Phase diagram, thermodynamic investigations, and modelling of systems relevant to lithium-ion batteries
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Siegfried Fürtauer
Abstract
This article reports on two consecutive joint projects titled “Experimental Thermodynamics and Phase Relations of New Electrode Materials for Lithium-Ion Batteries”, which were performed in the framework of the WenDeLIB 1473 priority program “Materials with new Design for Lithium Ion Batteries”. Hundreds of samples were synthesized using experimental techniques specifically developed to deal with highly reactive lithium and lithium-containing compounds to generate electrochemical, phase diagram and crystal structure data in the Cu–Li, Li–Sn, Li–Sb, Cu–Li–Sn, Cu–Li–Sb and selected oxide systems. The thermochemical and phase diagram data were subsequently used to develop self-consistent thermodynamic descriptions of several binary systems. In the present contribution, the experimental techniques, working procedures, results and their relevance to the development of new electrode materials for lithium ion batteries are discussed and summarized. The collaboration between the three groups has resulted in more than fifteen (15) published articles during the six-year funding period.
References
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© 2017, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Priority Programme 1473 (SPP1473) funded by the German Research Foundation: “Materials with new design for improved lithium ion batteries – WeNDeLIB”
- Original Contributions
- Enthalpies of formation of layered LiNixMnxCo1–2xO2 (0 ≤ x ≤ 0.5) compounds as lithium ion battery cathode materials
- Dependence of the constitution, microstructure and electrochemical behaviour of magnetron sputtered Li–Ni–Mn–Co–O thin film cathodes for lithium-ion batteries on the working gas pressure and annealing conditions
- Phase diagram, thermodynamic investigations, and modelling of systems relevant to lithium-ion batteries
- Thin-film calorimetry: In-situ characterization of materials for lithium-ion batteries
- Si- and Sn-containing SiOCN-based nanocomposites as anode materials for lithium ion batteries: synthesis, thermodynamic characterization and modeling
- Phase formation in alloy-type anode materials in the quaternary system Li–Sn–Si–C
- Thermodynamic characterization of lithium monosilicide (LiSi) by means of calorimetry and DFT-calculations
- Thermochemical stability of Li–Cu–O ternary compounds stable at room temperature analyzed by experimental and theoretical methods
- Coexistence of conversion and intercalation mechanisms in lithium ion batteries: Consequences for microstructure and interaction between the active material and electrolyte
- Ion transport and phase transformation in thin film intercalation electrodes
- Electrochemical lithiation of silicon electrodes: neutron reflectometry and secondary ion mass spectrometry investigations
- Interlaboratory study of the heat capacity of LiNi1/3Mn1/3Co1/3O2 (NMC111) with layered structure
- DGM News
- DGM News
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Priority Programme 1473 (SPP1473) funded by the German Research Foundation: “Materials with new design for improved lithium ion batteries – WeNDeLIB”
- Original Contributions
- Enthalpies of formation of layered LiNixMnxCo1–2xO2 (0 ≤ x ≤ 0.5) compounds as lithium ion battery cathode materials
- Dependence of the constitution, microstructure and electrochemical behaviour of magnetron sputtered Li–Ni–Mn–Co–O thin film cathodes for lithium-ion batteries on the working gas pressure and annealing conditions
- Phase diagram, thermodynamic investigations, and modelling of systems relevant to lithium-ion batteries
- Thin-film calorimetry: In-situ characterization of materials for lithium-ion batteries
- Si- and Sn-containing SiOCN-based nanocomposites as anode materials for lithium ion batteries: synthesis, thermodynamic characterization and modeling
- Phase formation in alloy-type anode materials in the quaternary system Li–Sn–Si–C
- Thermodynamic characterization of lithium monosilicide (LiSi) by means of calorimetry and DFT-calculations
- Thermochemical stability of Li–Cu–O ternary compounds stable at room temperature analyzed by experimental and theoretical methods
- Coexistence of conversion and intercalation mechanisms in lithium ion batteries: Consequences for microstructure and interaction between the active material and electrolyte
- Ion transport and phase transformation in thin film intercalation electrodes
- Electrochemical lithiation of silicon electrodes: neutron reflectometry and secondary ion mass spectrometry investigations
- Interlaboratory study of the heat capacity of LiNi1/3Mn1/3Co1/3O2 (NMC111) with layered structure
- DGM News
- DGM News
