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Interlaboratory study of the heat capacity of LiNi1/3Mn1/3Co1/3O2 (NMC111) with layered structure

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Published/Copyright: October 30, 2017
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 108 Issue 11

Abstract

An interlaboratory study was performed to determine the heat capacity of an active material for lithium-ion batteries with layered structure and nominal composition LiNi1/3 · Mn1/3Co1/3O2 (NMC111). The commercial sample, which was characterized using powder X-ray diffraction and inductively coupled plasma–optical emission spectroscopy, is single phase (α-NaFeO2 crystal structure) with a composition of Li1.02Ni0.32Mn0.31Co0.30O2. Heat capacity measurements of the homogeneous sample were performed at five laboratories using different operators, methods, devices, temperature ranges, gas atmospheres and crucible materials. The experimental procedures from each laboratory are presented and the results of the individual laboratories are analyzed. Based on a comprehensive evaluation of the data from each laboratory, the heat capacity of the NMC111 sample from 315 K to 1 020 K is obtained with an expanded reproducibility uncertainty of less than 1.22 %.

Keywords: Calorimetry; Heat capacity; Interlaboratory study; NMC111; Lithium-ion batteries
*Correspondence address, Dr. Damian M. Cupid, Electric Drive Technologies, Center for Low-Emission Transport, AIT Austrian Institute of Technology GmbH, Giefinggasse 2, 1210, Vienna, Austria, Tel.: +43 50550-6064, Fax: +43 50550-6595, E-mail:

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Received: 2017-05-22
Accepted: 2017-09-22
Published Online: 2017-10-30
Published in Print: 2017-11-10

© 2017, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Priority Programme 1473 (SPP1473) funded by the German Research Foundation: “Materials with new design for improved lithium ion batteries – WeNDeLIB”
  5. Original Contributions
  6. Enthalpies of formation of layered LiNixMnxCo1–2xO2 (0 ≤ x ≤ 0.5) compounds as lithium ion battery cathode materials
  7. Dependence of the constitution, microstructure and electrochemical behaviour of magnetron sputtered Li–Ni–Mn–Co–O thin film cathodes for lithium-ion batteries on the working gas pressure and annealing conditions
  8. Phase diagram, thermodynamic investigations, and modelling of systems relevant to lithium-ion batteries
  9. Thin-film calorimetry: In-situ characterization of materials for lithium-ion batteries
  10. Si- and Sn-containing SiOCN-based nanocomposites as anode materials for lithium ion batteries: synthesis, thermodynamic characterization and modeling
  11. Phase formation in alloy-type anode materials in the quaternary system Li–Sn–Si–C
  12. Thermodynamic characterization of lithium monosilicide (LiSi) by means of calorimetry and DFT-calculations
  13. Thermochemical stability of Li–Cu–O ternary compounds stable at room temperature analyzed by experimental and theoretical methods
  14. Coexistence of conversion and intercalation mechanisms in lithium ion batteries: Consequences for microstructure and interaction between the active material and electrolyte
  15. Ion transport and phase transformation in thin film intercalation electrodes
  16. Electrochemical lithiation of silicon electrodes: neutron reflectometry and secondary ion mass spectrometry investigations
  17. Interlaboratory study of the heat capacity of LiNi1/3Mn1/3Co1/3O2 (NMC111) with layered structure
  18. DGM News
  19. DGM News
https://doi.org/10.3139/146.111571
Keywords for this article
Calorimetry; Heat capacity; Interlaboratory study; NMC111; Lithium-ion batteries

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Priority Programme 1473 (SPP1473) funded by the German Research Foundation: “Materials with new design for improved lithium ion batteries – WeNDeLIB”
  5. Original Contributions
  6. Enthalpies of formation of layered LiNixMnxCo1–2xO2 (0 ≤ x ≤ 0.5) compounds as lithium ion battery cathode materials
  7. Dependence of the constitution, microstructure and electrochemical behaviour of magnetron sputtered Li–Ni–Mn–Co–O thin film cathodes for lithium-ion batteries on the working gas pressure and annealing conditions
  8. Phase diagram, thermodynamic investigations, and modelling of systems relevant to lithium-ion batteries
  9. Thin-film calorimetry: In-situ characterization of materials for lithium-ion batteries
  10. Si- and Sn-containing SiOCN-based nanocomposites as anode materials for lithium ion batteries: synthesis, thermodynamic characterization and modeling
  11. Phase formation in alloy-type anode materials in the quaternary system Li–Sn–Si–C
  12. Thermodynamic characterization of lithium monosilicide (LiSi) by means of calorimetry and DFT-calculations
  13. Thermochemical stability of Li–Cu–O ternary compounds stable at room temperature analyzed by experimental and theoretical methods
  14. Coexistence of conversion and intercalation mechanisms in lithium ion batteries: Consequences for microstructure and interaction between the active material and electrolyte
  15. Ion transport and phase transformation in thin film intercalation electrodes
  16. Electrochemical lithiation of silicon electrodes: neutron reflectometry and secondary ion mass spectrometry investigations
  17. Interlaboratory study of the heat capacity of LiNi1/3Mn1/3Co1/3O2 (NMC111) with layered structure
  18. DGM News
  19. DGM News
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