Abstract
A consistent thermodynamic data set for the Ru–Si system is obtained by a computer-aided least-squares method applied to the experimental phase diagram and thermodynamic data. The liquid phase is described by the Redlich-Kister formula. All of the compounds, Ru2Si, Ru4Si3, RuSi, and Ru2Si3, are treated as stoichiometric phases. Comparisons between the calculated and measured phase diagram and thermodynamic quantities show that all of the accurate experimental information is well accounted for by the thermodynamic description.
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One of the authors (Yong Du) gratefully acknowledges the visiting scholar grant released by Ministry of Education of P. R. China. This work is supported by the Austrian Science Foundation under grants no. P10736 and P13113.
Literature
48Red Redlich, O.; Kister, A.T.: Ind. Eng. Chem. 40 (1948) 345–348.10.1021/ie50458a036Suche in Google Scholar
62Fin Finnie, L.N: J. Less-Common Met. 4 (1962) 24–34.10.1016/0022-5088(62)90055-3Suche in Google Scholar
65Obr Obrowski, W.: Metall 19 (1965) 741–742.Suche in Google Scholar
68Eng Engstrom, I.; Johnsson, T.: Arkiv Kemi 30 (1968) 141–147.Suche in Google Scholar
70Eng Engstrom, I.: Acta Chem. Scand. 24 (1970) 1466–1468.10.3891/acta.chem.scand.24-1466Suche in Google Scholar
74Isr Israiloff, P.; Voellenkle, H.: Monatsh. Chem. 105 (1974) 1313–1321.10.1007/BF00909869Suche in Google Scholar
75Pou Poutcharovsky, D.J.; Parthe, E.: Acta Crystallogr. B30 (1975) 2692–2696.10.1107/S0567740874007825Suche in Google Scholar
85Sun Sundman, B.; Jansson, B.; Andersson, J.-O.: CALPHAD 9 (1985) 153–190.10.1016/0364-5916(85)90021-5Suche in Google Scholar
85Zur Zur, A.; McGill, T.C.; Nicolet, M.A.: J. Appl. Phys. 57 (1985) 600–603.10.1063/1.334743Suche in Google Scholar
88Top Topor, L.; Kleppa, O.J.: Z. Metallkd. 79 (1988) 623–628.Suche in Google Scholar
88Wei Weitzer, F.; Rogl, P.; Schuster, J.C.: Z. Metallkd. 79 (1988) 154–156.Suche in Google Scholar
90Cha Chang, Y.A.; Chou, M.L.: J. Appl. Phys. 68 (1990) 2411–2414.10.1063/1.346500Suche in Google Scholar
91Din Dinsdale, A.T.: CALPHAD 15 (1991) 317–425.10.1016/0364-5916(91)90030-NSuche in Google Scholar
92Rog Rogl, P.; Schuster, J.C.: Phase Diagrams of Ternary Boron Nitride and Silicon Nitride Systems, ASM International, Materials Park, OH (1992).Suche in Google Scholar
97Busl Buschinger, B.; Geibel, C.; Diehl, J.; Weiden, M.; Guth, W.; Wildbrett, A.; Horn, S.; Steglich, F.: J. Alloys & Comp. 256 (1997) 57–60.10.1016/S0925-8388(96)03021-6Suche in Google Scholar
97Bus2 Buschinger, B.; Guth, W.; Weiden, M.; Geibel, C.; Steglich, F.; Vescoli, V.; Degeorgi, L.; Wassilew-Reul, C.: J. Alloys & Comp. 262/263 (1997) 238–242.10.1016/S0925-8388(97)00389-7Suche in Google Scholar
97Du Du, Y.; Schmid-Fetzer, R.; Ohtani, H.: Z. Metallkd. 88 (1997) 545–556.Suche in Google Scholar
97Kun Kuntz, J.J.; Perring, L.; Feschotte, P.; Gachon, J.C.: J. Solid State Chem. 133 (1997) 439–444.10.1006/jssc.1997.7508Suche in Google Scholar
97Perl Perring, L.; Kuntz, J.J.; Feschotte, P.; Gachon, J.C.: J. Chim. Phys. 94 (1997) 939–947.10.1051/jcp/1997940939Suche in Google Scholar
97Per2 Perring, L.; Feschotte, P.; Gachon, J.C.: Thermochim. Acta 293 (1997) 101–108.10.1016/S0040-6031(97)00041-5Suche in Google Scholar
98Bus Buschinger, B.; Geibel, C.; Diehl, J.; Weiden, M.; Guth, W.; Wildbrett, A.; Horn, S.; Steglich, F.: J. Alloys & Comp. 265 (1998) 315.10.1016/S0925-8388(97)00575-6Suche in Google Scholar
98Cic Ciccioli, A.; Balducci, G.; Gigli, G.; Perring, L.; Kuntz, J.J.; Gachon, J.C.: Ber. Bunsenges. Phys. Chem. 102 (1998) 1275–1278.10.1002/bbpc.19981020936Suche in Google Scholar
98Du Du, Y.; Schuster, J.C.: J. Mater. Sci. Lett. 17 (1998) 1407–1408.10.1023/A:1026496918170Suche in Google Scholar
98Mes Meschel; S.V.; Kleppa, O.J.: J. Alloys & Comp. 274 (1998) 193–200.10.1016/S0925-8388(98)00504-0Suche in Google Scholar
98Per Perring, L.; Bussy, F.; Kuntz, J.J.; Gachon, J.C.: Ber. Bunsenges. Phys. Chem. 102 (1998) 1211–1216.10.1002/bbpc.19981020925Suche in Google Scholar
99Per Perring, L.; Bussy, F.; Gachon, J.C.; Feschotte, P.: J. Alloys & Comp. 284 (1999) 198–205.10.1016/S0925-8388(98)00911-6Suche in Google Scholar
© 2001 Carl Hanser Verlag, München
Artikel in diesem Heft
- Frontmatter
- Aufsätze/Articles
- On Properties of Interstitials and Vacancies in Stainless Steels: A Review
- Thermodynamic Assessment of the Ru–Si System
- The Phase Diagram of the In–Sb–Sn System
- The Excess Enthalpies of Liquid Ag-Ge-Te and Ag-Sn-Te Alloys
- A Model for the Calculation of the Bainitic Phase Transformation Kinetics from Dilatometric Data
- Untersuchung zum Vergleich der σ-Phasenausscheidung in einem rostfreien Superferrit und einem Duplex-Stahl
- Effect of Different Rolling Schedules on the Mechanical Properties and Microstructure of X60 Type HSLA Steel
- Thermochemical Study of High Temperature Corrosion of Iron in a Diluted HCl + SO2 Environment
- Calculation of the Debye Temperature and Study of the Lattice Dynamics of Fe80–xNixCr20 by 57Fe Mössbauer Spectroscopy
- Surface Self-Cleaning Effect of Zn-22Al Alloy during Superplastic Deformation
- Acoustic Emission and Strain Localization in FCC Single Crystals Compressed in Channel-Die at Low Temperature
- Wetting of Alumina, Iron and Stainless Steel Substrates by Molten Magnesium
- Split-Induced Lüders Bands in Non-Sag Tungsten Wires during Torsion
- The Structure and Crystallization of Amorphous Ni–Fe–P–B Alloys Prepared by Electrons Plating
- The Formation of Aluminum Phosphide in Aluminum Melt Treated with an Al–Fe–P Inoculant Addition
- Vapor Pressure and Critical Data for Uranium
- Mitteilungen/Notifications
- Personen
- Mitteilungen/News
- Bücher/Books
- Tagungen/Conferences
Artikel in diesem Heft
- Frontmatter
- Aufsätze/Articles
- On Properties of Interstitials and Vacancies in Stainless Steels: A Review
- Thermodynamic Assessment of the Ru–Si System
- The Phase Diagram of the In–Sb–Sn System
- The Excess Enthalpies of Liquid Ag-Ge-Te and Ag-Sn-Te Alloys
- A Model for the Calculation of the Bainitic Phase Transformation Kinetics from Dilatometric Data
- Untersuchung zum Vergleich der σ-Phasenausscheidung in einem rostfreien Superferrit und einem Duplex-Stahl
- Effect of Different Rolling Schedules on the Mechanical Properties and Microstructure of X60 Type HSLA Steel
- Thermochemical Study of High Temperature Corrosion of Iron in a Diluted HCl + SO2 Environment
- Calculation of the Debye Temperature and Study of the Lattice Dynamics of Fe80–xNixCr20 by 57Fe Mössbauer Spectroscopy
- Surface Self-Cleaning Effect of Zn-22Al Alloy during Superplastic Deformation
- Acoustic Emission and Strain Localization in FCC Single Crystals Compressed in Channel-Die at Low Temperature
- Wetting of Alumina, Iron and Stainless Steel Substrates by Molten Magnesium
- Split-Induced Lüders Bands in Non-Sag Tungsten Wires during Torsion
- The Structure and Crystallization of Amorphous Ni–Fe–P–B Alloys Prepared by Electrons Plating
- The Formation of Aluminum Phosphide in Aluminum Melt Treated with an Al–Fe–P Inoculant Addition
- Vapor Pressure and Critical Data for Uranium
- Mitteilungen/Notifications
- Personen
- Mitteilungen/News
- Bücher/Books
- Tagungen/Conferences