A Novel Non-Planar Transverse Stretching Process for Micro-Porous PTFE Membranes and Resulting Characteristics
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Y.-H. Chang
Abstract
Polytetrafluoroethylene (PTFE) micro-porous membranes were prepared from PTFE fine powder through extruding, rolling, and uniaxial longitudinally stretching. In contrast to conventional planar transverse stretching, a novel 3D mold design of non-planar transverse stretching process was employed in this study to produce micro-porous structure. The morphology, membrane thickness, mean pore size, and porosity of the PTFE membrane were investigated. The results show that the non-planar transverse stretched membranes exhibit more uniform average pore diameter with thinner membrane thickness. Morphological changes induced by planar and non-planar transverse stretching for pore characteristics were investigated. The stretching conditions, stretching temperature and rate, affect the stretched membrane. Increasing temperature facilitated the uniformity of pore size and uniformity of membrane thickness. Moreover, increase in stretching rate resulted in finer pore size and thinner membrane.
References
Bowman, J. B., Hubis, D. E., Lewis, J. D., Newman, S. C. and Staley, R. A., U.S. Patent 4 482 516 A (1984)Suche in Google Scholar
Chen, S., “SEM Image Analysis of Pore Structure of Extending PTFE Membrane”, Chin. J. Chem. Phys., 18, 228–232 (2005) 10.1016/S0376-7388(97)00184-1Suche in Google Scholar
Guo, Y. H., Chen, J. Y., Gao, J. X., Zhang, H. P. and Feng, X. X., “A Study on the Nonuniform Deformation of PTFE Membrane during its Tentering Transverse Stretching”, J. Appl. Polym. Sci., 116, 1124–1130 (2009) 10.1002/app.31605Suche in Google Scholar
Guo, Y. H., Chen, J., Hao, X., Zhang, J., Feng, X. and Zhang, H., “A Novel Process for Preparing Expanded PTFE Micro-Porous Membrane through ePTFE/ePTFE Co-Stretching Technique”, J. Mater. Sci., 42, 2081–2085 (2006) 10.1007/s10853-006-1214-1Suche in Google Scholar
Haney, A. F., Hesla, J., Hurst, B. S., Kettel, L. M., Murphy, A. A., Rock, J. A., Rowe, G. and Schlaff, W. D., “Expanded Polytetrafluoroethylene (Gore-Tex Surgical Membrane) Is Superior to Oxidized Regenerated Cellulose (Interceed TC7+) in Preventing Adhesions”, Fertil. Steril., 63, 1021–1026 (1995) 10.1016/S0015-0282(16)57541-4Suche in Google Scholar
Hao, X., Zhang, J., Guo, Y. and Zhang, H., “Studies on Porous and Morphological Structures of Expanded PTFE Membrane through Biaxial Stretching Technique”, INJ Summer, 2, 31–38 (2005) 10.1533/9780857092953.1.59Suche in Google Scholar
House, W. D., Myers, D. J., U.S. Patent 4 877 661 A (1989)Suche in Google Scholar
Huang, L.T., Hsu, P. S., Kuo, C. Y., Chen, S. C. and Lai, J. Y., “Pore Size Control of PTFE Membranes by Stretch Operation with Asymmetric Heating System”, Desalin. Water Treat., 233, 64–72 (2008) 10.1016/j.desal.2007.09.028Suche in Google Scholar
Huang, R., Hsu, P. S., Kuo, C. Y., Chen, S. C., Lai, J. Y. and Lee, L. J., “Paste Extrusion Control and its Influence on Pore Size Properties of PTFE Membranes”, Adv. Polym. Technol., 26, 163–172 (2007) 10.1002/adv.20099Suche in Google Scholar
Kitamura, T., Kurumada, K. I., Tanigaki, M., Ohshima, M. and Kanazawa, S. I., “Formation Mechanism of Porous Structure in Polytetrafluoroethylene (PTFE) Porous Membrane through Mechanical Operations”, Polym. Eng. Sci., 39, 2256–2263 (1999) 10.1002/pen.11613Suche in Google Scholar
Kitamura, T., Okabe, S., Tanigaki, M., Kurumada, K. I., Ohshima, M. and Kanazawa, S. I., “Morphology Change in Polytetrafluoroethylene (PTFE), Porous Membrane Caused by Heat Treatment”, Polym. Eng. Sci., 40, 809–817 (2000) 10.1002/pen.11210Suche in Google Scholar
Kurumada, K. I., Kitamura, T., Fukumoto, N., Ohshima, M., Tanigaki, M. and Kanazawa, S. I., “Structure Generation in PTFE Porous Membranes Induced by the Uniaxial and Biaxial Stretching Operations”, J. Memb. Sci., 149, 51–57 (1998) 10.1016/S0376-7388(98)00179-3Suche in Google Scholar
Liu, G., Gao, C., Li, X., Guo, C., Chen, Y., and Lv, J., “Preparation and Properties of Porous PTFE Hollow Fiber Membrane through Mechanical Operation”, J. Appl. Polym. Sci., 132, 42696 (2015) 10.1002/app.42696Suche in Google Scholar
Ranjbarzadeh-Dibazar, A., Shokrollahi, P., Barzin, J. and Rahimi, A., “Lubricant Facilitated Thermo-Mechanical Stretching of PTFE and Morphology of the Resulting Membranes”, J. Membr. Sci., 470, 458–469 (2014) 10.1016/j.memsci.2014.07.062Suche in Google Scholar
Sun, H. Q., Luo, H. and Huang, P., “Property of Biaxial Stretching PTFE Composite Film”, Beijing Plastics Research Institute, 1001–9456 (2009) 10.1533/9780857092953.1.3Suche in Google Scholar
Wang, D. F., Lick, S., Alpard, S. K., Deyo, D. J., Savage, C., Duarte, A., Chambers, S. and Zwischenberger, J. B., “Toward Ambulatory Arteriovenous CO2 Removal: Initial Studies and Prototype Development”, Asaio J., 49, 564–567 (2003) 14524565 10.1097/01.MAT.0000084116.78848.0CSuche in Google Scholar PubMed
Wang, K. Y., Chung, T. S. and Gryta, M., “Hydrophobic PVDF Hollow Fiber Membranes with Narrow Pore Size Distribution and Ultra-Thin Skin for the Fresh Water Production through Membrane Distillation”, Chem. Eng. Sci., 63, 2587–2589 (2008) 10.1016/j.ces.2008.02.020Suche in Google Scholar
Yoo, H., Kwak, S. Y., “Surface Functionalization of PTFE Membranes with Hyperbranched Poly(amidoamine) for the Removal of Cu 2þ Ions From Aqueous Solution”, J. Membr. Sci., 448, 125–134 (2013) 10.1016/j.memsci.2013.07.052Suche in Google Scholar
Zhu, H., Wang, H., Wang, F., Guo, Y., Zhang, H. and Chen, J., “Preparation and Properties of PTFE Hollow Fiber Membranes for Desalination through Vacuum Membrane Distillation”, J. Membr. Sci., 446, 145–153 (2013) 10.1016/j.memsci.2013.06.037Suche in Google Scholar
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Artikel in diesem Heft
- Contents
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- Regular Contributed Articles
- Semi-Rigid Composite Foams of Calcium Sodium Aluminosilicate from Eggshells Embedded in Polyurethane
- Effect of Spin-Draw Rate and Stretching Ratio on Polypropylene Hollow Fiber Membrane Made by Melt-Spinning and Stretching Method
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- Photo-Degradation of Polypropylene-Ascorbic Acid TiO2 Composite Films
- Melt Flow and Flexural Properties of Polypropylene Composites Reinforced with Graphene Nano-Platelets
- Effect of the Addition of ENR on Foam Properties of EVA/NR/Clay Nanocomposites
- Development of High Pressure Injection Technology for Normal Hydraulic Injection Molding Machines
- Influence of Electron Induced Reactive Processing and Secondary Rubber Phase on Spinnability of Polypropylene and Polypropylene/Rubber Blends
- Monitoring of Injection Molding Tool Corrosion and Effects of Wood Plastic Compound's Moisture on Material Properties
- Simulation of Micropelletization Mechanisms in Polymer Melt – Air Systems
- Cross-Linked Hydrophobic Starch Granules in Blends with PLA
- Numerical Predictions of Fiber Orientation for Injection Molded Rectangle Plate and Tensile Bar with Experimental Validations
- Fabrication of Polyethylene Terephthalate Microfluidic Chip Using CO2 Laser System
- Minimization of Warpage for Injection Molded Parts by Inverse Thermal Mold Design
- Influence of Titanium Dioxide Modified Expandable Graphite and Ammonium Polyphosphate on Combustion Behavior and Physicomechanical Properties of Rigid Polyurethane Foam
- Preparation, Foaming and Characterization of Poly(l-lactic acid))/Poly(d-lactic acid)-Grafted Graphite Oxide Blends
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