Abstract
The performance of thermal barrier coatings (TBCs) in jet engines is strongly influenced by thermal and mechanical properties of the bond coat. In this investigation two different types of Pt-modified diffusion coatings developed for application as oxidation protection or as a bond coat in TBC systems were studied with respect to their microstructure and mechanical properties. The microstructural analyses based on different microscopy techniques and X-ray diffraction measurements revealed distinct differences between the two coatings: the coating aluminized by a gas phase process consisted solely of a (NiPt)Al phase, while the coating fabricated by pack-cementation consisted mainly of the two phases (NiPt)Al and Al2Pt, leading to a higher strength in comparison with the single-phase coating. In contrast, the ductility determined with 3-point bend tests between room temperature and 700 °C was clearly better for the single-phase coating. Additionally, the substrate curvature of coated sheets was measured to gain some information about coating stresses.
The authors thank Dr. E. Bischoff for the SEM/EDS measurements, the staff of the ZWE Röntgen at the MPI for Metals Research and S. Geupel (PML) for the performance of XRD experiments, P. Gruber for the help with the sin2 ψ method, N. Sauer for metallography and J. Haug from MTU Aero Engines for his support. MTU Aero Engines provided the specimen material. This work was partially funded by the CEC in the framework of the research project ORDICO.
References
[1] M.W. Chen, K.J.T. Livi, P.K. Wright, K.J. Hemker: Met. Mat. Transactions A 34 (2003) 2289.10.1007/s11661-003-0293-8Search in Google Scholar
[2] D. Pan, M.W. Chen, P.K. Wright, K.J. Hemker: Acta Mater. 51 (2003) 2205.10.1016/S1359-6454(03)00014-4Search in Google Scholar
[3] J.A. Haynes, M.J. Lance, B.A. Pint, I.G. Wright: Surface & Coatings Techn. 146 (2001) 140.10.1016/S0257-8972(01)01483-9Search in Google Scholar
[4] M.J. Stiger, N.M. Yanar, M.G. Topping, F.S. Pettit, G.H. Meier: Z. Metallkd. 90 (1999) 1069.10.1515/ijmr-1999-901218Search in Google Scholar
[5] M. Peters, C. Leyens, U. Schulz, W. Kaysser: Adv. Eng. Mater. 3 No. 4 (2001) 193.10.1002/1527-2648(200104)3:4<193::AID-ADEM193>3.0.CO;2-USearch in Google Scholar
[6] A.L. Purvis, B.M.Warnes: Surface & Coatings Techn. 146 (2001) 1.10.1016/S0257-8972(01)01362-7Search in Google Scholar
[7] W.D. Nix: Metallurgical Transactions A 20 (1989) 2217.10.1007/BF02666659Search in Google Scholar
[8] G.M. Pharr, W.C. Oliver, F.R. Brotzen: J. Mater. Res. 7 (1992) 613.10.1557/JMR.1992.0613Search in Google Scholar
[9] JCPDS No. 65-3199; NiAl (1937); International Center for Diffraction Data, Swathmore, Pennsylvania.Search in Google Scholar
[10] D.B. Miracle: Acta Met. Mater. 41 (1993) 649.10.1016/0956-7151(93)90001-9Search in Google Scholar
[11] JCPDS No. 45-027; Ni (1988); International Center for Diffraction Data, Swathmore, Pennsylvania.Search in Google Scholar
[12] JCPDS No. 44-1159; NiO (1992); International Center for Diffraction Data, Swathmore, Pennsylvania.Search in Google Scholar
[13] JCPDS No. 04-0806; W (1953); International Center for Diffraction Data, Swathmore, Pennsylvania.Search in Google Scholar
[14] JCPDS No. 35-0801; TaC (1984); International Center for Diffraction Data, Swathmore, Pennsylvania.Search in Google Scholar
[15] P. Wellner, G. Dehm, O. Kraft, E. Arzt: Z. Metallkd. 95 (2004) 769.10.3139/146.018020Search in Google Scholar
[16] E.E. Affeldt: Adv. Eng. Mat. 2 (2000) 811.10.1002/1527-2648(200012)2:12<811::AID-ADEM811>3.0.CO;2-YSearch in Google Scholar
[17] E.E. Affeldt: unpublished results.Search in Google Scholar
[18] M.W. Chen, R.T. Ott, T.C. Hufnagel, P.K. Wright, K.J. Hemker: Surface & Coatings Techn. 163 (2003) 25.10.1016/S0257-8972(02)00591-1Search in Google Scholar
© 2006 Carl Hanser Verlag, München
Articles in the same Issue
- Frontmatter
- Microstructure and mechanical behavior of Pt-modified NiAl diffusion coatings
- Evolution of C-rich SiOC ceramics
- Evolution of C-rich SiOC ceramics
- Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
- Thermodynamic analysis of structural transformations induced by annealing of amorphous Si–C–N ceramics derived from polymer precursors
- Thermodynamic modelling of the Ce–Ni system
- Thermodynamic assessment of the Ce–O system in solid state from 60 to 67 mol.% O
- Phase transformations of iron nitrides at low temperatures (< 700 K) – application of mechanical mixtures of powders of nitrides and iron
- Effect of organic self-assembled monolayers on the deposition and adhesion of hydroxyapatite coatings on titanium
- Reconstruction and structural transition at metal/diamond interfaces
- Microstructure, hardness, and fracture toughness evolution of hot-pressed SiC/Si3N4 nano/micro composite after high-temperature treatment
- High-temperature plasticity of SiC sintered with Lu2O3-AlN additives
- Interaction of functionalised surfaces on silica with dissolved metal cations in aqueous solutions
- XRD and TEM study of NiO–LSGM reactivity
- Microstructure and dielectric properties of nanoscale oxide layers on sintered capacitor-grade niobium and V-doped niobium powder compacts
- Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}
- Aqueous solution deposition of indium hydroxide and indium oxide columnar type thin films
- Thermodynamic properties of B2-AlFeNi alloys: modelling of the B2-AlFe and B2-AlNi phases
- Kinetics of precipitate formation in (TixWyCrz)B2 solid solutions: influence of Cr concentration and Co impurities
- On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)
- Out-of-pile chemical compatibility of Pb–Bi eutectic alloy with Graphite
- Microstructural characterisation of a Co–Cr–Mo laser clad applied on railway wheels
- The Na–H system: from first-principles calculations to thermodynamic modeling
- Personal
- Conferences
- Frontmatter
- Basic
- Microstructure and mechanical behavior of Pt-modified NiAl diffusion coatings
- Evolution of C-rich SiOC ceramics
- Evolution of C-rich SiOC ceramics
- Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
- Thermodynamic analysis of structural transformations induced by annealing of amorphous Si–C–N ceramics derived from polymer precursors
- Thermodynamic modelling of the Ce–Ni system
- Thermodynamic assessment of the Ce–O system in solid state from 60 to 67 mol.% O
- Phase transformations of iron nitrides at low temperatures (< 700 K) – application of mechanical mixtures of powders of nitrides and iron
- Effect of organic self-assembled monolayers on the deposition and adhesion of hydroxyapatite coatings on titanium
- Reconstruction and structural transition at metal/diamond interfaces
- Applied
- Microstructure, hardness, and fracture toughness evolution of hot-pressed SiC/Si3N4 nano/micro composite after high-temperature treatment
- High-temperature plasticity of SiC sintered with Lu2O3-AlN additives
- Interaction of functionalised surfaces on silica with dissolved metal cations in aqueous solutions
- XRD and TEM study of NiO–LSGM reactivity
- Microstructure and dielectric properties of nanoscale oxide layers on sintered capacitor-grade niobium and V-doped niobium powder compacts
- Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}
- Aqueous solution deposition of indium hydroxide and indium oxide columnar type thin films
- Thermodynamic properties of B2-AlFeNi alloys: modelling of the B2-AlFe and B2-AlNi phases
- Regular Articles
- Kinetics of precipitate formation in (TixWyCrz)B2 solid solutions: influence of Cr concentration and Co impurities
- On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)
- Out-of-pile chemical compatibility of Pb–Bi eutectic alloy with Graphite
- Microstructural characterisation of a Co–Cr–Mo laser clad applied on railway wheels
- The Na–H system: from first-principles calculations to thermodynamic modeling
- Notifications
- Personal
- Conferences
Articles in the same Issue
- Frontmatter
- Microstructure and mechanical behavior of Pt-modified NiAl diffusion coatings
- Evolution of C-rich SiOC ceramics
- Evolution of C-rich SiOC ceramics
- Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
- Thermodynamic analysis of structural transformations induced by annealing of amorphous Si–C–N ceramics derived from polymer precursors
- Thermodynamic modelling of the Ce–Ni system
- Thermodynamic assessment of the Ce–O system in solid state from 60 to 67 mol.% O
- Phase transformations of iron nitrides at low temperatures (< 700 K) – application of mechanical mixtures of powders of nitrides and iron
- Effect of organic self-assembled monolayers on the deposition and adhesion of hydroxyapatite coatings on titanium
- Reconstruction and structural transition at metal/diamond interfaces
- Microstructure, hardness, and fracture toughness evolution of hot-pressed SiC/Si3N4 nano/micro composite after high-temperature treatment
- High-temperature plasticity of SiC sintered with Lu2O3-AlN additives
- Interaction of functionalised surfaces on silica with dissolved metal cations in aqueous solutions
- XRD and TEM study of NiO–LSGM reactivity
- Microstructure and dielectric properties of nanoscale oxide layers on sintered capacitor-grade niobium and V-doped niobium powder compacts
- Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}
- Aqueous solution deposition of indium hydroxide and indium oxide columnar type thin films
- Thermodynamic properties of B2-AlFeNi alloys: modelling of the B2-AlFe and B2-AlNi phases
- Kinetics of precipitate formation in (TixWyCrz)B2 solid solutions: influence of Cr concentration and Co impurities
- On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)
- Out-of-pile chemical compatibility of Pb–Bi eutectic alloy with Graphite
- Microstructural characterisation of a Co–Cr–Mo laser clad applied on railway wheels
- The Na–H system: from first-principles calculations to thermodynamic modeling
- Personal
- Conferences
- Frontmatter
- Basic
- Microstructure and mechanical behavior of Pt-modified NiAl diffusion coatings
- Evolution of C-rich SiOC ceramics
- Evolution of C-rich SiOC ceramics
- Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
- Thermodynamic analysis of structural transformations induced by annealing of amorphous Si–C–N ceramics derived from polymer precursors
- Thermodynamic modelling of the Ce–Ni system
- Thermodynamic assessment of the Ce–O system in solid state from 60 to 67 mol.% O
- Phase transformations of iron nitrides at low temperatures (< 700 K) – application of mechanical mixtures of powders of nitrides and iron
- Effect of organic self-assembled monolayers on the deposition and adhesion of hydroxyapatite coatings on titanium
- Reconstruction and structural transition at metal/diamond interfaces
- Applied
- Microstructure, hardness, and fracture toughness evolution of hot-pressed SiC/Si3N4 nano/micro composite after high-temperature treatment
- High-temperature plasticity of SiC sintered with Lu2O3-AlN additives
- Interaction of functionalised surfaces on silica with dissolved metal cations in aqueous solutions
- XRD and TEM study of NiO–LSGM reactivity
- Microstructure and dielectric properties of nanoscale oxide layers on sintered capacitor-grade niobium and V-doped niobium powder compacts
- Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}
- Aqueous solution deposition of indium hydroxide and indium oxide columnar type thin films
- Thermodynamic properties of B2-AlFeNi alloys: modelling of the B2-AlFe and B2-AlNi phases
- Regular Articles
- Kinetics of precipitate formation in (TixWyCrz)B2 solid solutions: influence of Cr concentration and Co impurities
- On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)
- Out-of-pile chemical compatibility of Pb–Bi eutectic alloy with Graphite
- Microstructural characterisation of a Co–Cr–Mo laser clad applied on railway wheels
- The Na–H system: from first-principles calculations to thermodynamic modeling
- Notifications
- Personal
- Conferences