Startseite Crystal structure of tetraethylammonium bicarbonate–1-(diaminomethylene)thiourea(1/1)
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Crystal structure of tetraethylammonium bicarbonate–1-(diaminomethylene)thiourea(1/1)

  • Zheng Zhang , Peiyu Wang und Xin Zhu ORCID logo EMAIL logo
Veröffentlicht/Copyright: 5. Juni 2024
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Zeitschrift für Kristallographie - New Crystal Structures
Aus der Zeitschrift Zeitschrift für Kristallographie - New Crystal Structures Band 239 Heft 4

Abstract

C44H108N20O12S4, monoclinic, P21/n (no. 14), a = 8.0480(3) Å, b = 18.6415(7) Å, c = 11.9008(4) Å, β = 103.242(2)°, V = 1737.97(11) Å3, Z = 4, Rgt (F) = 0.0471, wRref (F 2) = 0.1422, T = 296(2) K.

CCDC no.: 2357536

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colorless block
Size: 0.47 × 0.12 × 0.07 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 0.20 mm−1
Diffractometer, scan mode: φ and ω
θ max, completeness: 25.0°, 99 %
N(hkl)measured, N(hkl)unique, R int: 10,226, 3044, 0.019
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 2410
N(param)refined: 221
Programs: SHELX 1 , 2
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
S1 0.32990 (9) 1.00951 (3) 0.87658 (5) 0.0736 (3)
C1 0.2556 (2) 0.97088 (10) 0.74530 (17) 0.0483 (5)
N1 0.2140 (3) 1.01363 (9) 0.65342 (16) 0.0630 (5)
H1A 0.1717 0.9957 0.5864 0.076*
H1B 0.2293 1.0592 0.6611 0.076*
O1 0.9445 (2) 0.89455 (7) 0.54335 (13) 0.0658 (5)
H1 1.032 (3) 0.8892 (17) 0.599 (2) 0.099*
C2 0.2812 (3) 0.84572 (10) 0.78966 (17) 0.0511 (5)
N2 0.2237 (2) 0.90117 (8) 0.71882 (13) 0.0522 (5)
O2 0.79049 (19) 0.83603 (7) 0.39712 (12) 0.0589 (4)
C3 0.9049 (3) 0.83194 (9) 0.48672 (16) 0.0447 (5)
N3 0.2254 (3) 0.78137 (9) 0.74990 (16) 0.0684 (6)
H3A 0.2612 0.7436 0.7896 0.082*
H3B 0.1536 0.7775 0.6845 0.082*
O3 0.9859 (2) 0.77752 (7) 0.52714 (12) 0.0625 (4)
N4 0.3914 (3) 0.84963 (10) 0.89030 (16) 0.0654 (6)
H4A 0.4253 0.8111 0.9285 0.078*
H4B 0.4292 0.8907 0.9177 0.078*
C4a 0.7777 (6) 0.1207 (3) 0.6318 (4) 0.0906 (16)
H4Ca 0.8411 0.0776 0.6234 0.109*
H4Da 0.8363 0.1610 0.6064 0.109*
C4′b 0.5941 (9) 0.1323 (5) 0.6866 (7) 0.089 (2)
H4′Ab 0.5442 0.1792 0.6920 0.106*
H4′Bb 0.5259 0.0969 0.7154 0.106*
N5 0.7770 (3) 0.13075 (13) 0.75835 (19) 0.0730 (6)
C5a 0.5958 (6) 0.1149 (4) 0.5533 (3) 0.165 (2)
H5Aa 0.6036 0.1087 0.4745 0.247*
H5Ba 0.5380 0.0745 0.5768 0.247*
H5Ca 0.5332 0.1579 0.5598 0.247*
C5′b 0.5958 (6) 0.1149 (4) 0.5533 (3) 0.165 (2)
H5′Ab 0.4811 0.1157 0.5071 0.247*
H5′Bb 0.6628 0.1504 0.5252 0.247*
H5′Cb 0.6445 0.0683 0.5485 0.247*
C6a 0.6921 (7) 0.0657 (3) 0.7999 (5) 0.0959 (16)
H6Aa 0.5727 0.0637 0.7599 0.115*
H6Ba 0.6981 0.0700 0.8819 0.115*
C6′b 0.8761 (9) 0.0709 (4) 0.7326 (7) 0.087 (2)
H6′Ab 0.9942 0.0753 0.7744 0.104*
H6′Bb 0.8723 0.0690 0.6506 0.104*
C7a 0.7847 (7) −0.0053 (2) 0.7757 (6) 0.159 (2)
H7Aa 0.7307 −0.0458 0.8020 0.238*
H7Ba 0.7773 −0.0097 0.6943 0.238*
H7Ca 0.9025 −0.0035 0.8161 0.238*
C7′b 0.7847 (7) −0.0053 (2) 0.7757 (6) 0.159 (2)
H7′Ab 0.8463 −0.0468 0.7604 0.238*
H7′Bb 0.7892 −0.0025 0.8569 0.238*
H7′Cb 0.6679 −0.0087 0.7338 0.238*
C8a 0.9604 (6) 0.1369 (3) 0.8193 (5) 0.0937 (16)
H8Aa 1.0108 0.1794 0.7938 0.112*
H8Ba 1.0236 0.0952 0.8037 0.112*
C8′b 0.7622 (9) 0.1334 (5) 0.8836 (6) 0.080 (2)
H8′Ab 0.7119 0.0896 0.9048 0.096*
H8′Bb 0.6934 0.1739 0.8967 0.096*
C9a 0.9645 (7) 0.1424 (3) 0.9585 (4) 0.174 (2)
H9Aa 1.0806 0.1465 1.0015 0.261*
H9Ba 0.9013 0.1838 0.9725 0.261*
H9Ca 0.9140 0.1000 0.9824 0.261*
C9′b 0.9645 (7) 0.1424 (3) 0.9585 (4) 0.174 (2)
H9′Ab 0.9671 0.1445 1.0395 0.261*
H9′Bb 1.0303 0.1020 0.9435 0.261*
H9′Cb 1.0120 0.1857 0.9354 0.261*
C10a 0.6703 (6) 0.1940 (3) 0.7738 (5) 0.0897 (16)
H10Aa 0.6536 0.1944 0.8520 0.108*
H10Ba 0.5591 0.1902 0.7212 0.108*
C10′b 0.8756 (12) 0.2016 (5) 0.7359 (9) 0.106 (3)
H10Cb 0.9846 0.2047 0.7911 0.127*
H10Db 0.8965 0.2006 0.6588 0.127*
C11a 0.7612 (7) 0.2682 (2) 0.7493 (5) 0.164 (2)
H11Aa 0.6908 0.3081 0.7597 0.246*
H11Ba 0.8705 0.2723 0.8021 0.246*
H11Ca 0.7761 0.2681 0.6715 0.246*
C11′b 0.7612 (7) 0.2682 (2) 0.7493 (5) 0.164 (2)
H11Db 0.8183 0.3115 0.7361 0.246*
H11Eb 0.6539 0.2648 0.6941 0.246*
H11Fb 0.7416 0.2689 0.8259 0.246*

  1. aOccupancy: 0.613 (4), boccupancy: 0.387 (4).

1 Source of materials

Amidinothiourea and tetraethylammonium (25 % aqueous solution) were phurchased and used without further purification. The two compounds were mixed in a molar ratio of 1:1. The mixture was dissolved in a minimum amount of ethanol and water, the mixture was vigorously stirred for about 60 min. Subsequently the clean solution was set aside to allow it slow evaporation at room temperature. Colorless block crystals were obtained about 15 days later. It can be concluded that the bicarbonate anions are present in the crystal structure due to the absorption of CO2 of the air under basic conditions.

2 Experimental details

Crystal data, data collection and structure refinement details are summarized in Table 1. It is noted that there exists position disorder in tetraethylammonium due to the rotation of the terminal ethyl groups. To solve this problem, the C–C chains were split to two sets and the related EADP and EXYZ orders were used in the refinement.

3 Comment

Amidinothiourea can be applied in different research fields including supramolecular architecture 3 and membrane materials. 4 It can be seen as a planar configuration that can form plentiful hydrogen bonds due to its N–H functional groups. Till now, the organic crystal structure of tetrabutylammonium sulfanilate – 1-(diaminomethylene)thiourea, 5 bis(tetrapropylammonium) terephthalate – 1-(diaminomethylene)thiourea – water 6 and tetrapropylammonium bicarbonate – 1-(diaminomethylene)thiourea – water 7 have been reported.

In the title compound, the asymmetric unit of the title compound contains one independent 1-(diaminomethylene)thiourea molecule, one bicarbonate anion and one disordered tetraethylammonium cation. Observing the linking mode of the structure, the amidinothiourea molecule directly connects with the neighboring bicarbonate anion to generate the hydrogen-bonded chains by strong N–H⋯O contacts, then the adjacent chains link with each other to obtain the 2-dimensional layers by the linkage of the bicarbonate ions. The tetraethylammonium is between the layers mentioned above. Clearly, this crystal structure is a very typical ‘sandwich-like’ structure.

Corresponding author: Xin Zhu, Pharmacy College, Henan University of Chinese Medicine, Zhengzhou, 450046, China, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This project was sponsored by the Scientific and Technological Brainstorm Project of Henan Province (242102310525).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

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2. Sheldrick, G. M. Crystal Structure Refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8. https://doi.org/10.1107/s2053229614024218.Suche in Google Scholar

3. Janczak, J. Supramolecular Architecture and SHG Activity of Organic Crystals Formed Between the Amidinothiourea and Nicotinic Acid. J. Mol. Struct. 2023, 1273, 134385. https://doi.org/10.1016/j.molstruc.2022.134385.Suche in Google Scholar

4. Yang, B.; Hu, X.; Zhou, Q. Construction of Amidinothiourea Crosslinked Graphene Oxide Membrane by Multilayer Self-Assembly for Efficient Removal of Heavy Metal Ions. Mater. Test. 2024, 66, 526–533. https://doi.org/10.1515/mt-2023–0352.10.1515/mt-2023-0352Suche in Google Scholar

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6. Li, M.; Geng, F.; Zhu, H. Crystal Structure of Bis(Tetrapropylammonium) Terephthalate – 1-(Diaminomethylene)Thiourea – Water (1/2/4) C18H40N5O4S. Z. Kristallogr. N. Cryst. Struct. 2023, 238, 491–493. https://doi.org/10.1515/ncrs-2023-0051.Suche in Google Scholar

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Received: 2024-04-12
Accepted: 2024-05-23
Published Online: 2024-06-05
Published in Print: 2024-08-27

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of hexaquazinc(II) poly[hexakis(μ2-4-methylbenzenesulfinato-κ2O:O′) dizinc(II)]
  4. The crystal structure of poly[((2-(4,5-dihydro-1H-pyrazol-4-yl)-1,3-dioxoisoindoline-5-carbonyl)oxy)(1-(dimethylamino)ethoxy)zinc[II]], C16H14ZnN4O5
  5. Crystal structure of bis[(triaqua-4-iodopyridine-2,6-dicarboxylato-κ 3 N,O,O ″)cobalt(II)] trihydrate, C14H22N2O17I2Co2
  6. Crystal structure of bis(methanol-κO)-bis(nitrato-kO)-bis(1-((2-(2-chloro-4-(4-chlorophenoxy)phenyl)-4-methyl-1,3-dioxolan-2-yl)methyl)-1H-1,2,4-triazole-κN)cadmium(II), C40H42O14N8Cl4Cd
  7. Crystal structure of poly[μ2-dichlorido-(μ2-1-[(2,4-dimethyl-1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2N:N′)cadmium(II)], C11H12CdN6Cl2
  8. The crystal structure of (3aS, 4R, 7S, 7aR)-hexahydro-4, 7-methano-1H-isoindole-1, 3-(2H)-dione, C9H11NO2
  9. The crystal structure of N-(acridin-9-yl)-4-chloro-N-(4-chloro-butanoyl) butanamide, C21H20Cl2N2O2
  10. Crystal structure of 3,3′-dimethoxy-4,4′-oxy-di-benzaldehyde, C16H14O5
  11. The crystal structure of tetrakis(μ 2-2-amino-3,5-dibromobenzoate-κ 2 O:O′)-octakis(n-butyl-κ 1 C)-bis(μ 3-oxo)tetratin(II), C60H92Br8N4O10Sn4
  12. Crystal structure of methyl-1-(naphthalen-1-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b] indole-3-carboxylate, C23H20N2O2
  13. Crystal structure of tetrapropylammonium bicarbonate–1-(diaminomethylene)thiourea(1/1)
  14. Crystal structure of 6,6′-((1E,1′E)-((2-phenylpyrimidine-4,6-diyl)bis(hydrazin-2-yl-1-ylidene))bis(methaneylylidene))bis(2-methoxyphenol)monohydrate, C26H26N6O5
  15. Crystal structure of bis(N,N,N-trimethylbutanaminium) tetrathiotungstate(VI), (BuMe3N)2[WS4]
  16. The crystal structure of 2,3,9-triphenyl-9-(2-phenylbenzofuran-3-yl)-9H-9λ 5-benzo[4,5][1,2]oxaphospholo[2,3-b][1,2,5]oxadiphosphole 2-oxide, C40H28O4P2
  17. Crystal structure of 1–methyl-3-propyl-4-nitro-1H-pyrazole-5-carboxylic acid, C8H11N3O4
  18. Crystal structure of N-(benzo[d]thiazol-2-yl)-2-chloroacetamide, C9H7ClN2OS
  19. The crystal structure of N-benzyl-2-chloro-N-(p-tolyl) acetamide, C16H16ClNO
  20. Crystal structure of 3,4-dimethoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C23H24O5
  21. Crystal structure of 2,5-bis(2,5-dimethoxybenzyl)-3,6-dimethyl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione, C26H28N2O6
  22. Crystal structure of poly[(μ3-5-bromoisophthalato-κ4 O,O′ :O″,O‴)-(μ2-1,2-bis(1,2,4-triazole-1-ylmethyl)benzene-κ2 N:N′)cobalt(II)], C20H15BrCoN6O4
  23. The crystal structure of bis(2-(piperidin-1-ium-4-yl)-1Hbenzo[d]imidazol-3-ium) dihydrogen decavanadate, C24H36N6O28V10
  24. Crystal structure of diaqua-bis(1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine3-carboxylato-O,O′)-cobalt(ii)dihydrate, C26H36N4O14Co
  25. Crystal structure of poly[(μ2-5-bromoisophthalato-κ4 O,O ′:O ″,O ‴)-(μ2-1,4-bis(2-methylimidazol-1-ylmethyl)benzene-N:N′)cadmium(II)], C24H21BrCdN4O4
  26. The crystal structure of dimethyl 8-(3-methoxy-2-(methoxycarbonyl)-3-oxoprop-1-en-1-yl)-4-methyl-1-(p-tolyl)-1,3a,4,8b-tetrahydro-3H-furo[3,4-b]indole-3,3-dicarboxylate. C28H29NO9
  27. Crystal structure of (3R)-1-(3,5-dimethoxyphenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate chloride, C21H23ClN2O4
  28. Synthesis and crystal structure of 3-(4,5-dihydroisoxazol-3-yl)-2-methyl-4-(methylsulfonyl)benzoic acid, C12H13NO5S
  29. The crystal structure of hexaaquamagnesium(II) bis-3-(1,2,3,4-tetrahydrobenzo[4,5]imidazo[1,2-α]pyridin-1-yl)benzoate, C36H42N4O10Mg
  30. Crystal structure of 4-formyl-2-methoxyphenyl 2-acetoxybenzoate, C17H14O6
  31. Crystal structure of poly[octakis(μ-oxido)-tris(μ-1,1′-[[1,1′-biphenyl]-4,4′-diylbis(methylene)]bis(1H-imidazole))-tetrakis(oxido)-tetra-vanadium-dimanganese(II)dihydrate], C30H29MnN6O7V2
  32. Crystal structure of 4,8a-bis(4-chlorophenyl)-1,5,6-tris(4-fluorobenzyl)-1,4,4a,4b,5,6,8a,8b-octahydrocyclobuta[1,2-b:3,4-c′]dipyridine-3,8-dicarbonitrile, C45H33Cl2F3N4
  33. Crystal structure of benzo[d][1,3]dioxol-5-ylmethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C22H20O5
  34. Crystal structure of N-benzoyl-N-phenylhydroxylaminato-dicarbonylrhodium(I), [Rh(BNA)CO2]
  35. The crystal structure of N-(2-((2-methoxynaphthalen-1-yl)ethynyl)phenyl)-4-methylbenzenesulfonamide, C26H21NO3S
  36. The crystal structure of methyl ((4-aminobenzyl)sulfonyl)-d-prolinate, C13H18N2O4S
  37. The crystal structure of dichlorido-(N-isopropyl-N-(pyridin-2-ylmethyl)propan-2-amine-κ 2 N, N′)palladium(II), C12H20N2PdCl2
  38. Crystal structure of poly[(μ 2-5-hydroxyisophthalato-κ4 O,O′:O″,O‴)-(μ 2-1,4-bis(2-methylimidazolyl)-1-butene-N:N′)nickel(II)], C20H20NiN4O5
  39. The crystal structure of {hexakis(1-methyl-1H-imidazole-κ 1 N)cobalt(II)}(μ 2-oxido)-hexaoxido-dimolybdenum(VI)— 1-methyl-1H-imidazole (1/2), C32H48CoMo2N16O7
  40. Synthesis, crystal structure and nonlinear optical property of 1-((propan-2-ylideneamino)oxy)propan-2-yl-4-methylbenzenesulfonate, C13H19O4NS
  41. The crystal structure of N,N-(ethane-1,1-diyl)dibenzamide, C16H16N2O2
  42. Crystal structure of 1-(4-bromophenyl)-3-(diphenylphosphoryl)-3-hydroxypropan-1-one, C21H18BrO3P
  43. The crystal structure of fac-tricarbonyl(bis(3,5-dimethyl-4H-pyrazole)-κ1 N)-((nitrato)-κ1 O)-rhenium(I)— 3,5-dimethyl-4H-pyrazole(1/1), C18H23N7O6Re
  44. The crystal structure of 4′-chloro-griseofulvin: (2S,6′R)-4′,7-dichloro-4,6-dimethoxy-6′-methyl-3H-spiro[benzofuran-2,1′-cyclohexan]-3′-ene-2′,3-dione, C16H14Cl2O5
  45. Crystal structure of tetraethylammonium bicarbonate–1-(diaminomethylene)thiourea(1/1)
  46. Crystal structure of 1-cyclohexyl-4-p-tolyl-1,4-dihydropyridine-3,5-dicarboxylic acid dimethyl ester, C22H27NO4
  47. The crystal structure of catena-poly(μ2-1,4-bis-(1H-imidazol-1-yl)benzene-copper(I)) dichloridocopper(I), {[CuC12H10N4]+[CuCl2]−} n
  48. The crystal structure of propane-1-aminium-2-carbamate, C4H10N2O2
  49. Crystal structure of 5,6,3′,4′,5′-pentamethoxy-flavone dihydrate, C20H24O9
  50. Crystal structure of (E)-N-(2-bromophenyl)-4-(4-(3,5-dimethoxystyryl)phenoxy)pyrimidin-2-amine, C26H22BrN3O3
  51. Crystal structure of methyl (3R)-1-(2-bromo-4-fluorophenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate hydrochloride hydrate, C19H19BrClFN2O3
  52. The crystal structure of 1-(2-chlorophenyl)-3-(p-tolyl)urea, C14H13ClN2O
  53. The crystal structure of 1-cyclohexyl-3-(p-tolyl)urea, C14H20N2O
  54. Crystal structure of ((benzyl(hydroxy)-amino)(4-chlorophenyl)methyl)-diphenylphosphine oxide, C26H23ClNO2P
  55. The crystal structure of ethyl 3-(1-methyl-1H-indole-2-carbonyl)-2-phenylquinoline-4-carboxylate, C28H22N2O3
  56. The crystal structure of 1,4-bis(1H-imidazol-3-ium-1-yl)benzene dinitrate, C12H12N4 2+·2(NO3 −)
  57. Crystal structure of tris(hexafluoroacetylacetonato-κ2O,O′) bis(triphenylphosphine oxide-κ1O)samarium(III), C51H33F18O8P2Sm
  58. Crystal structure of 1-(4-(dimethylamino)phenyl)-2,3-bis(diphenylphosphoryl)propan-1-one, C35H33NO3P2
  59. Crystal structure of diaqua[bis(μ 2-pyridine 2,6-dicarboxylato) bismuth(III) potassium(I)], C14H10BiKN2O10
  60. Crystal structure of (R)-N, N ′-dimethyl-[1, 1′-binaphthalene]-2, 2′-diamine, C22H20N2
  61. Crystal structure of 1-phenyl-4-(2-furoyl)-3-furyl-1H-pyrazol-5-ol, C18H12N2O4
  62. Crystal structure of bis(14,34-dimethyl[11,21:23,31-terphenyl]-22-yl)diselane, C40H34Se2
https://doi.org/10.1515/ncrs-2024-0169
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Artikel in diesem Heft

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of hexaquazinc(II) poly[hexakis(μ2-4-methylbenzenesulfinato-κ2O:O′) dizinc(II)]
  4. The crystal structure of poly[((2-(4,5-dihydro-1H-pyrazol-4-yl)-1,3-dioxoisoindoline-5-carbonyl)oxy)(1-(dimethylamino)ethoxy)zinc[II]], C16H14ZnN4O5
  5. Crystal structure of bis[(triaqua-4-iodopyridine-2,6-dicarboxylato-κ 3 N,O,O ″)cobalt(II)] trihydrate, C14H22N2O17I2Co2
  6. Crystal structure of bis(methanol-κO)-bis(nitrato-kO)-bis(1-((2-(2-chloro-4-(4-chlorophenoxy)phenyl)-4-methyl-1,3-dioxolan-2-yl)methyl)-1H-1,2,4-triazole-κN)cadmium(II), C40H42O14N8Cl4Cd
  7. Crystal structure of poly[μ2-dichlorido-(μ2-1-[(2,4-dimethyl-1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2N:N′)cadmium(II)], C11H12CdN6Cl2
  8. The crystal structure of (3aS, 4R, 7S, 7aR)-hexahydro-4, 7-methano-1H-isoindole-1, 3-(2H)-dione, C9H11NO2
  9. The crystal structure of N-(acridin-9-yl)-4-chloro-N-(4-chloro-butanoyl) butanamide, C21H20Cl2N2O2
  10. Crystal structure of 3,3′-dimethoxy-4,4′-oxy-di-benzaldehyde, C16H14O5
  11. The crystal structure of tetrakis(μ 2-2-amino-3,5-dibromobenzoate-κ 2 O:O′)-octakis(n-butyl-κ 1 C)-bis(μ 3-oxo)tetratin(II), C60H92Br8N4O10Sn4
  12. Crystal structure of methyl-1-(naphthalen-1-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b] indole-3-carboxylate, C23H20N2O2
  13. Crystal structure of tetrapropylammonium bicarbonate–1-(diaminomethylene)thiourea(1/1)
  14. Crystal structure of 6,6′-((1E,1′E)-((2-phenylpyrimidine-4,6-diyl)bis(hydrazin-2-yl-1-ylidene))bis(methaneylylidene))bis(2-methoxyphenol)monohydrate, C26H26N6O5
  15. Crystal structure of bis(N,N,N-trimethylbutanaminium) tetrathiotungstate(VI), (BuMe3N)2[WS4]
  16. The crystal structure of 2,3,9-triphenyl-9-(2-phenylbenzofuran-3-yl)-9H-9λ 5-benzo[4,5][1,2]oxaphospholo[2,3-b][1,2,5]oxadiphosphole 2-oxide, C40H28O4P2
  17. Crystal structure of 1–methyl-3-propyl-4-nitro-1H-pyrazole-5-carboxylic acid, C8H11N3O4
  18. Crystal structure of N-(benzo[d]thiazol-2-yl)-2-chloroacetamide, C9H7ClN2OS
  19. The crystal structure of N-benzyl-2-chloro-N-(p-tolyl) acetamide, C16H16ClNO
  20. Crystal structure of 3,4-dimethoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C23H24O5
  21. Crystal structure of 2,5-bis(2,5-dimethoxybenzyl)-3,6-dimethyl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione, C26H28N2O6
  22. Crystal structure of poly[(μ3-5-bromoisophthalato-κ4 O,O′ :O″,O‴)-(μ2-1,2-bis(1,2,4-triazole-1-ylmethyl)benzene-κ2 N:N′)cobalt(II)], C20H15BrCoN6O4
  23. The crystal structure of bis(2-(piperidin-1-ium-4-yl)-1Hbenzo[d]imidazol-3-ium) dihydrogen decavanadate, C24H36N6O28V10
  24. Crystal structure of diaqua-bis(1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine3-carboxylato-O,O′)-cobalt(ii)dihydrate, C26H36N4O14Co
  25. Crystal structure of poly[(μ2-5-bromoisophthalato-κ4 O,O ′:O ″,O ‴)-(μ2-1,4-bis(2-methylimidazol-1-ylmethyl)benzene-N:N′)cadmium(II)], C24H21BrCdN4O4
  26. The crystal structure of dimethyl 8-(3-methoxy-2-(methoxycarbonyl)-3-oxoprop-1-en-1-yl)-4-methyl-1-(p-tolyl)-1,3a,4,8b-tetrahydro-3H-furo[3,4-b]indole-3,3-dicarboxylate. C28H29NO9
  27. Crystal structure of (3R)-1-(3,5-dimethoxyphenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate chloride, C21H23ClN2O4
  28. Synthesis and crystal structure of 3-(4,5-dihydroisoxazol-3-yl)-2-methyl-4-(methylsulfonyl)benzoic acid, C12H13NO5S
  29. The crystal structure of hexaaquamagnesium(II) bis-3-(1,2,3,4-tetrahydrobenzo[4,5]imidazo[1,2-α]pyridin-1-yl)benzoate, C36H42N4O10Mg
  30. Crystal structure of 4-formyl-2-methoxyphenyl 2-acetoxybenzoate, C17H14O6
  31. Crystal structure of poly[octakis(μ-oxido)-tris(μ-1,1′-[[1,1′-biphenyl]-4,4′-diylbis(methylene)]bis(1H-imidazole))-tetrakis(oxido)-tetra-vanadium-dimanganese(II)dihydrate], C30H29MnN6O7V2
  32. Crystal structure of 4,8a-bis(4-chlorophenyl)-1,5,6-tris(4-fluorobenzyl)-1,4,4a,4b,5,6,8a,8b-octahydrocyclobuta[1,2-b:3,4-c′]dipyridine-3,8-dicarbonitrile, C45H33Cl2F3N4
  33. Crystal structure of benzo[d][1,3]dioxol-5-ylmethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C22H20O5
  34. Crystal structure of N-benzoyl-N-phenylhydroxylaminato-dicarbonylrhodium(I), [Rh(BNA)CO2]
  35. The crystal structure of N-(2-((2-methoxynaphthalen-1-yl)ethynyl)phenyl)-4-methylbenzenesulfonamide, C26H21NO3S
  36. The crystal structure of methyl ((4-aminobenzyl)sulfonyl)-d-prolinate, C13H18N2O4S
  37. The crystal structure of dichlorido-(N-isopropyl-N-(pyridin-2-ylmethyl)propan-2-amine-κ 2 N, N′)palladium(II), C12H20N2PdCl2
  38. Crystal structure of poly[(μ 2-5-hydroxyisophthalato-κ4 O,O′:O″,O‴)-(μ 2-1,4-bis(2-methylimidazolyl)-1-butene-N:N′)nickel(II)], C20H20NiN4O5
  39. The crystal structure of {hexakis(1-methyl-1H-imidazole-κ 1 N)cobalt(II)}(μ 2-oxido)-hexaoxido-dimolybdenum(VI)— 1-methyl-1H-imidazole (1/2), C32H48CoMo2N16O7
  40. Synthesis, crystal structure and nonlinear optical property of 1-((propan-2-ylideneamino)oxy)propan-2-yl-4-methylbenzenesulfonate, C13H19O4NS
  41. The crystal structure of N,N-(ethane-1,1-diyl)dibenzamide, C16H16N2O2
  42. Crystal structure of 1-(4-bromophenyl)-3-(diphenylphosphoryl)-3-hydroxypropan-1-one, C21H18BrO3P
  43. The crystal structure of fac-tricarbonyl(bis(3,5-dimethyl-4H-pyrazole)-κ1 N)-((nitrato)-κ1 O)-rhenium(I)— 3,5-dimethyl-4H-pyrazole(1/1), C18H23N7O6Re
  44. The crystal structure of 4′-chloro-griseofulvin: (2S,6′R)-4′,7-dichloro-4,6-dimethoxy-6′-methyl-3H-spiro[benzofuran-2,1′-cyclohexan]-3′-ene-2′,3-dione, C16H14Cl2O5
  45. Crystal structure of tetraethylammonium bicarbonate–1-(diaminomethylene)thiourea(1/1)
  46. Crystal structure of 1-cyclohexyl-4-p-tolyl-1,4-dihydropyridine-3,5-dicarboxylic acid dimethyl ester, C22H27NO4
  47. The crystal structure of catena-poly(μ2-1,4-bis-(1H-imidazol-1-yl)benzene-copper(I)) dichloridocopper(I), {[CuC12H10N4]+[CuCl2]−} n
  48. The crystal structure of propane-1-aminium-2-carbamate, C4H10N2O2
  49. Crystal structure of 5,6,3′,4′,5′-pentamethoxy-flavone dihydrate, C20H24O9
  50. Crystal structure of (E)-N-(2-bromophenyl)-4-(4-(3,5-dimethoxystyryl)phenoxy)pyrimidin-2-amine, C26H22BrN3O3
  51. Crystal structure of methyl (3R)-1-(2-bromo-4-fluorophenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate hydrochloride hydrate, C19H19BrClFN2O3
  52. The crystal structure of 1-(2-chlorophenyl)-3-(p-tolyl)urea, C14H13ClN2O
  53. The crystal structure of 1-cyclohexyl-3-(p-tolyl)urea, C14H20N2O
  54. Crystal structure of ((benzyl(hydroxy)-amino)(4-chlorophenyl)methyl)-diphenylphosphine oxide, C26H23ClNO2P
  55. The crystal structure of ethyl 3-(1-methyl-1H-indole-2-carbonyl)-2-phenylquinoline-4-carboxylate, C28H22N2O3
  56. The crystal structure of 1,4-bis(1H-imidazol-3-ium-1-yl)benzene dinitrate, C12H12N4 2+·2(NO3 −)
  57. Crystal structure of tris(hexafluoroacetylacetonato-κ2O,O′) bis(triphenylphosphine oxide-κ1O)samarium(III), C51H33F18O8P2Sm
  58. Crystal structure of 1-(4-(dimethylamino)phenyl)-2,3-bis(diphenylphosphoryl)propan-1-one, C35H33NO3P2
  59. Crystal structure of diaqua[bis(μ 2-pyridine 2,6-dicarboxylato) bismuth(III) potassium(I)], C14H10BiKN2O10
  60. Crystal structure of (R)-N, N ′-dimethyl-[1, 1′-binaphthalene]-2, 2′-diamine, C22H20N2
  61. Crystal structure of 1-phenyl-4-(2-furoyl)-3-furyl-1H-pyrazol-5-ol, C18H12N2O4
  62. Crystal structure of bis(14,34-dimethyl[11,21:23,31-terphenyl]-22-yl)diselane, C40H34Se2
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© 2025 De Gruyter Brill
Heruntergeladen am 22.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ncrs-2024-0169/html
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