Experimental investigation and thermodynamic assessment of the Al–Ca–Y ternary system
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Ligang Zhang
,
Qian Song
Abstract
The experimental investigation and thermodynamic assessment of the Al–Ca–Y ternary system were carried out in this work. The isothermal section of the Al–Ca–Y ternary system at 673 K and 873 K was determined by using equilibrated alloys, combined with scanning electron microscopy, electron probe micro-analysis and powder X-ray diffractometry. Phase transition temperatures were measured by differential scanning calorimetry analysis. A certain range of solubility was detected between Al2Ca and Al2Y in this work, the maximum solid solubility of Y in Al2Ca was 11.9 at.% and that of Ca in Al2Y was 12.6 at.%. According to the thermodynamic data of binary systems in the literature and the ternary experimental data from this work and the literature, the Al–Ca–Y ternary system was optimized and a set of self-consistent thermodynamic parameters was obtained. Calculated phase equilibria were consistent with the experimental results.
Funding source: National Natural Science Foundation of China
Award Identifier / Grant number: Unassigned
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Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: The authors acknowledge the financial support from the National Natural Science Foundation of China (Grant No. 51871248), the National MCF Energy R&D Program of China (No. 2018YFE0306100), Natural Science Foundation of Hunan Province,China(Grant No. 2020JJ4739).
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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Articles in the same Issue
- Frontmatter
- Editorial
- Preface of the issue of the 19th national symposium on phase diagram and materials design
- Review
- Improvement of the thermoelectric properties of GeTe- and SnTe-based semiconductors aided by the engineering based on phase diagram
- Original Papers
- Diffusivities and atomic mobilities in the Ni-rich fcc Ni–Al–Cu alloys: experiment and modeling
- Composition-dependent interdiffusivity matrices of ordered bcc_B2 phase in ternary Ni–Al–Ru system at 1273∼1473 K
- Investigation of interdiffusion behavior in the Ti–Zr–Cu ternary system
- Measurement of the diffusion coefficient in Mg–Sn and Mg–Sc binary alloys
- Thermodynamic calculation of phase equilibria of rare earth metals with boron binary systems
- Thermodynamic modeling of the Bi–Ca and Bi–Zr systems
- Redetermination of the Fe–Pt phase diagram by using diffusion couple technique combined with key alloys
- Experimental determination of the isothermal sections and liquidus surface projection of the Mo–Si–V ternary system
- Experimental determination of isothermal sections of the Hf–Nb–Ni system at 950 and 1100 °C
- Experimental investigation and thermodynamic assessment of the Al–Ca–Y ternary system
- Phase equilibria of the Ni–Cr–Y ternary system at 900 °C
- Phase constituents near the center of the Co–Cr–Fe–Ni–Ti system at 1000 °C
- Metastable phase diagram of the Gd2O3–SrO–CoO x ternary system
- Crystallization kinetic and dielectric properties of CaO–MgO–Al2O3–SiO2 glass/Al2O3 composites
- Investigation of the phase relation of the Bi2O3–Fe2O3–Nd2O3 system at 973 K and the microwave absorption performance of NdFeO3/Bi25FeO40 with different mass ratios
- The influence of SrCl2 on the corrosion behavior of magnesium
- Retraction
- Retraction of: Electrolytic synthesis of ZrSi/ZrC nanocomposites from ZrSiO4 and carbon black powder in molten salt
- News
- DGM – Deutsche Gesellschaft für Materialkunde
Articles in the same Issue
- Frontmatter
- Editorial
- Preface of the issue of the 19th national symposium on phase diagram and materials design
- Review
- Improvement of the thermoelectric properties of GeTe- and SnTe-based semiconductors aided by the engineering based on phase diagram
- Original Papers
- Diffusivities and atomic mobilities in the Ni-rich fcc Ni–Al–Cu alloys: experiment and modeling
- Composition-dependent interdiffusivity matrices of ordered bcc_B2 phase in ternary Ni–Al–Ru system at 1273∼1473 K
- Investigation of interdiffusion behavior in the Ti–Zr–Cu ternary system
- Measurement of the diffusion coefficient in Mg–Sn and Mg–Sc binary alloys
- Thermodynamic calculation of phase equilibria of rare earth metals with boron binary systems
- Thermodynamic modeling of the Bi–Ca and Bi–Zr systems
- Redetermination of the Fe–Pt phase diagram by using diffusion couple technique combined with key alloys
- Experimental determination of the isothermal sections and liquidus surface projection of the Mo–Si–V ternary system
- Experimental determination of isothermal sections of the Hf–Nb–Ni system at 950 and 1100 °C
- Experimental investigation and thermodynamic assessment of the Al–Ca–Y ternary system
- Phase equilibria of the Ni–Cr–Y ternary system at 900 °C
- Phase constituents near the center of the Co–Cr–Fe–Ni–Ti system at 1000 °C
- Metastable phase diagram of the Gd2O3–SrO–CoO x ternary system
- Crystallization kinetic and dielectric properties of CaO–MgO–Al2O3–SiO2 glass/Al2O3 composites
- Investigation of the phase relation of the Bi2O3–Fe2O3–Nd2O3 system at 973 K and the microwave absorption performance of NdFeO3/Bi25FeO40 with different mass ratios
- The influence of SrCl2 on the corrosion behavior of magnesium
- Retraction
- Retraction of: Electrolytic synthesis of ZrSi/ZrC nanocomposites from ZrSiO4 and carbon black powder in molten salt
- News
- DGM – Deutsche Gesellschaft für Materialkunde
