Band 12, Heft 21

Optical image sensors are 2D arrays of pixels that integrate semiconductor photodiodes and field effect transistors for efficient photon conversion and processing of generated electrons. With technological advancements and subsequent democratization of these sensors, opportunities for integration with microfluidics devices are currently explored. 2D pixel arrays of such optical image sensors can reach dimensions larger than one centimeter with a sub-micrometer pixel size, for high spatial resolution lensless imaging with large field of view, a feat that cannot be achieved with lens-based optical microscopy. Moreover, with advancements in fabrication processes, the field of microfluidics has evolved to develop microfluidic devices with an overall size below one centimeter and individual components of sub-micrometer size, such that they can now be implemented onto optical image sensors. The convergence of these fields is discussed in this article, where we review fundamental principles, opportunities, challenges, and outlook for integration, with focus on contact-mode imaging configuration. Most recent developments and applications of microfluidic lensless contact-based imaging to the field of biosensors, in particular those related to the potential for point of need applications, are also discussed.

We numerically investigate second harmonic generation (SHG) from a monolayer of 2D-material placed on photonic moiré superlattice fabricated by dielectric materials. The greatly enhanced local field at the resonance modes of moiré superlattice can dramatically boost the SHG response in 2D materials. Considering a typical 2D-material MoS 2 monolayer placed on a photonic moiré superlattice of a twist angle 9.43°, the maximum SHG conversion efficiency reaches up to 10 −1 at a relatively low intensity of fundamental light 1 kW/cm 2 , which is around 14 orders of magnitude larger than that from the monolayer placed on a flat dielectric slab without moiré superlattices. The SHG conversion efficiency from the monolayer can be further enhanced with the decrease of the twist angles of moiré superlattice due to the even more confinement of local field. The flat bands in the moiré superlattices formed by the small twist angles can particularly ensure the efficiency even under wide-angle illuminations. The results indicate that photonic moiré superlattice which can tightly confine light is a promising platform for efficient nonlinear optics.

The current approach to 2D optical phased array (OPA) encounters challenges, such as the requirement for a highly tunable laser that is incompatible with certain 2D beam-steering applications or significant power consumption, large antenna spacing and complex wiring resulting from independent control of array elements. To address these challenges, we propose an OPA architecture based on cascaded periodically poled LiNbO 3 sequences, a multi-layered domains engineered structure within the LiNbO 3 electro-optic crystal, only two control electronics to program the 2D beam-steering trajectory with a range of approximately θ y = ±20° and θ z = ±16° through simulations. This structure enables the uniform distribution of phase differences between adjacent array elements (adjacent domains) upon beam exit from the crystal, ensuring optimal performance. The aim of this study is to develop a methodology that employs domain engineering techniques for designing high-performance phase-controlled devices with customized functional units and sequences in electro-optical crystals. Our research has implications for emerging optoelectronic applications, such as customizable optical interconnects and integrated LiDAR systems.

Tip-enhanced Raman spectroscopy (TERS) has recently been developed to push the spatial resolution down to single-chemical-bond scale. The morphology of the scanning tip, especially the atomistic protrusion at the tip apex, plays an essential role in obtaining both high spatial resolution and large field enhancement at the Ångström level. Although it is very difficult to directly characterize the atomistic structures of the tip, the Raman scattering from the apex’s own vibrations of the metal tip can provide valuable information about the stacking of atoms at the tip apex. However, conventional quantum chemistry packages can only simulate the Raman scattering of small metal clusters with few atoms due to huge computational cost, which is not enough since the shaft of the tip behind the apex also makes significant contributions to the polarizabilities of the whole tip. Here we propose an atomistic polarization model to simulate the Raman spectra of large metal tips at subwavelength scales based on the combination of the atomistic discrete dipole approximation model and the density functional theory. The atomistic tip with different sizes and stacking structures is considered in its entirety during the calculation of polarizabilities, and only the vibrational contributions from the tip apex are taken into account to simulate the Raman spectra of the tip. The Raman spectral features are found to be very sensitive to the local constituent element at the tip apex, atomic stacking modes, and shape of the tip apex, which can thus be used as a fingerprint to identify different atomistic structures of the tip apex. Moreover, our approaches can be extended to the metal tips with sub-wavelength sizes, making it possible to consider both the large scale and the atomistic detail of the tip simultaneously. The method presented here can be used as a basic tool to simulate the Raman scattering process of the metal tips and other nanostructures in an economic way, which is beneficial for understanding the roles of atomistic structures in tip- and surface-enhanced spectroscopies.

Chiral metasurfaces have great potential in various applications such as polarimetric imaging and biomedical recognition. However, simultaneous broadband and high circular dichroism (CD) with high polarization extinction ratio (PER) remains a challenge. Here, we present a novel approach to realize simultaneous broadband and high CD with high PER in the optical communication band using a two-dimensional all-dielectric chiral metasurface. The structure is formed by a two-level chiral structure of split cross (first-order) and trapezoid-shaped (second-order) of Si nano ribs, respectively, in which constructively coupled first- and second-order of chirality occurs, resulting in the broad chiral response in the far field of multipoles excited by incident light of different chiralities. Theoretical results show that a CD in transmission reaching 0.9 (up to 0.993) and a PER exceeding 20 dB (up to 35 dB) over the entire wavelength range from 1.39 to 1.61 μm can be achieved simultaneously, consistent with the experimental results of CD ∼0.9 and PER of 10 dB (up to 19.7 dB). Our design paves the way for chiral metasurfaces toward practical applications in terms of working bandwidth, high CD and PER as well as integrality of the devices in many fields.

miRNAs are small non-coding RNA molecules which serve as promising biomarkers due to their important roles in the development and progression of various cancer types. The detection of miRNAs is of vital importance to the early-stage diagnostics and prognostics of multiple diseases. However, traditional detection strategies have faced some challenges owing to the intrinsic characteristics of miRNAs including small size, short sequence length, low concentration level and high sequence homology in complex real samples. To overcome these challenges, we proposed a MXene-enhanced plasmonic biosensor for real-time and label-free detection of miRNA. By utilizing MXene nanomaterial which possesses unique characteristics including large surface area and strong carrier confinement abilities, we tuned the absorption of our plasmonic sensing substrate to reach a “zero-reflection” state and induced an extremely sharp phase change at the resonance angle. Combined with the sensing mechanism based on phase-induced lateral displacement measurement, this MXene-enhanced plasmonic biosensor can achieve a much superior sensing performance compared to traditional SPR devices. Based on this biosensing scheme, the ultrasensitive detection of target miRNA with a detection limit down to 10 fM has been successfully demonstrated. More importantly, single-base mismatched miRNA can be easily distinguished from the target miRNA according to the sensing signal. Furthermore, our plasmonic biosensor is capable of detecting miRNA in complex media such as 100 % human serum samples without compromising the detection sensitivity. This MXene-enhanced plasmonic sensing scheme has the ability of detecting miRNAs with extremely low concentration levels in complex surrounding media without the need of introducing extra labels or amplification tags, which holds great potential in various biological applications and clinical diagnostics.

Negative refraction has a wide range of applications in diverse fields such as imaging, sensing, and waveguides and typically entails the fabrication of intricate metamaterials endowed with hyperbolic features. In contrast to artificially engineered hyperbolic materials, natural van der Waals (vdW) materials are more accessible owing to their inherent strong in-plane covalent bonding and weak interlayer interactions. However, most vdW materials manifest uniaxial crystal properties, which restrict their behavior solely to out-of-plane hyperbolicity. This characteristic poses a considerable challenge to their seamless integration via planar fabrication techniques, unless a suitable pattern is employed. Recent advances have identified natural biaxial α -MoO 3 as a promising vdW material capable of exhibiting in-plane hyperbolicity. In this study, we performed numerical simulations demonstrating that negative refraction could be achieved by interfacing differently oriented α -MoO 3 slabs coated with tunable graphene on a gold substrate. Our comprehensive analysis yielded three notable outcomes: negative refraction, simultaneous positive and negative refractions, and diffractionless propagation. These outcomes could be operated in a broad range of frequencies and achieved at all angles to offer a superior platform for the flexible manipulation of mid-infrared polaritons. Our findings provide valuable insights into the potential application of other two-dimensional vdW materials for advances in nanoscale super-resolution imaging, molecular sensing, and on-chip photonic integrated circuits.

The intriguing properties of polaritons resulting from strong and ultrastrong light–matter coupling have been extensively investigated. However, most research has focused on spectroscopic characteristics of polaritons, such as their eigenfrequencies and Rabi splitting. Here, we study the decay rates of a plasmon–microcavity system in the strong and ultrastrong coupling regimes experimentally and numerically. We use a classical scattering matrix approach, approximating our plasmonic system with an effective Lorentz model, to obtain the decay rates through the imaginary part of the complex quasinormal mode eigenfrequencies. Our classical model automatically includes all the interaction terms necessary to account for ultrastrong coupling without dealing with the rotating-wave approximation and the diamagnetic term. We find an asymmetry in polaritonic decay rates, which deviate from the expected average of the uncoupled system’s decay rates at zero detuning. Although this phenomenon has been previously observed in exciton–polaritons and attributed to their disorder, we observe it even in our homogeneous system. As the coupling strength of the plasmon–microcavity system increases, the asymmetry also increases and can become so significant that the lower (upper) polariton decay rate reduction (increase) goes beyond the uncoupled decay rates, γ − < γ 0, c < γ + . Furthermore, our findings demonstrate that polaritonic linewidth asymmetry is a generic phenomenon that persists even in the case of bulk polaritons.

Wavelength switchable microcavity is indispensable component for various integrated photonic devices. However, achieving two wavelength band emission of the whispering gallery mode (WGM) laser is challenging. Here, we propose a strategy to realize two wavelength band emission WGM lasers activated by photo-isomerization based on excited-state intramolecular proton transfer (ESIPT) process in isolated/coupled polymer microfiber cavities. The WGM microcavity is built by highly polarized organic intramolecular charge-transfer (ICT) dye molecules. The two cooperative gain states of ICT dye molecules can be controlled by optimizing energy levels. Thereby, the lasing wavelength can be reversibly switched under photo-isomerization activated in the ESIPT energy-level progress. The photonic bar code can be generated by following the strategy of proposed design. This work provides a promising route to achieve switchable WGM laser in on-chip photonic integration.

We propose two designs of low-loss and temperature-insensitive single-mode waveguide crossing on silicon-on-insulator (SOI) platform with 415-nm operation bandwidth covering all optical communication bands. Both designs are enabled by subwavelength grating (SWG) modeled as an anisotropic metamaterial. The initial design applies straight SWG as the lateral cladding of the waveguide crossing to minimize the refractive index contrast and reduce the insertion loss (IL), but needs a relatively long taper. An improved design is then proposed where the curved SWG is introduced to replace the straight SWG to decrease the taper length and improve the performance. The waveguide crossing with the improved design achieves a calculated maximum IL of 0.229 dB and maximum crosstalk of −35.6 dB over a 415-nm wavelength range from 1260 nm to 1675 nm. The proposed devices are fabricated and characterized. Measured results of the improved design show a maximum IL of 0.264 dB and maximum crosstalk of −30.9 dB over a 230-nm wavelength range including O-, C-, and L-bands, which accord well with the simulation. Low temperature sensitivity has also been demonstrated in both simulations and experiments.

Chaotic semiconductor lasers have been widely investigated for high-speed random bit generation, which is applied for the generation of cryptographic keys for classical and quantum cryptography systems. Here, we propose and demonstrate a self-chaotic microlaser with enhanced chaotic bandwidth for high-speed random bit generation. By designing tri-mode interaction in a deformed square microcavity laser, we realize a self-chaotic laser caused by two-mode internal interaction, and achieve an enhanced chaotic standard bandwidth due to the photon–photon resonance effect by introducing the third mode. Moreover, 500 Gb/s random bit generation is realized and the randomness is verified by the NIST SP 800-22 statistics test. Our demonstration promises the applications of microlasers in secure communication, chaos radar, and optical reservoir computing, and also provides a platform for the investigations of multimode nonlinear laser dynamics.

Luminescent solar concentrators (LSCs) are attractive for the easy operation and high compatibility with building integrated photovoltaics due to their low cost, large-scale and applicability. However, underutilized sunlight in visible wavelengths often impedes the advance of LSCs. Here, we demonstrate an orange-emitting carbon nanodots-based LSC (O-CDs) with excitation concentrated in the visible wavelengths. The orange-emitting carbon nanodots (O-CDs) with highly localized excitonic emission are prepared via atomic condensation of doped pyrrolic nitrogen, delivering a high photoluminescence quantum yield of 80 % and a suitable Stokes shift with absorption spectrum situated in the visible region. The O-CDs are embedded in polyvinylpyrrolidone to obtain a highly transparent, stable and environmentally friendly O-CDs-based LSC. Thanks to efficient utilization of solar radiation in visible areas and well match between the emission of O-CDs and the response bands of photovoltaic cells, the O-CDs-based LSC reveals an optical conversion efficiency of 5.17 %, superior to that of most carbon nanodots-based LSCs. These results provide an effective strategy to develop carbon-based luminescent concentrated materials for architectural integrated photovoltaic technology.