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Diffusivities and atomic mobilities of an Sn–Ag–Bi–Cu–Pb melt

  • Weimin Chen , Lijun Zhang , Yong Du and Baiyun Huang
Published/Copyright: September 15, 2014
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 105 Issue 9

Abstract

The recently developed Arrhenius formula of a modified Sutherland equation was employed to calculate the self- and impurity diffusivities in liquid Sn, Ag, Bi, Cu and Pb. The reliability of the calculated self- and impurity diffusivities was validated by comparing the calculated diffusivities with the critically reviewed literature data. Based on the reliable tracer, intrinsic and chemical diffusivities available in the literature, the atomic mobility parameters in an Sn–Ag–Bi–Cu–Pb melt were then evaluated by the DICTRA (DIffusion-Controlled TRAnsformations) software package with the aid of the available thermodynamic description for the liquid phase. Comprehensive comparisons show that most of the measured and theoretical diffusivities in Sn–Ag–Bi–Cu–Pb melts can be reasonably reproduced by the currently obtained atomic mobilities. The atomic mobilities were further verified by comparing the model-predicted concentration profiles with the measured ones in various liquid Ag–Pb, Bi–Pb and Sn–Bi–Pb diffusion couples. Finally, the simulation of dissolution of Ag and Cu substrates into liquid solder alloys during the reflow process was performed by using the presently obtained atomic mobilities in the Sn–Ag–Bi–Cu–Pb melts.

Keywords: Solder alloys; Liquid; Diffusivity; Atomic mobility; Sn–Ag–Bi–Cu–Pb melt
* Correspondence address, Professor Dr. Lijun Zhang, State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083, People's Republic of China, Tel.: +86 731 88877963, Fax: +86 731 88710855, E-mail: ;

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Received: 2013-12-22
Accepted: 2014-04-16
Published Online: 2014-09-15
Published in Print: 2014-09-15

© 2014, Carl Hanser Verlag, München

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Diffusivities and atomic mobilities of an Sn–Ag–Bi–Cu–Pb melt
  5. Experimental study of the phase relations in the Fe–Cr–Si ternary system at 700°C
  6. Effect of molybdenum on the microstructure, mechanical properties and corrosion behavior of Ti alloys
  7. Mechanism of grain refinement and coarsening in undercooled Ni–Fe alloy
  8. Effects of copper content and liquid separation on the microstructure formation of Co–Cu immiscible alloys
  9. Influence of the solidification temperature range on Gasar structures made from Cu–Mn alloys
  10. Effect of ageing time on mechanical properties and tribological behaviour of aluminium hybrid composite
  11. Microstructure and tensile properties of a friction stir welded Al–Mg–Si alloy
  12. Lüders effect in Al 99.7% extruded via the KoBo method
  13. Reduced graphene oxide nanocomposites with different diameters and crystallinity of TiO2 nanoparticles – synthesis, characterization and photocatalytic activity
  14. Constitutive modelling of mill loads during hot rolling of AISI 321 austenitic stainless steel
  15. X-ray stress measurement with two-dimensional detector based on Fourier analysis
  16. People
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  19. DGM News
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https://doi.org/10.3139/146.111103
Keywords for this article
Solder alloys; Liquid; Diffusivity; Atomic mobility; Sn–Ag–Bi–Cu–Pb melt

Articles in the same Issue

  1. Contents
  2. Contents
  3. Original Contributions
  4. Diffusivities and atomic mobilities of an Sn–Ag–Bi–Cu–Pb melt
  5. Experimental study of the phase relations in the Fe–Cr–Si ternary system at 700°C
  6. Effect of molybdenum on the microstructure, mechanical properties and corrosion behavior of Ti alloys
  7. Mechanism of grain refinement and coarsening in undercooled Ni–Fe alloy
  8. Effects of copper content and liquid separation on the microstructure formation of Co–Cu immiscible alloys
  9. Influence of the solidification temperature range on Gasar structures made from Cu–Mn alloys
  10. Effect of ageing time on mechanical properties and tribological behaviour of aluminium hybrid composite
  11. Microstructure and tensile properties of a friction stir welded Al–Mg–Si alloy
  12. Lüders effect in Al 99.7% extruded via the KoBo method
  13. Reduced graphene oxide nanocomposites with different diameters and crystallinity of TiO2 nanoparticles – synthesis, characterization and photocatalytic activity
  14. Constitutive modelling of mill loads during hot rolling of AISI 321 austenitic stainless steel
  15. X-ray stress measurement with two-dimensional detector based on Fourier analysis
  16. People
  17. People
  18. People
  19. DGM News
  20. Personal
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