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Bio-based polyurethane aqueous dispersions

  • Xing Zhou EMAIL logo , Xin Zhang , Pu Mengyuan , Xinyu He and Chaoqun Zhang EMAIL logo
Published/Copyright: April 19, 2021
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Abstract

With the advances of green chemistry and nanoscience, the synthesis of green, homogenous bio-based waterborne polyurethane (WPU) dispersions with high performance have gained great attention. The presented chapter deals with the recent synthesis of waterborne polyurethane with the biomass, especially the vegetable oils including castor oil, soybean oil, sunflower oil, linseed oil, jatropha oil, and palm oil, etc. Meanwhile, the other biomasses, such as cellulose, starch, lignin, chitosan, etc., have also been illustrated with the significant application in preparing polyurethane dispersions. The idea was to highlight the main vegetable oil-based polyols, and the isocyanate, diols as chain extenders, which have supplied a class of raw materials in WPU. The conversion of biomasses into active chemical agents, which can be used in synthesis of WPU, has been discussed in detail. The main mechanisms and methods are also presented. It is suggested that the epoxide ring opening method is still the main route to transform vegetable oils to polyols. Furthermore, the nonisocyanate WPU may be one of the main trends for development of WPU using biomasses, especially the abundant vegetable oils.


Corresponding authors: Xing Zhou, PhD, Faculty of Printing, Packaging Engineering and Digital Media Technology, Xi’an University of Technology, Xi’an 710048, P. R. China; and School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, P. R. China; and Chaoqun Zhang, College of Materials and Energy, South China Agricultural University, Guangzhou 510642, P. R. China, E-mail: (X. Zhou), (C. Zhang)

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 51802259

Funding source: Natural Science Foundation of Shaanxi

Award Identifier / Grant number: 2019JQ-510

Funding source: Xi’an Beilin District Programs for Science and Technology Plan

Award Identifier / Grant number: 201805037YD15CG21(18), GX1913

Funding source: Promotion Program for Youth of Shaanxi University Science and Technology Association

Award Identifier / Grant number: 20190415

Funding source: Fund of Key laboratory of Processing and Quality Evaluation Technology of Green Plastics of China National Light Industry Council

Award Identifier / Grant number: PQETGP2019003

Funding source: Ph.D. Start-Up Fund Project

Award Identifier / Grant number: 108-451118001

Funding source: Xi’an University of Technology

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors acknowledge the financial support provided by the National Natural Science Foundation of China [Grant No. 51802259], the Natural Science Foundation of Shaanxi [Grant No. 2019JQ-510], Xi’an and Xi’an Beilin District Programs for Science and Technology Plan [Grant No. 201805037YD15CG21(18) and GX1913], the Promotion Program for Youth of Shaanxi University Science and Technology Association [Grant No. 20190415], Fund of Key laboratory of Processing and Quality Evaluation Technology of Green Plastics of China National Light Industry Council [Grant No. PQETGP2019003], the Ph.D. Start-Up Fund Project [Grant No. 108-451118001] of Xi’an University of Technology.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Published Online: 2021-04-19

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Reviews
  3. Magnetic characterization of magnetoactive elastomers containing magnetic hard particles using first-order reversal curve analysis
  4. Microscopic understanding of particle-matrix interaction in magnetic hybrid materials by element-specific spectroscopy
  5. Biodeinking: an eco-friendly alternative for chemicals based recycled fiber processing
  6. Bio-based polyurethane aqueous dispersions
  7. Cellulose-based polymers
  8. Biodegradable shape-memory polymers and composites
  9. Natural substances in cancer—do they work?
  10. Personalized and targeted therapies
  11. Identification of potential histone deacetylase inhibitory biflavonoids from Garcinia kola (Guttiferae) using in silico protein-ligand interaction
  12. Chemical computational approaches for optimization of effective surfactants in enhanced oil recovery
  13. Social media and learning in an era of coronavirus among chemistry students in tertiary institutions in Rivers State
  14. Techniques for the detection and quantification of emerging contaminants
  15. Occurrence, fate, and toxicity of emerging contaminants in a diverse ecosystem
  16. Updates on the versatile quinoline heterocycles as anticancer agents
  17. Trends in microbial degradation and bioremediation of emerging contaminants
  18. Power to the city: Assessing the rooftop solar photovoltaic potential in multiple cities of Ecuador
  19. Phytoremediation as an effective tool to handle emerging contaminants
  20. Recent advances and prospects for industrial waste management and product recovery for environmental appliances: a review
  21. Integrating multi-objective superstructure optimization and multi-criteria assessment: a novel methodology for sustainable process design
  22. A conversation on the quartic equation of the secular determinant of methylenecyclopropene
  23. Recent developments in the synthesis and anti-cancer activity of acridine and xanthine-based molecules
  24. An overview of in silico methods used in the design of VEGFR-2 inhibitors as anticancer agents
  25. Fragment based drug design
  26. Advances in heterocycles as DNA intercalating cancer drugs
  27. Systems biology–the transformative approach to integrate sciences across disciplines
  28. Pharmaceutical interest of in-silico approaches
  29. Membrane technologies for sports supplementation
  30. Fused pyrrolo-pyridines and pyrrolo-(iso)quinoline as anticancer agents
  31. Membrane applications in the food industry
  32. Membrane techniques in the production of beverages
  33. Statistical methods for in silico tools used for risk assessment and toxicology
  34. Dicarbonyl compounds in the synthesis of heterocycles under green conditions
  35. Green synthesis of triazolo-nucleoside conjugates via azide–alkyne C–N bond formation
  36. Anaerobic digestion fundamentals, challenges, and technological advances
  37. Survival is the driver for adaptation: safety engineering changed the future, security engineering prevented disasters and transition engineering navigates the pathway to the climate-safe future
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