Influence of Electron Induced Reactive Processing and Secondary Rubber Phase on Spinnability of Polypropylene and Polypropylene/Rubber Blends
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S. ALRahhal
, H. Brünig , U. Gohs and G. Heinrich
Abstract
The melt spinning behavior of electron-irradiated polypropylene (PP) and PP/ethylene-octene-copolymer (EOC) blends was studied. The low ability to fiber formation of the impact enhanced PP/EOC blends with 2.5 mass percent of high viscous and non-spinnable EOC rubber was enhanced to a large extent by applying a dose of 6 kGy using a continuous electron induced reactive processing (CEIReP). The influence of structure alteration during CEIReP on the fiber formation as well as the textile physical properties of as-spun blend fiber were explored. A remarkable enhancement of the initial modulus as well as the linear elastic region of CEIReP modified PP/EOC blend fiber were achieved.
References
Aghjeh, M. R., Khonakdar, H. A., Jafari, S. H., Zschech, C., Gohs, U. and Heinrich, G., “Rheological, Morphological and Mechanical Investigations on Ethylene Octene Copolymer Toughened Polypropylene Prepared by Continuous Electron Induced Reactive Processing”, RSC Adv., 6, 24651–24660 (2016) 10.1039/C6RA00359ASearch in Google Scholar
ALRahhal, S., Brünig, H., Gohs, U. and Heinrich, G., “Melt Spun Matrix Fibers of Toughened Polypropylene Copolymers Modified by High Energy Electrons”, J. Appl. Polym. Sci., 133, 44011 (2016)10.1002/app.44011Search in Google Scholar
Beyreuther, R., Vogel, R., “Spinnability of Polymer Melts – a Complex Problem in Basic Research”, Int. Polym. Proc., 11, 154–158 (1996) 10.3139/217.960154Search in Google Scholar
Brünig, H., Tändler, B., “A New Method to Determine the Filament Force Tension within the Fibre Formation Zone”, Int. Polym. Proc., 18, 41–45 (2003) 10.3139/217.1715Search in Google Scholar
Krause, B., Voigt, D., Häußler, L., Auhl, D. and Münstedt, H., “Characterization of Electron Beam Irradiated Polypropylene: Influence of Irradiation Temperature on Molecular and Rheological Properties”, J. Appl. Polym. Sci., 100, 2770–2780 (2006) 10.1002/app.23453Search in Google Scholar
Lim, J., Kim, S. K., “Thermal Shrinkage Stress in High-Speed-Spun, High Molecular Weight Poly(ethylene terephthalate) Filaments”, J. Polym. Sci., Part B: Polym. Phys., 39, 964–972 (2001) 10.1002/polb.1072Search in Google Scholar
Lovisi, H., Silva, A. L. N., de Santa Maria, L. C., Rocha, M. C., Bretas, R. E., Farah, M. and Coutinho, F., “Mechanical, Rheological, Thermal, and Morphological Properties of Blends Based on Poly(propylene)/Poly(propylene-co-1-octene)/Poly(ethylene-co-1-octene)”, J. Appl. Polym. Sci., 89, 1690–1695 (2003) 10.1002/app.12294Search in Google Scholar
Mäder, E., Rothe, C. and Gao, S.L., “Commingled Yarns of Surface Nanostructured Glass and Polypropylene Filaments for Effective Composite Properties”, J. Mater. Sci., 42, 8062–8070 (2007) 10.1007/s10853-006-1481-xSearch in Google Scholar
Mäder, E., Rausch, J. and Schmidt, N., “Commingled Yarns – Processing Aspects and Tailored Surfaces of Polypropylene/Glass Composites”, Composites Part A: Applied Science and Manufacturing, 39, 612–623 (2008) 10.1016/j.compositesa.2007.07.011Search in Google Scholar
Rajeshbabu, R., Singha, N. K. and Naskar, K., “Interrelationships of Morphology, Thermal and Mechanical Properties in Uncrosslinked and Dynamically Crosslinked PP/EOC and PP/EPDM Blends”, eXPRESS Polym. Lett., 4, 197–209 (2010) 10.3144/expresspolymlett.2010.26MSearch in Google Scholar
Rajeshbabu, R., Gohs, U., Naskar, K., Mondal, M., Wagenknecht, U. and Heinrich, G., “Electron-Induced Reactive Processing of Poly Propylene/Ethylene–Octene Copolymer Blends: A Novel Route to Prepare Thermoplastic Vulcanizates”, Macromol. Mater. Eng., 297, 659–669 (2012) 10.1002/mame.201100209Search in Google Scholar
Svoboda, P.Svobodova, D., Slobodian, P., Ougizawa, T. and Inoue, T., “Transmission Electron Microscopy Study of Phase Morphology in Polypropylene/Ethylene-Octene Copolymer Blends”, Eur. Polym. J., 45, 1485–1492 (2009) 10.1016/j.eurpolymj.2009.01.032Search in Google Scholar
Tran, N. H. A., Brünig, H. and Heinrich, G., “Controlling Micro- and Nanofibrillar Morphology of Polymer Blends in Low-Speed Melt Spinning Process. I. Profiles of PLA/PVA-Filament Parameters along the Spinline”, J. Appl. Polym. Sci., 133, 44258 (2016) 10.1002/APP.44258Search in Google Scholar
Walton, K. L., “Metallocene Catalyzed Ethylene/Alpha Olefin Copolymers Used in Thermoplastic Elastomers”, Rubber Chem. Technol., 77, 552–568 (2004) 10.5254/1.3547836Search in Google Scholar
© 2018, Carl Hanser Verlag, Munich
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Semi-Rigid Composite Foams of Calcium Sodium Aluminosilicate from Eggshells Embedded in Polyurethane
- Effect of Spin-Draw Rate and Stretching Ratio on Polypropylene Hollow Fiber Membrane Made by Melt-Spinning and Stretching Method
- A Novel Non-Planar Transverse Stretching Process for Micro-Porous PTFE Membranes and Resulting Characteristics
- Photo-Degradation of Polypropylene-Ascorbic Acid TiO2 Composite Films
- Melt Flow and Flexural Properties of Polypropylene Composites Reinforced with Graphene Nano-Platelets
- Effect of the Addition of ENR on Foam Properties of EVA/NR/Clay Nanocomposites
- Development of High Pressure Injection Technology for Normal Hydraulic Injection Molding Machines
- Influence of Electron Induced Reactive Processing and Secondary Rubber Phase on Spinnability of Polypropylene and Polypropylene/Rubber Blends
- Monitoring of Injection Molding Tool Corrosion and Effects of Wood Plastic Compound's Moisture on Material Properties
- Simulation of Micropelletization Mechanisms in Polymer Melt – Air Systems
- Cross-Linked Hydrophobic Starch Granules in Blends with PLA
- Numerical Predictions of Fiber Orientation for Injection Molded Rectangle Plate and Tensile Bar with Experimental Validations
- Fabrication of Polyethylene Terephthalate Microfluidic Chip Using CO2 Laser System
- Minimization of Warpage for Injection Molded Parts by Inverse Thermal Mold Design
- Influence of Titanium Dioxide Modified Expandable Graphite and Ammonium Polyphosphate on Combustion Behavior and Physicomechanical Properties of Rigid Polyurethane Foam
- Preparation, Foaming and Characterization of Poly(l-lactic acid))/Poly(d-lactic acid)-Grafted Graphite Oxide Blends
- A Simple Method of Fabricating Graphene-Polymer Conductive Films
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Semi-Rigid Composite Foams of Calcium Sodium Aluminosilicate from Eggshells Embedded in Polyurethane
- Effect of Spin-Draw Rate and Stretching Ratio on Polypropylene Hollow Fiber Membrane Made by Melt-Spinning and Stretching Method
- A Novel Non-Planar Transverse Stretching Process for Micro-Porous PTFE Membranes and Resulting Characteristics
- Photo-Degradation of Polypropylene-Ascorbic Acid TiO2 Composite Films
- Melt Flow and Flexural Properties of Polypropylene Composites Reinforced with Graphene Nano-Platelets
- Effect of the Addition of ENR on Foam Properties of EVA/NR/Clay Nanocomposites
- Development of High Pressure Injection Technology for Normal Hydraulic Injection Molding Machines
- Influence of Electron Induced Reactive Processing and Secondary Rubber Phase on Spinnability of Polypropylene and Polypropylene/Rubber Blends
- Monitoring of Injection Molding Tool Corrosion and Effects of Wood Plastic Compound's Moisture on Material Properties
- Simulation of Micropelletization Mechanisms in Polymer Melt – Air Systems
- Cross-Linked Hydrophobic Starch Granules in Blends with PLA
- Numerical Predictions of Fiber Orientation for Injection Molded Rectangle Plate and Tensile Bar with Experimental Validations
- Fabrication of Polyethylene Terephthalate Microfluidic Chip Using CO2 Laser System
- Minimization of Warpage for Injection Molded Parts by Inverse Thermal Mold Design
- Influence of Titanium Dioxide Modified Expandable Graphite and Ammonium Polyphosphate on Combustion Behavior and Physicomechanical Properties of Rigid Polyurethane Foam
- Preparation, Foaming and Characterization of Poly(l-lactic acid))/Poly(d-lactic acid)-Grafted Graphite Oxide Blends
- A Simple Method of Fabricating Graphene-Polymer Conductive Films
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts