Volume 11, Issue 10

Plasmonic optical tweezers that stem from the need to trap and manipulate ever smaller particles using non-invasive optical forces, have made significant contributions to precise particle motion control at the nanoscale. In addition to the optical forces, other effects have been explored for particle manipulation. For instance, the plasmonic heat delivery mechanism generates micro- and nanoscale optothermal hydrodynamic effects, such as natural fluid convection, Marangoni fluid convection and thermophoretic effects that influence the motion of a wide range of particles from dielectric to biomolecules. In this review, a discussion of optothermal effects generated by heated plasmonic nanostructures is presented with a specific focus on applications to optical trapping and particle manipulation. It provides a discussion on the existing challenges of optothermal mechanisms generated by plasmonic optical tweezers and comments on their future opportunities in life sciences.

The polarization of light is crucial for numerous optical applications ranging from quantum information processing to biomedical sensing due to the fundamental role of polarization as another intrinsic characteristic of optical waves, which is uncorrelated with the amplitude, phase, and frequency. However, conventional optical waveplates that enable polarization control are based on the accumulated retardation between two orthogonally polarized electric fields when light propagates a distance much larger than its wavelength in birefringent materials, resulting in bulky configurations and limited functionalities. Optical metasurfaces, ultrathin arrays of engineered meta-atoms, have attracted increasing attention owing to their unprecedented capabilities of manipulating light with surface-confined configurations and subwavelength spatial resolutions, thereby opening up new possibilities for revolutionizing bulky optical waveplates with ultrathin planar elements that feature compactness, integration compatibility, broadband operation bandwidths, and multiple functionalities. Herein, we review the recent progress in metasurface-enabled optical waveplates, which covers both basic principles and emerging applications. We provide an overview of metasurface-based conventional half- and quarter-waveplates as well as their use in wavefront shaping applications, followed by a discussion of advanced waveplates, including multifunctional waveplates and all-polarization generators. We also discuss dynamic waveplates based on active metasurfaces. Finally, we conclude by providing our outlook in this emerging and fast-growing research field.

The nonlinear optical properties of silicon have great potentials for developing all-optical switches and modulators, etc. Strategies based on all dielectric silicon photonic crystals and resonators have been proposed to design the nanophotonic devices with high nonlinearity. Nevertheless, the lack of compatible configuration with the mature CMOS technology may hinder the practical applications of the all dielectric devices. In this work, we proposed a metal–silicon hybrid metasurface to generate strong third harmonic signals from an amorphous silicon (α-Si) film. By integrating the α-Si film into a gold plasmonic nanocavity and controlling the periods of the gold meta-atoms, the efficiency of the THG process is expected to be greatly boosted. Compared to the planar α-Si film, the THG signal is enhanced by a factor of ∼370. The presented results in this work may open new routes for developing various silicon photonic devices with high optical nonlinearity.

Fenestrations in liver sinusoidal endothelial cells (LSEC) are transcellular nanopores of 50–350 nm diameter that facilitate bidirectional transport of solutes and macromolecules between the bloodstream and the parenchyma of the liver. Liver diseases, ageing, and various substances such as nicotine or ethanol can negatively influence LSECs fenestrations and lead to defenestration. Over the years, the diameter of fenestrations remained the main challenge for imaging of LSEC in vitro . Several microscopy, or rather nanoscopy, approaches have been used to quantify fenestrations in LSEC to assess the effect of drugs and, and toxins in different biological models. All techniques have their limitations, and measurements of the “true” size of fenestrations are hampered because of this. In this study, we approach the comparison of different types of microscopy in a correlative manner. We combine scanning electron microscopy (SEM) with optical nanoscopy methods such as structured illumination microscopy (SIM) or stimulated emission depletion (STED) microscopy. In addition, we combined atomic force microscopy (AFM) with SEM and STED, all to better understand the previously reported differences between the reports of fenestration dimensions. We conclude that sample dehydration alters fenestration diameters. Finally, we propose the combination of AFM with conventional microscopy that allows for easy super-resolution observation of the cell dynamics with additional chemical information that can be traced back for the whole experiment. Overall, by pairing the various types of imaging techniques that provide topological 2D/3D/label-free/chemical information we get a deeper insight into both limitations and strengths of each type microscopy when applied to fenestration analysis.

Plasmonic nanoantennas have the ability to confine and enhance incident electromagnetic fields into very sub-wavelength volumes, while at the same time efficiently radiating energy to the far-field. These properties have allowed plasmonic nanoantennas to be extensively used for exciting quantum emitters—such as molecules and quantum dots—and also for the extraction of photons from them for measurements in the far-field. Due to electromagnetic reciprocity, it is expected that plasmonic nanoantennas radiate energy as efficiently as an external source can couple energy to them. In this paper, we adopt a multipole expansion (Mie theory) and numerical simulations to show that although reciprocity holds, certain plasmonic antennas radiate energy much more efficiently than one can couple energy into them. This work paves the way towards designing plasmonic antennas with specific properties for applications where the near-to-far-field relationship is of high significance, such as: surface-enhanced Raman spectroscopy, strong coupling at room temperature, and the engineering of quantum states in nanoplasmonic devices.

Projection photolithography using an extreme-ultraviolet light source is the core technology that has enabled patterning on the scale of a few nanometers that is required for modern electronic chips. However, this high-end system is neither affordable nor needed for photonics where critical feature sizes are of 100s of nanometers (or of submicron). Although electron-beam lithography can provide a means for photonic device fabrication, it suffers from extremely low throughput. Therefore, a lithographic technique for submicron pattern generation at high throughput and low cost is in high demand. This group recently showed that maskless digital photolithography (MDPL), a convenient and versatile photolithographic technique that requires no photomask, could potentially address this demand by demonstrating photonic crystal (PhC) patterns with submicron periodicity and associated PhC band-edge lasers. In this paper, we report the fabrication of a PhC L3 cavity laser, which contains irregular air holes in terms of their positions and sizes, using the MDPL technique. Successful generation of such an aperiodic and nontrivial submicron pattern requires thorough understanding and scrupulous manipulation on light diffraction. Our achievements should provide the concrete foundation upon which compact, versatile, convenient, speedy, and economical lithographic tools for arbitrary submicron pattern generation can be developed.

As the key element for optical systems, polarization controllers with versatile functionalities are highly desired. Here, a CMOS-compatible polarization switch is proposed and realized by using a Mach–Zehnder interferometer integrated with two polarization-dependent mode converters (PDMCs) at the input/output ends. The PDMCs, which utilize the mode hybridness and adiabatic mode evolution in a silicon-on-insulator (SOI) ridge waveguide taper, provide a low-loss adiabatic transmission for the launched TE 0 mode as well as efficient mode conversion from the launched TM 0 mode to the TE 1 mode. For the MZI structure, there are two 1 × 2 dual-mode 3-dB power splitters based on a triple-core adiabatic taper, and two thermally-tunable phase-shifters embedded in the arms. The polarization state and the polarization extinction ratio (PER) of the transmitted light can be dynamically tuned by introducing some phase difference between the MZI arms electrically. The fabricated device has an excess loss of ∼0.6 dB for the TE 0 and TM 0 modes. When the switch is off, the TE 0 and TM 0 modes go through the device without exchange. In contrast, when the switch is on, the TE 0 –TM 0 conversion occurs and the measured PER is about 20 dB.

Laser-induced transformations of plasmonic metasurfaces pave the way for controlling their anisotropic optical response with a micrometric resolution over large surfaces. Understanding the transient state of matter is crucial to optimize laser processing and reach specific optical properties. This article proposes an experimental and numerical study to follow and explain the diverse irreversible transformations encountered by a random plasmonic metasurface submitted to multiple femtosecond laser pulses at a high repetition rate. A pump-probe spectroscopic imaging setup records pulse after pulse, and with a nanosecond time resolution, the polarized transmission spectra of the plasmonic metasurface, submitted to 50,000 ultrashort laser pulses at 75 kHz. The measurements reveal different regimes, occurring in different ranges of accumulated pulse numbers, where successive self-organized embedded periodic nanostructures with very different periods are observed by post-mortem electron microscopy characterizations. Analyses are carried out; thanks to laser-induced temperature rise simulations and calculations of the mode effective indices that can be guided in the structure. The overall study provides a detailed insight into successive mechanisms leading to shape transformation and self-organization in the system, their respective predominance as a function of the laser-induced temperature relative to the melting temperature of metallic nanoparticles and their kinetics. The article also demonstrates the dependence of the self-organized period on the guided-mode effective index, which approaches a resonance due to system transformation. Such anisotropic plasmonic metasurfaces have a great potential for security printing or data storage, and better understanding their formation opens the way to smart optimization of their properties.

The generation of optical pulse trains from continuous-wave light has attracted growing attention in recent years because it provides a simple way to obtain high repetition rate ultrashort pulses. While pulse generation has been extensively demonstrated in optical fibers, pulse train generation from weak, continuous wave light in photonic chips has posed significant challenges because of the short interaction length and therefore difficulty in acquiring sufficient new frequency content, and/or absence of the appropriate dispersion environment. In this manuscript, we report the pulse train generation of a low continuous-wave signal to 18 ps, by leveraging cross-phase modulation induced by co-propagating pump pulses with a peak power of 3.7 W in an ultra-silicon-rich nitride grating. The pulse train generation dynamics are documented both experimentally and theoretically to arise from cross-phase modulation-induced generation of new spectral content, and dispersive re-phasing. This is a new approach in which picosecond pulse generation may be achieved from low power, continuous-wave light.

The recent discovery of natural biaxial hyperbolicity in van der Waals crystals, such as α -MoO 3 , has opened up new avenues for mid-IR nanophotonics due to their deep subwavelength phonon polaritons. However, a significant challenge is the lack of active tunability of these hyperbolic phonon polaritons. In this work, we investigate heterostructures of graphene and α -MoO 3 for actively tunable hybrid plasmon phonon polariton modes via electrostatic gating in the mid-infrared spectral region. We observe a unique propagation direction dependent hybridization of graphene plasmon polaritons with hyperbolic phonon polaritons for experimentally feasible values of graphene chemical potential. We further report an application to tunable valley quantum interference in this system with a broad operational bandwidth due to the formation of these hybrid modes. This work presents a lithography-free alternative for actively tunable, anisotropic spontaneous emission enhancement using a sub-wavelength thick naturally biaxial hyperbolic material.

Babinet complementary patterns of a spectrally tunable metamaterial incorporating a nematic liquid crystal is normally assumed to exhibit the same tuning range. Here we show that for a hybrid, liquid crystal-loaded metamaterial, the sensitivity of its terahertz resonances to the variations of the refractive index differs substantially for the two complementary patterns. This is due to a mismatch between the alignment of the liquid crystal and the direction of the local electric field induced in the metamaterial patterns. Furthermore, and more intriguingly, our experimental data indicate that it is possible to shift the resonance of the positive metamaterial pattern beyond the limit imposed by the alignment mismatch. Our analysis suggests that the observed anomalous frequency shift results from the orientational optical nonlinearity of a nematic liquid crystal.

Optical polarization has attracted considerable research attention by extra detection dimension in angular space, flourishing modern optoelectronic applications. Nonetheless, purposive polarization controlling at nanoscales and even at the single-particle level constitutes a challenge. Plasmonic nanoantenna opens up new perspectives in polarization state modification. Herein, we report angular-dependent upconversion luminescence (UCL) of rare-earth ions doped upconversion nanoparticles (UCNPs) in both emission and excitation polarization via constructing angularly anisotropic plasmonic local-field distributions in gold nanorods (Au NRs) antennae with different configurations at a single-particle level. The UCL of UCNP tailored by plasmonic Au NRs nanoantennae is enhanced and exhibits linear polarization. The highest enhancement factor of 138 is obtained in the collinear Au NR-UCNP-Au NR configuration under parallel excitation. Simultaneously, the maximum degree of linear polarization (DOLP) of UCL with factors of 85% and 81% are achieved in the same structure in emission and excitation polarization measurements, respectively. The observed linear polarizations and UCL enhancements are due to varied resonant responses at 660 nm and the anisotropic near-field enhancement in different nanoantennae-load UCNP. The theoretical simulations reveal the periodic changing of near-field enhancement factors of nanoantennae in angular space with the incident light polarization angles and are well-matched with the experimental results.

Photoresponsive materials feature properties that can be adjusted by light near-instantaneously, reversibly, and with high spatiotemporal precision. There is considerable interest in maximising the degree of photoswitching, and in measuring this degree during illumination in complex environments. We study the switching of photoresponsive lipid membranes that allow for precise and reversible manipulation of membrane shape, permeability, and fluidity. Though these macroscopic responses are clear, it is unclear how large the changes of trans / cis ratio are, and whether they can be improved. Here, we used small-angle X-ray scattering to measure the thickness of photoswitchable lipid membranes, and we correlate lipid bilayer thickness to trans / cis ratios. This reveals an unexpected dependency of photoswitching ratio upon aqueous phase composition. In buffer with ionic strength, we observe thickness variations twice as large as previously observed. Furthermore, soft X-rays can quantitatively isomerise photolipid membranes to the all- trans state; enabling X-ray-based membrane control. High energy X-rays do not influence the state of the photoswitches, presumably because they deposit less dose in the sample.

Electromagnetic vortex carries the orbital angular momentum, one of the most fundamental properties of waves. The order of such vortex can be unbounded in principle, thus facilitating high-capability wave technologies for optical communications, photonic integrated circuits and others. However, it remains a key challenge to generate the high-order vortex beams in a reconfigurable, broadband and cost-effective manner. Here, inspired by the balanced-ternary concept, we demonstrate the reconfigurable generation of order-controllable vortices via cascaded N -layer metasurfaces. We theoretically showed that 3 N − 1 ${3}^{N}-1$ different vortex modes can be generated by cascading N metasurfaces, each one serving as an individual vortex beam generator for the order of 3 k ${3}^{k}$ ( k  = 0,1,2 …, N − 1 $N-1$ ). As a proof-of-concept demonstration, a reconfigurable generation of 26 different vortex beams, with orders from 1 to 13 and from −1 to −13, is showcased in a broad millimeter-wave region by a cascade of 3 metasurfaces. Our method can be easily extended to vortex beam generator of arbitrary orders in a reconfigurable and easily implementable manner, paving a new avenue towards tremendous practical applications.

We introduce subwavelength color routers with perfect optical efficiency in a red-green-green-blue (RGGB) Bayer layout for solid state image sensors. This is the first demonstration of a subwavelength device concept that shows the full potential of color routing, i.e., perfect routing without loss of photons, with a broadband, polarization-independent, and angular robust response. As an example, we show a color router for 320 nm wide image sensor pixels, which are two times smaller than the smallest state-of-the-art pixels, that features perfect optical efficiency, i.e., no crosstalk between color channels, no reflections, and no leakage into non-photodetector regions, even though the pixel photodetectors are 2–3 times smaller than the wavelength of the incident light. Our color router outperforms all other color separation approaches and can replace the entire optical stack in solid state image sensors.