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Investigation of the phase relation of the Bi2O3–Fe2O3–Nd2O3 system at 973 K and the microwave absorption performance of NdFeO3/Bi25FeO40 with different mass ratios

  • Jinxiang Guo , Chuang Tian , Qingrong Yao EMAIL logo , Zhaofei Tong , Qihua Liang , Jiang Wang EMAIL logo and Huaiying Zhou
Published/Copyright: April 29, 2022
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Abstract

The phase equilibrium relationship of the Bi2O3–Fe2O3–Nd2O3 system at 973 K was established by means of X-ray diffraction. The phase diagram contains 9 single-phase regions, 5 two-phase regions, 7 three-phase regions and no ternary compounds. There are three solid solutions of Bi1.446Nd0.554O3-type, R3c-BiFeO3 and Pnma-NdFeO3. The lattice parameters of the Nd1-xBi x O3 compound increase with increasing Bi2O3 content, but the XRD peaks shift to lower 2θ values when x is 0–0.75. The effect of different mass percentages of two phases, NdFeO3 and Bi25FeO40, on the performance of the sample is explored. When the mass percentage of the second phase Bi25FeO40 increases, the magnetic properties of the samples decrease instead. The sample with a mass ratio of 59 % Bi25FeO40 shows the best adsorption performance. The effective bandwidths of the samples are 2.12 GHz, 2.76 GHz and 2.25 GHz when the mass percentage of the second phase is 17 wt.%, 59 wt.%, and 77 wt.%, respectively.


Corresponding authors: Qingrong Yao and Jiang Wang, School of Materials Science and Engineering, Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin, 541004, P. R. China, E-mail: (Q. Yao), (J. Wang)

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work is financially supported by the National Natural Science Foundations of China (Grant Nos. 51871066, 51761007). Technology Base and Special Talents at Guangxi (Grant No. 2018AD19088).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-07-01
Revised: 2022-03-12
Accepted: 2022-03-03
Published Online: 2022-04-29
Published in Print: 2022-05-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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