11N3S2)2]
  51. Crystal structure of 1,8-dihydroxy-3-{[(triphenylstannyl)oxy]carbonyl} anthracene-9,10-dione, C33H22O6Sn
  52. The crystal structure of (E)-4-(2-(pyridin-4-ylmethylene)hydrazine-1-carbonyl)pyridin-1-ium-2-olate dihydrate, C12H14N4O4
  53. The crystal structure of 6-amino-pyridinium-2-carboxylate, C6H6N2O2
  54. The crystal structure of catena-poly[aqua-nitrato-κ3O,O:O′′-(1,10-phenanthroline-κ2N,N′)sodium(I)], C24H18N6O7Na2
  55. Retractions
  56. Retraction of: Crystal structure of bis[diaquaisonicotinatosamarium(III)]-µ-isonicotinato-[diisonicotinatocopper(II)], CuSm2(C6H4NO2)8(H2O)4
  57. Retraction of: Crystal structure of aqua(2,2′-bipyridine-k 2 N:N′)(nitrato)-(4-aminobenzoato)cadmium(II) nitrate, [Cd(H2O)(NO3)(C10H8N2)(C7H7NO2)][NO3]
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