Home The crystal structure of bis(2-(piperidin-1-ium-4-yl)-1Hbenzo[d]imidazol-3-ium) dihydrogen decavanadate, C24H36N6O28V10
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The crystal structure of bis(2-(piperidin-1-ium-4-yl)-1Hbenzo[d]imidazol-3-ium) dihydrogen decavanadate, C24H36N6O28V10

  • Qiu-Chen Mao , Xiao-Jie Gong , Si-Yu Zhou and Bao-Kuan Chen ORCID logo EMAIL logo
Published/Copyright: May 24, 2024
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 239 Issue 4

Abstract

C24H36N6O28V10, monoclinic, P21/c (no. 14), a = 10.4869(6) Å, b = 11.5123(7) Å, c = 17.4627(9) Å, β = 108.459(3)°, V = 1999.8(2) Å3, Z = 2, Rgt (F) = 0.0209, wRref (F 2) = 0.0582, T = 296 K.

CCDC no.: 2352346

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Yellow block
Size: 0.23 × 0.22 × 0.20 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 2.33 mm−1
Diffractometer, scan mode: Bruker APEX-II,
θ max, completeness: 25.2°, >99 %
N(hkl)measured, N(hkl)unique, R int: 9980, 3600, 0.021
Criterion for I obs, N(hkl)gt: I obs > 2σ(I obs), 3286
N(param)refined: 311
Programs: Bruker, 1 Olex2, 2 SHELX 3 , 4
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
C1 0.2373 (2) 0.98257 (18) 0.64079 (12) 0.0199 (4)
H1 0.263063 1.063125 0.656335 0.024*
C2 0.2843 (2) 0.95465 (18) 0.57115 (13) 0.0194 (4)
C3 0.3646 (2) 0.86481 (19) 0.48322 (13) 0.0199 (4)
C4 0.3330 (2) 0.97885 (19) 0.45744 (13) 0.0193 (4)
C5 0.3534 (2) 1.0205 (2) 0.38728 (13) 0.0240 (5)
H5 0.331533 1.096321 0.369575 0.029*
C6 0.4070 (2) 0.9446 (2) 0.34590 (13) 0.0259 (5)
H6 0.420153 0.968827 0.298158 0.031*
C7 0.4429 (2) 0.8307 (2) 0.37326 (14) 0.0265 (5)
H7 0.481361 0.782333 0.343961 0.032*
C8 0.4226 (2) 0.7890 (2) 0.44239 (14) 0.0251 (5)
H8 0.446674 0.713716 0.460696 0.030*
C9 0.0832 (2) 0.9765 (2) 0.61482 (13) 0.0270 (5)
H9A 0.045412 1.030844 0.571058 0.032*
H9B 0.053883 0.899024 0.595146 0.032*
C10 0.0323 (2) 1.0051 (2) 0.68442 (14) 0.0292 (5)
H10A 0.051819 1.085750 0.699868 0.035*
H10B −0.064431 0.994647 0.667844 0.035*
C11 0.2462 (3) 0.9392 (2) 0.78194 (14) 0.0320 (6)
H11A 0.284167 0.888437 0.827837 0.038*
H11B 0.271810 1.018390 0.799060 0.038*
C12 0.3015 (2) 0.9068 (2) 0.71469 (13) 0.0247 (5)
H12A 0.282645 0.825642 0.700651 0.030*
H12B 0.398195 0.917458 0.732621 0.030*
N1 0.33117 (18) 0.85341 (15) 0.55419 (11) 0.0213 (4)
H1A 0.339542 0.791044 0.582473 0.026*
N2 0.28333 (18) 1.03039 (15) 0.51395 (11) 0.0200 (4)
H2 0.255872 1.101044 0.512092 0.024*
N3 0.0970 (2) 0.92901 (17) 0.75433 (12) 0.0302 (5)
H3A 0.066252 0.947766 0.795345 0.036*
H3B 0.073982 0.854746 0.740575 0.036*
O1 0.63256 (14) 0.59421 (13) 0.35088 (9) 0.0214 (3)
O2 0.73942 (17) 0.75834 (14) 0.27888 (9) 0.0296 (4)
O3 1.06539 (13) 0.46613 (12) 0.39161 (8) 0.0146 (3)
O4 0.98921 (14) 0.69078 (12) 0.38479 (8) 0.0189 (3)
O5 1.23587 (14) 0.62714 (12) 0.48346 (9) 0.0188 (3)
O6 0.50827 (15) 0.43224 (15) 0.41383 (10) 0.0282 (4)
O7 0.71201 (14) 0.37255 (12) 0.35978 (9) 0.0188 (3)
O8 0.89631 (15) 0.31388 (13) 0.28668 (9) 0.0223 (3)
O9 0.82871 (14) 0.53766 (12) 0.29354 (8) 0.0190 (3)
O10 0.83716 (16) 0.76169 (13) 0.60115 (9) 0.0254 (3)
O11 0.68318 (15) 0.58854 (13) 0.51012 (10) 0.0216 (3)
O12 0.79857 (14) 0.75138 (12) 0.44448 (8) 0.0194 (3)
O13 0.87623 (13) 0.53098 (11) 0.45235 (8) 0.0146 (3)
O14 1.03994 (14) 0.68448 (11) 0.54707 (8) 0.0149 (3)
V1 1.07214 (3) 0.59862 (3) 0.46004 (2) 0.01400 (9)
V2 0.88052 (3) 0.40645 (3) 0.35176 (2) 0.01579 (9)
V3 0.79001 (4) 0.66266 (3) 0.34769 (2) 0.01906 (10)
V4 0.85241 (4) 0.67133 (3) 0.53516 (2) 0.01662 (9)
V5 0.65692 (3) 0.47615 (3) 0.42060 (2) 0.01832 (10)
H11 0.641 (3) 0.583 (2) 0.5372 (16) 0.031 (8)*

1 Source of materials

The title compound was prepared by hydrothermal methods in a mixture of 2-(piperidin-1-ium-4-yl)-1Hbenzo[d]imidazol-3-ium dichloride dihydrate, (0.62 g, 2 mmol), (NH4)6V10O28·6H2O (1.173 g, 1 mmol) and H2O (10 mL). The mixture was stirred for 1 h in air and then transferred to a Teflon-lined stainless steel autoclave (20 mL) and kept at 373 K for 2 h. After the autoclave had cooled to room temperature over 6 h, orange block crystals were filtered off, washed with distilled water, and air-dried to give a yield of 70 % based on V.

2 Experimental details

The structure was solved by Direct Methods with the SHELXS-2018 program. All H-atoms from C atoms and N atoms were positioned with idealized geometry and refined isotropically (U iso(H) = 1.2 U eq(C) or 1.2 U eq(N) for all H atoms) using a riding model with C–H = 0.93–0.97 Å and N–H = 0.86–0.90 Å. The H-atom positions of dihydrogen decavanadate were fixed as found (O–H = 0.85 Å, with U iso(H) = 1.5 U eq(O)), which is also consistent with empirical bond length/bond number calculation.

3 Comment

The synthesis and structure of decavanadate-based inorganic-organic hybrid crystalline compounds have sparked extensive research in coordination chemistry. 5 – 15 Among them, dihydrogen decavanadate anion, [H2V10O28]4− receives growing interest for studying the most probable protonation sites and understanding the key factors determining the crystal packing mode by hydrogen bonding. 11 – 15 As is known to all, benzimidazole derivatives have exhibited much better biological activity in clinical applications and may form hydrogen bonds with oxygen atoms of [H2V10O28]4−. To the best of our knowledge, there are no examples based on the assembly of 2-(piperidin-1-ium-4-yl)-1H-benzo[d]imidazol-3-ium and [H2V10O28]4−. For above considerations, we design and synthesize a new compound with molecular formula: (C12H17N3)2[H2V10O28].

As shown in figure, the asymmetrical unit is made of 2-(piperidin-1-ium-4-yl)-1H-benzo[d]imidazol-3-ium and half of one dihydrogendecavanadate anion, [H2V10O28]4−. Compared to previous [H2V10O28]4−, all the bond lengths and angles of the [H2V10O28]4− anion in title compound are comparable to above analogues. 11 – 14

The 2-(piperidin-1-ium-4-yl)-1H-benzo[d]imidazol-3-ium of the title compound adopts an entirely different conformation with previous report, 16 in which two nitrogen atoms are protonated for balancing charge and stabilizing the crystal structure by hydrogen bonds. There are extensive hydrogen bonds between the protonation of organic amine and [H2V10O28]4− cluster. The typical hydrogen bonds are N1⋯O5 = 2.921 Å, N2⋯O12 = 2.824 Å and N3⋯O3 = 2.797 Å, which ultimately leads to a three-dimensional supermolecular structure.

Corresponding author: Bao-Kuan Chen, School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun, Liaoning, 113001, P.R. China, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: National Natural Science Foundation of China (22171122).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Bruker. SAINT v8.40A; Bruker AXS Inc: Madison, Wisconsin, USA, 2016.Search in Google Scholar

2. Bourhis, L.-J.; Dolomanov, O.-V.; Gildea, R.-J.; Howard, J.-A.-K.; Puschmann, H. The Anatomy of a Comprehensive Constrained, Restrained Refinement Program for the Modern Computing Environment–Olex2 Dissected. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314022207.Search in Google Scholar

3. Sheldrick, G.-M. Crystal Structure Refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8, https://doi.org/10.1107/s2053229614024218.Search in Google Scholar

4. Sheldrick, G. Using Phases to Determine the Space Group. Acta Crystallogr. 2018, A74, A353; https://doi.org/10.1107/s0108767318096472.Search in Google Scholar

5. Yotnoi, B.; Yimklan, S.; Prior, T. J.; Rujiwatra, A. Microwave Assisted Crystal Growth of a New Organic-Decavanadate Assembly: [V10O27(OH)]·2(C6N2H14)·(C6N2H13)·(C6N2H12)·2H2O. J. Inorg. Organomet. Polym. Mater. 2009, 19, 306–313, https://doi.org/10.1007/s10904-009-9271-y.Search in Google Scholar

6. Correia, I.; Avecilla, F.; Marcao, S.; Costa Pessoa, J. Structural Studies of Decavanadate Compounds with Organic Molecules and Inorganic Ions in Their Crystal Packing. Inorg. Chim. Acta 2004, 357, 4476–4487; https://doi.org/10.1016/j.ica.2004.06.055.Search in Google Scholar

7. Wang, Q.; Deng, Y. H. Crystal Structure of Bis(2,5,5,7-Tetramethyl-1,4-Diazepane-1,4-Diium)Diaqua-Bis(1,2-Diaminopropane)Copper(II) Bis(μ6-oxido)Tetrakis(μ3-oxido)-Tetradecakis(μ2-Oxido)-Octaoxido-Decavanadium(V)-Water (1/4), C24H76CuN8V10O34. Z. Kristallogr. N. Cryst. Struct. 2023, 238, 345–347, https://doi.org/10.1515/ncrs-2022-0542.Search in Google Scholar

8. Silva, J. L. F.; da Piedade, M. F. M.; Decavanadates, D. M. T. A Building-Block for Supramolecular Assemblies. Inorg. Chim. Acta 2003, 356, 222–242.10.1016/S0020-1693(03)00385-2Search in Google Scholar

9. Chinea, E.; Dakternieks, D.; Duthie, A.; Ghilardi, C. A.; Gili, P.; Mederos, A.; Midollini, S.; Orlandini, A. Synthesis and Characterization of (NH4)4 [H4V10O28] [NTPH2]2·4H2O (NTPH3=N(CH2CH2COOH)3). Inorg. Chim. Acta 2000, 298, 172–177, https://doi.org/10.1016/s0020-1693(99)00440-5.Search in Google Scholar

10. Biagioli, M.; Strinna-Erre, L.; Micera, G.; Panzanelli, A.; Zema, M. Tetrahydrogendecavanadate (V) and Its Binding to Glycylglycine. Inorg. Chem. Commun. 1999, 2, 214–217; https://doi.org/10.1016/s1387-7003(99)00053-2.Search in Google Scholar

11. Wery, A. S.; Gutierrez–Zorrila, J. M.; Luque, A.; Roman, P.; Martinez-Ripoll, M. Influence of Protonation on Crystal Packing and Thermal Behaviour of Tert-Butylammonium Decavanadates. Polyhedron 1996, 15, 4555–4564; https://doi.org/10.1016/0277-5387(96)00186-6.Search in Google Scholar

12. Farahbakhsh, M.; Kogerler, P.; Schmidt, H.; Rehder, D. Wrapping Oxometalates with Macrocyclic Ligands: The Decavanadate-Cryptand System. Inorg. Chem. Commun. 2000, 3, 111–114; https://doi.org/10.1016/s1387-7003(98)00029-x.Search in Google Scholar

13. Bosnjakovic-Pavlovic, N.; Prevost, J.; Spasojevic-de Bire, A. Crystallographic Statistical Study of Decavanadate Anion Based-Structures: Toward a Prediction of Noncovalent Interactions. Cryst. Growth Des. 2011, 9, 3778–3789.10.1021/cg200236dSearch in Google Scholar

14. Rakovsky, E.; Zurkova, L.; Marek, J. 1,6-Hexanediammonium Dihydrogendecavanadate Dihydrate, (H3N–(CH2)6–NH3)2H2V10O28·2H2O. Cryst. Res. Technol. 2001, 36, 339–344, https://doi.org/10.1002/1521-4079(200103)36:3<339::aid-crat339>3.0.co;2-y.10.1002/1521-4079(200103)36:3<339::AID-CRAT339>3.0.CO;2-YSearch in Google Scholar

15. Missina, J. M.; Gavinho, B.; Postal, K.; Santana, F. S.; Valdameri, G.; De Souza, E. M.; Hughes, D. L.; Ramirez, M. I.; Soares, J. F.; Nunes, G. G. Effects of Decavanadate Salts with Organic and Inorganic Cations on Escherichia coli, Giardia Intestinalis, and Vero Cells. Inorg. Chem. 2018, 57, 11930–11941; https://doi.org/10.1021/acs.inorgchem.8b01298.Search in Google Scholar

16. Cai, B.; Li, S. J.; Liu, G. J.; Shi, X. M.; Du, C. J. The Crystal Structure of 2-(PIPeridin-1-Ium-4-Yl)-1h-Benzo[d]imidazol-3-Ium Dichloride Dihydrate. Z. Kristallogr. N. Cryst. Struct. 2019, 234, 337–339; https://doi.org/10.1515/ncrs-2018-0402.Search in Google Scholar
Received: 2024-03-13
Accepted: 2024-04-30
Published Online: 2024-05-24
Published in Print: 2024-08-27

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  59. Crystal structure of diaqua[bis(μ 2-pyridine 2,6-dicarboxylato) bismuth(III) potassium(I)], C14H10BiKN2O10
  60. Crystal structure of (R)-N, N ′-dimethyl-[1, 1′-binaphthalene]-2, 2′-diamine, C22H20N2
  61. Crystal structure of 1-phenyl-4-(2-furoyl)-3-furyl-1H-pyrazol-5-ol, C18H12N2O4
  62. Crystal structure of bis(14,34-dimethyl[11,21:23,31-terphenyl]-22-yl)diselane, C40H34Se2
https://doi.org/10.1515/ncrs-2024-0127
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of hexaquazinc(II) poly[hexakis(μ2-4-methylbenzenesulfinato-κ2O:O′) dizinc(II)]
  4. The crystal structure of poly[((2-(4,5-dihydro-1H-pyrazol-4-yl)-1,3-dioxoisoindoline-5-carbonyl)oxy)(1-(dimethylamino)ethoxy)zinc[II]], C16H14ZnN4O5
  5. Crystal structure of bis[(triaqua-4-iodopyridine-2,6-dicarboxylato-κ 3 N,O,O ″)cobalt(II)] trihydrate, C14H22N2O17I2Co2
  6. Crystal structure of bis(methanol-κO)-bis(nitrato-kO)-bis(1-((2-(2-chloro-4-(4-chlorophenoxy)phenyl)-4-methyl-1,3-dioxolan-2-yl)methyl)-1H-1,2,4-triazole-κN)cadmium(II), C40H42O14N8Cl4Cd
  7. Crystal structure of poly[μ2-dichlorido-(μ2-1-[(2,4-dimethyl-1H-triazole-1-yl)methyl]-1H-benzotriazole-κ2N:N′)cadmium(II)], C11H12CdN6Cl2
  8. The crystal structure of (3aS, 4R, 7S, 7aR)-hexahydro-4, 7-methano-1H-isoindole-1, 3-(2H)-dione, C9H11NO2
  9. The crystal structure of N-(acridin-9-yl)-4-chloro-N-(4-chloro-butanoyl) butanamide, C21H20Cl2N2O2
  10. Crystal structure of 3,3′-dimethoxy-4,4′-oxy-di-benzaldehyde, C16H14O5
  11. The crystal structure of tetrakis(μ 2-2-amino-3,5-dibromobenzoate-κ 2 O:O′)-octakis(n-butyl-κ 1 C)-bis(μ 3-oxo)tetratin(II), C60H92Br8N4O10Sn4
  12. Crystal structure of methyl-1-(naphthalen-1-yl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b] indole-3-carboxylate, C23H20N2O2
  13. Crystal structure of tetrapropylammonium bicarbonate–1-(diaminomethylene)thiourea(1/1)
  14. Crystal structure of 6,6′-((1E,1′E)-((2-phenylpyrimidine-4,6-diyl)bis(hydrazin-2-yl-1-ylidene))bis(methaneylylidene))bis(2-methoxyphenol)monohydrate, C26H26N6O5
  15. Crystal structure of bis(N,N,N-trimethylbutanaminium) tetrathiotungstate(VI), (BuMe3N)2[WS4]
  16. The crystal structure of 2,3,9-triphenyl-9-(2-phenylbenzofuran-3-yl)-9H-9λ 5-benzo[4,5][1,2]oxaphospholo[2,3-b][1,2,5]oxadiphosphole 2-oxide, C40H28O4P2
  17. Crystal structure of 1–methyl-3-propyl-4-nitro-1H-pyrazole-5-carboxylic acid, C8H11N3O4
  18. Crystal structure of N-(benzo[d]thiazol-2-yl)-2-chloroacetamide, C9H7ClN2OS
  19. The crystal structure of N-benzyl-2-chloro-N-(p-tolyl) acetamide, C16H16ClNO
  20. Crystal structure of 3,4-dimethoxybenzyl 2-(6-methoxynaphthalen-2-yl)propanoate, C23H24O5
  21. Crystal structure of 2,5-bis(2,5-dimethoxybenzyl)-3,6-dimethyl-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione, C26H28N2O6
  22. Crystal structure of poly[(μ3-5-bromoisophthalato-κ4 O,O′ :O″,O‴)-(μ2-1,2-bis(1,2,4-triazole-1-ylmethyl)benzene-κ2 N:N′)cobalt(II)], C20H15BrCoN6O4
  23. The crystal structure of bis(2-(piperidin-1-ium-4-yl)-1Hbenzo[d]imidazol-3-ium) dihydrogen decavanadate, C24H36N6O28V10
  24. Crystal structure of diaqua-bis(1-(3-carboxyphenyl)-5-methyl-4-oxo-1,4-dihydropyridazine3-carboxylato-O,O′)-cobalt(ii)dihydrate, C26H36N4O14Co
  25. Crystal structure of poly[(μ2-5-bromoisophthalato-κ4 O,O ′:O ″,O ‴)-(μ2-1,4-bis(2-methylimidazol-1-ylmethyl)benzene-N:N′)cadmium(II)], C24H21BrCdN4O4
  26. The crystal structure of dimethyl 8-(3-methoxy-2-(methoxycarbonyl)-3-oxoprop-1-en-1-yl)-4-methyl-1-(p-tolyl)-1,3a,4,8b-tetrahydro-3H-furo[3,4-b]indole-3,3-dicarboxylate. C28H29NO9
  27. Crystal structure of (3R)-1-(3,5-dimethoxyphenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate chloride, C21H23ClN2O4
  28. Synthesis and crystal structure of 3-(4,5-dihydroisoxazol-3-yl)-2-methyl-4-(methylsulfonyl)benzoic acid, C12H13NO5S
  29. The crystal structure of hexaaquamagnesium(II) bis-3-(1,2,3,4-tetrahydrobenzo[4,5]imidazo[1,2-α]pyridin-1-yl)benzoate, C36H42N4O10Mg
  30. Crystal structure of 4-formyl-2-methoxyphenyl 2-acetoxybenzoate, C17H14O6
  31. Crystal structure of poly[octakis(μ-oxido)-tris(μ-1,1′-[[1,1′-biphenyl]-4,4′-diylbis(methylene)]bis(1H-imidazole))-tetrakis(oxido)-tetra-vanadium-dimanganese(II)dihydrate], C30H29MnN6O7V2
  32. Crystal structure of 4,8a-bis(4-chlorophenyl)-1,5,6-tris(4-fluorobenzyl)-1,4,4a,4b,5,6,8a,8b-octahydrocyclobuta[1,2-b:3,4-c′]dipyridine-3,8-dicarbonitrile, C45H33Cl2F3N4
  33. Crystal structure of benzo[d][1,3]dioxol-5-ylmethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C22H20O5
  34. Crystal structure of N-benzoyl-N-phenylhydroxylaminato-dicarbonylrhodium(I), [Rh(BNA)CO2]
  35. The crystal structure of N-(2-((2-methoxynaphthalen-1-yl)ethynyl)phenyl)-4-methylbenzenesulfonamide, C26H21NO3S
  36. The crystal structure of methyl ((4-aminobenzyl)sulfonyl)-d-prolinate, C13H18N2O4S
  37. The crystal structure of dichlorido-(N-isopropyl-N-(pyridin-2-ylmethyl)propan-2-amine-κ 2 N, N′)palladium(II), C12H20N2PdCl2
  38. Crystal structure of poly[(μ 2-5-hydroxyisophthalato-κ4 O,O′:O″,O‴)-(μ 2-1,4-bis(2-methylimidazolyl)-1-butene-N:N′)nickel(II)], C20H20NiN4O5
  39. The crystal structure of {hexakis(1-methyl-1H-imidazole-κ 1 N)cobalt(II)}(μ 2-oxido)-hexaoxido-dimolybdenum(VI)— 1-methyl-1H-imidazole (1/2), C32H48CoMo2N16O7
  40. Synthesis, crystal structure and nonlinear optical property of 1-((propan-2-ylideneamino)oxy)propan-2-yl-4-methylbenzenesulfonate, C13H19O4NS
  41. The crystal structure of N,N-(ethane-1,1-diyl)dibenzamide, C16H16N2O2
  42. Crystal structure of 1-(4-bromophenyl)-3-(diphenylphosphoryl)-3-hydroxypropan-1-one, C21H18BrO3P
  43. The crystal structure of fac-tricarbonyl(bis(3,5-dimethyl-4H-pyrazole)-κ1 N)-((nitrato)-κ1 O)-rhenium(I)— 3,5-dimethyl-4H-pyrazole(1/1), C18H23N7O6Re
  44. The crystal structure of 4′-chloro-griseofulvin: (2S,6′R)-4′,7-dichloro-4,6-dimethoxy-6′-methyl-3H-spiro[benzofuran-2,1′-cyclohexan]-3′-ene-2′,3-dione, C16H14Cl2O5
  45. Crystal structure of tetraethylammonium bicarbonate–1-(diaminomethylene)thiourea(1/1)
  46. Crystal structure of 1-cyclohexyl-4-p-tolyl-1,4-dihydropyridine-3,5-dicarboxylic acid dimethyl ester, C22H27NO4
  47. The crystal structure of catena-poly(μ2-1,4-bis-(1H-imidazol-1-yl)benzene-copper(I)) dichloridocopper(I), {[CuC12H10N4]+[CuCl2]−} n
  48. The crystal structure of propane-1-aminium-2-carbamate, C4H10N2O2
  49. Crystal structure of 5,6,3′,4′,5′-pentamethoxy-flavone dihydrate, C20H24O9
  50. Crystal structure of (E)-N-(2-bromophenyl)-4-(4-(3,5-dimethoxystyryl)phenoxy)pyrimidin-2-amine, C26H22BrN3O3
  51. Crystal structure of methyl (3R)-1-(2-bromo-4-fluorophenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate hydrochloride hydrate, C19H19BrClFN2O3
  52. The crystal structure of 1-(2-chlorophenyl)-3-(p-tolyl)urea, C14H13ClN2O
  53. The crystal structure of 1-cyclohexyl-3-(p-tolyl)urea, C14H20N2O
  54. Crystal structure of ((benzyl(hydroxy)-amino)(4-chlorophenyl)methyl)-diphenylphosphine oxide, C26H23ClNO2P
  55. The crystal structure of ethyl 3-(1-methyl-1H-indole-2-carbonyl)-2-phenylquinoline-4-carboxylate, C28H22N2O3
  56. The crystal structure of 1,4-bis(1H-imidazol-3-ium-1-yl)benzene dinitrate, C12H12N4 2+·2(NO3 −)
  57. Crystal structure of tris(hexafluoroacetylacetonato-κ2O,O′) bis(triphenylphosphine oxide-κ1O)samarium(III), C51H33F18O8P2Sm
  58. Crystal structure of 1-(4-(dimethylamino)phenyl)-2,3-bis(diphenylphosphoryl)propan-1-one, C35H33NO3P2
  59. Crystal structure of diaqua[bis(μ 2-pyridine 2,6-dicarboxylato) bismuth(III) potassium(I)], C14H10BiKN2O10
  60. Crystal structure of (R)-N, N ′-dimethyl-[1, 1′-binaphthalene]-2, 2′-diamine, C22H20N2
  61. Crystal structure of 1-phenyl-4-(2-furoyl)-3-furyl-1H-pyrazol-5-ol, C18H12N2O4
  62. Crystal structure of bis(14,34-dimethyl[11,21:23,31-terphenyl]-22-yl)diselane, C40H34Se2
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