Home Technology The Structure and Crystallization of Amorphous Ni–Fe–P–B Alloys Prepared by Electrons Plating
Article
Licensed
Unlicensed Requires Authentication

The Structure and Crystallization of Amorphous Ni–Fe–P–B Alloys Prepared by Electrons Plating

  • EMAIL logo , , , and
Published/Copyright: January 6, 2022

Abstract

Amorphous quaternary Ni–Fe–P–B alloy deposits have been first and successfully made by electroless plating. It was found that the deposits show an amorphous structure when the reductant NaH2PO2 concentration ranges from 23 to 38 g/l. The crystallization processes of the alloys have been studied by X-ray diffraction. The crystallization processes of different alloys vary with composition, which is determined by the prepared conditions. A two-step process of crystallization was observed for the amorphous alloys. At first, the crystalline phases are Fe2B, γ-(Fe, Ni) solid solution and Ni3Fe, then Ni3P, Fe3P and (Ni, Fe) solid solution appear at high temperatures. The lattice spacing first decreases then increases with heating temperature for the γ-(Fe, Ni) solid solution.


L. L. Wang College of Materials Science and Engineering Hunan University Changsha 410082, P. R. China Fax:+86731 8821483

5

5 Literature

1 Schmeckenbecher, A.F.: J. Electrochem. Soc. 113 (1966) 778.10.1149/1.2424118Search in Google Scholar

2 Hotta, S.; Sugano, M.; Honma, H.: Jpn. J. Surf. Fin. 44 (1993) 217.10.4139/sfj.44.217Search in Google Scholar

3 Schmeckenbecher, A.F.: Plating 58 (1971) 905.Search in Google Scholar

4 Chang, Y.S.; Hsieh, I.J.: Plat. Surf. Fin. 77 (1990) 52.Search in Google Scholar

5 Yi, G.; Zhang, B.W.; Wu, L.J.; Yang, Q.Q.: Physica B216 (1995) 103.10.1016/0921-4526(95)00436-XSearch in Google Scholar

6 Luborsky, F.E.: Mater. Sei. Eng. 28 (1977) 139.10.1016/0025-5416(77)90097-0Search in Google Scholar

7 Wang, L.L.; Zhao, L.H.; Huang, G.F.; Yuan, X.J.: Surf. Coat. Tech. 126 (2000) 272.10.1016/S0257-8972(00)00545-4Search in Google Scholar

8 Zhang, B.W.; Yi, G.: J. Phys.: Condens. Mater. 8 (1996) 5451.Search in Google Scholar

9 Matsuoko, M.; Hayashi, T.: Plat. Surf. Fin. 69 (1982) 53.Search in Google Scholar

10 Kim, D.; Matsuda, H.; Aoki, K.; Takano, O.: Plat. Surf. Fin. 83 (1996) 35.Search in Google Scholar

11 Sheng, L.L.; Liang, H.H.: Plat. Surf. Fin. 79 (1992) 56; 83 (1996) 35.Search in Google Scholar

Received: 2000-03-22
Published Online: 2022-01-06

© 2001 Carl Hanser Verlag, München

Downloaded on 27.3.2026 from https://www.degruyterbrill.com/document/doi/10.3139/ijmr-2001-0076/html
Scroll to top button