Startseite Experimental study of the phase relations in the Fe–Cr–Si ternary system at 700°C
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Experimental study of the phase relations in the Fe–Cr–Si ternary system at 700°C

  • Zhi Li , Zhe Zhou , Xinming Wang , Yongxiong Liu , Yu Wu , Manxiu Zhao und Fucheng Yin
Veröffentlicht/Copyright: 15. September 2014
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 105 Heft 9

Abstract

The 700°C isothermal section of the Fe–Cr–Si ternary phase diagram has been determined experimentally by means of scanning electron microscopy coupled with energy dispersive X-ray spectroscopy and X-ray powder diffraction. Ten three-phase regions exist in the 700°C isothermal section. The binary σ phase contains 0–17.6 at.% Si and 31.4–59.2 at.% Cr; the Fe5Si3 phase is stable at 700°C because of the dissolution of Cr. At this temperature, Fe and Cr cannot be entirely substituted by each other to form the FeSi or CrSi phases: the maximum possible Cr content in FeSi2, Fe5Si3 and D03 is 3.9, 20.7 and 15.2 at.%, respectively, and the maximum soluble Fe in CrSi2, Cr5Si3 and Cr3Si is 2.5, 20.4 and 16.8 at.%, respectively.

Keywords: Fe–Cr–Si system; Phase diagram; Scanning electron microscopy; X-ray diffraction
* Correspondence address, Professor Zhi Li, School of Mechanical Engineering, Xiangtan University, Hunan 411105, PR China, and, Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University, Hunan 411105, PR China, Tel.: +86 0731 58292210;, Fax: +86 0731 58292210;, E-mail:

References

[1] K.Yamamoto, Y.Kimura, Y.Mishima: Scr. Mater. 50 (2004) 977. 10.1016/j.scriptamat.2004.01.006Suche in Google Scholar

[2] P.J.Cunat: Alloying Elements in Stainless Steel and Other Chromium-Containing Alloys, Int. Chromium Dev. Assoc.Paris, (2004).Suche in Google Scholar

[3] J.Robertson, M.I.Manning: J. Mater. Sci. Technol. 5 (1989) 741. 10.1179/026708389790222825Suche in Google Scholar

[4] Z.Zhou, Z.Li, X.M.Wang, Y.X.Liu, Y.Wu, M.X.Zhao, F.C.Yin: Thermochim. Acta. 577 (2014) 59. 10.1016/j.tca.2013.12.009Suche in Google Scholar

[5] A.G.H.Andersen, E.R.Jette: Trans. Amer. Soc. Met. 24 (1936) 375.Suche in Google Scholar

[6] E.I.Gladyshevsky, L.K.Borusevich: Izv. Akad. Nauk SSSR, Met. 1 (1966) 159.Suche in Google Scholar

[7] V.Raghavan: Phase diagrams of ternary iron alloys, Part 1, ASM International, Materials Park, Ohio, 11 (1987) 31.Suche in Google Scholar

[8] M.Lindholm: J. Phase Equilib. 18 (1997) 432. 10.1007/BF02647699Suche in Google Scholar

[9] Y.Dusausoy, J.Protas: Acta Crystallogr. 27 (1971) 1209. 10.1107/S0567740871003765Suche in Google Scholar

[10] R.Wartchow, S.Gerighausen, M.Binnewies: Z. Kristallogr. 212 (1997) 320. 10.1524/zkri.1997.212.1.57Suche in Google Scholar

[11] D.Errandonea, D.Santamaría–Perez, A.Vegas, J.Nuss, M.Jansen, P.Rodríguez–Hernandez, A.Muñoz: Phys. Rev. B77 (2008) 094113–1. 10.1103/PhysRevB.77.045208Suche in Google Scholar

[12] M.Schuette, R.Wartchow, M.Binnewies: Z. Anorg. Allg. Chem. 629 (2003) 1846. 10.1002/zaac.200300125Suche in Google Scholar

[13] T.Dasgupta, J.Etourneau, B.Chevalier, S.F.Matar, A.M.Umarji: J. Appl. Phys. 103 (2008) 113516–1. 10.1063/1.2917347Suche in Google Scholar

[14] W.Jauch, A.J.Schultz, G.Heger: J. Appl. Crystallogr. 20 (1987) 117. 10.1107/S0021889887086400Suche in Google Scholar

[15] C.H.Dauben, D.H.Templeton, C.E.Myers: J. Phys. Chem. 60 (1956) 443. 10.1021/j150538a015Suche in Google Scholar

[16] B.Altintas: J. Phys. Chem. Solids72 (2011) 1325. 10.1016/j.jpcs.2011.07.027Suche in Google Scholar

[17] V.Raghavan: J. Phase Equilib. 24 (2003) 265. 10.1007/s11669-003-0009-1Suche in Google Scholar

[18] O.Kubaschewski: Iron Binary Phase Diagrams, Springer, Berlin (1982).Suche in Google Scholar

[19] S.Ackerbauer, N.Krendelsberger, F.Weitzer, K.Hiebl, J.C.Schuster: Intermetallics17 (2009) 414. 10.1016/j.intermet.2008.11.016Suche in Google Scholar

Received: 2014-01-13
Accepted: 2014-04-14
Published Online: 2014-09-15
Published in Print: 2014-09-15

© 2014, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Diffusivities and atomic mobilities of an Sn–Ag–Bi–Cu–Pb melt
  5. Experimental study of the phase relations in the Fe–Cr–Si ternary system at 700°C
  6. Effect of molybdenum on the microstructure, mechanical properties and corrosion behavior of Ti alloys
  7. Mechanism of grain refinement and coarsening in undercooled Ni–Fe alloy
  8. Effects of copper content and liquid separation on the microstructure formation of Co–Cu immiscible alloys
  9. Influence of the solidification temperature range on Gasar structures made from Cu–Mn alloys
  10. Effect of ageing time on mechanical properties and tribological behaviour of aluminium hybrid composite
  11. Microstructure and tensile properties of a friction stir welded Al–Mg–Si alloy
  12. Lüders effect in Al 99.7% extruded via the KoBo method
  13. Reduced graphene oxide nanocomposites with different diameters and crystallinity of TiO2 nanoparticles – synthesis, characterization and photocatalytic activity
  14. Constitutive modelling of mill loads during hot rolling of AISI 321 austenitic stainless steel
  15. X-ray stress measurement with two-dimensional detector based on Fourier analysis
  16. People
  17. People
  18. People
  19. DGM News
  20. Personal
https://doi.org/10.3139/146.111100
Schlagwörter für diesen Artikel
Fe–Cr–Si system; Phase diagram; Scanning electron microscopy; X-ray diffraction

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Diffusivities and atomic mobilities of an Sn–Ag–Bi–Cu–Pb melt
  5. Experimental study of the phase relations in the Fe–Cr–Si ternary system at 700°C
  6. Effect of molybdenum on the microstructure, mechanical properties and corrosion behavior of Ti alloys
  7. Mechanism of grain refinement and coarsening in undercooled Ni–Fe alloy
  8. Effects of copper content and liquid separation on the microstructure formation of Co–Cu immiscible alloys
  9. Influence of the solidification temperature range on Gasar structures made from Cu–Mn alloys
  10. Effect of ageing time on mechanical properties and tribological behaviour of aluminium hybrid composite
  11. Microstructure and tensile properties of a friction stir welded Al–Mg–Si alloy
  12. Lüders effect in Al 99.7% extruded via the KoBo method
  13. Reduced graphene oxide nanocomposites with different diameters and crystallinity of TiO2 nanoparticles – synthesis, characterization and photocatalytic activity
  14. Constitutive modelling of mill loads during hot rolling of AISI 321 austenitic stainless steel
  15. X-ray stress measurement with two-dimensional detector based on Fourier analysis
  16. People
  17. People
  18. People
  19. DGM News
  20. Personal
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 7.9.2025 von https://www.degruyterbrill.com/document/doi/10.3139/146.111100/html
Button zum nach oben scrollen