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Trace element partitioning between olivine and melt in lunar basalts

  • Sha Chen , Peng Ni , Youxue Zhang ORCID logo und Joel Gagnon
Veröffentlicht/Copyright: 27. Juli 2022
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Abstract

Mineral/melt partition coefficients have been widely used to provide insights into magmatic processes. Olivine is one of the most abundant and important minerals in the lunar mantle and mare basalts. Yet, no systematic olivine/melt partitioning data are available for lunar conditions. We report trace element partition data between host mineral olivine and its melt inclusions in lunar basalts. Equilibrium is evaluated using the Fe-Mg exchange coefficient, leading to the choice of melt inclusion-host olivine pairs in lunar basalts 12040, 12009, 15016, 15647, and 74235. Partition coefficients of 21 elements (Li, Mg, Al, Ca, Ti, V, Cr, Mn, Fe, Co, Y, Zr, Nb, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) were measured. Except for Li, V, and Cr, these elements show no significant difference in olivine-melt partitioning compared to the data for terrestrial samples. The partition coefficient of Li between olivine and melt in some lunar basalts with low Mg# (Mg# < 0.75 in olivine, or < ~0.5 in melt) is higher than published data for terrestrial samples, which is attributed to the dependence of DLi on Mg# and the lack of literature DLi data with low Mg#. The partition coefficient of V in lunar basalts is measured to be 0.17 to 0.74, significantly higher than that in terrestrial basalts (0.003 to 0.21), which can be explained by the lower oxygen fugacity in lunar basalts. The significantly higher DV can explain why V is less enriched in evolved lunar basalts than terrestrial basalts. The partition coefficient of Cr between olivine and basalt melt in the Moon is 0.11 to 0.62, which is lower than those in terrestrial settings by a factor of ~2. This is surprising because previous authors showed that Cr partition coefficient is independent of fO2. A quasi-thermodynamically based model is developed to correlate Cr partition coefficient to olivine and melt composition and fO2. The lower Cr partition coefficient between olivine and basalt in the Moon can lead to more Cr enrichment in the lunar magma ocean, as well as more Cr enrichment in mantle-derived basalts in the Moon. Hence, even though Cr is typically a compatible element in terrestrial basalts, it is moderately incompatible in primitive lunar basalts, with a similar degree of incompatibility as V based on partition coefficients in this work, as also evidenced by the relatively constant V/Cr ratio of 0.039 ± 0.011 in lunar basalts. The confirmation of constant V/Cr ratio is important for constraining concentrations of Cr (slightly volatile and siderophile) and V (slightly siderophile) in the bulk silicate Moon.

Acknowledgments and Funding

We thank Dante Danil and an anonymous reviewer for their constructive reviews, which significantly improved this paper. This work was supported by NASA grant NNX15AH37G and 80NSSC19K0782, and NSF grants EAR-1829822 and EAR-2020603. We thank NASA CAPTEM for providing the lunar samples, K.P. Jochum for providing the MPI-DING glass standards, J.C. Barrette for assistance in LA-ICP-MS analyses, and Yunbin Guan for assistance in SIMS analyses. The electron microprobe Cameca SX100 used in this study was purchased using NSF grant EAR-9911352.

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Received: 2021-01-13
Accepted: 2021-07-29
Published Online: 2022-07-27
Published in Print: 2022-08-26

© 2022 Mineralogical Society of America

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