Startseite Effect of additive and current density on microstructure and texture characteristics of copper electrodeposits
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Effect of additive and current density on microstructure and texture characteristics of copper electrodeposits

  • R. Manu und Sobha Jayakrishnan
Veröffentlicht/Copyright: 17. August 2013
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 104 Heft 2

Abstract

Copper was electrodeposited at different current densities with additive modifications of the plating bath. With respect to applied current density there is modification of the microstructure as well as the physical properties of the copper deposit. There is notable change in cathodic potential, as revealed from polarization analysis, with Mw of poly ethylene glycol. The increase in current density increased crystallite size and increased the hardness of the deposit. There is significant change in grain size and shape with respect to applied current density in the case of the same kind of additives. The crystallographic orientation of the deposit has a prominent (220) plane for deposit at high current density and the ratio I(111)/I(220) decreased with increase in current density. The observed changes can be envisaged as due to the adsorption nature, nucleation characteristics with respect to various additives and also on the hydrogen evolution rate with applied current density, which influenced the deposit character.

Keywords: Copper; Plating; Scanning electron microscopy; Atomic force microscopy
* Correspondence address, Dr. R. Manu, EMFT Division, CSIR-CECRI, Karaikudi, Tamilnadu, INDIA-630006, Tel.: +914565241572, Fax: +9104565227713, E-mail: ,

References

[1] C.E.Täubert, D.M.Kolb, U.Memmert, H.Meyer: J. Electrochem. Soc.154 (2007) D293. 10.1149/1.2719611Suche in Google Scholar

[2] W.P.Dow, C.C.Li, M.W.Lin, G.W.Su, C.C.Huang: J. Electrochem. Soc.156 (2009) D314. 10.1149/1.3147273Suche in Google Scholar

[3] J.Reid, C.Gack, S.J.Hearne: Electrochem. Solid State Lett.6 (2003) C26. 10.1149/1.1535754Suche in Google Scholar

[4] W.P.Dow, H.S.Huang, M.Y.Yen, H.H.Chen: J. Electrochem. Soc.152 (2005) C77. 10.1149/1.1849935Suche in Google Scholar

[5] M.Alodan, W.H.Smyrl: Electrochim. Acta.44 (1998) 299. 10.1016/S0013-4686(98)00060-7Suche in Google Scholar

[6] J.H.Choi, S.Y.Kang, D.N.Lee: J. Mater. Sci.35 (2000) 4055. 10.1023/A:1004834204320Suche in Google Scholar

[7] D.N.Lee, Y.W.Chang: J. Korean Inst. Met.12 (1974) 243.Suche in Google Scholar

[8] Y.B.Li, W.Wang, Y.Li: Appl. Surf. Sci.255 (7) (2009) 3977. 10.1016/j.apsusc.2008.10.099Suche in Google Scholar

[9] R.Winand, I.H.Warren (Eds.): Application of Polarization Measurements in the Control of Metal Deposition, Elsevier, Amsterdam (1984) 47.Suche in Google Scholar

[10] R.Winand: J. Appl. Electrochem.21 (1991) 377. 10.1007/BF01024572Suche in Google Scholar

[11] A.Wu, D.P.Barkey: J. Electroanal. Chem.150 (2003) C533. 10.1149/1.1590993Suche in Google Scholar

[12] A.Damjanovic, T.H.V.Setty, J. O’M.Bockris: J. Electrochem. Soc.113 (1966) 429. 10.1149/1.2423989Suche in Google Scholar

[13] M.Kang, A.A.Gewirth: J. Electrochem. Soc.150 (2003) C426. 10.1149/1.1572152Suche in Google Scholar

[14] P.Celos, J.R.Roos, C.E.Buelens, in: Directional properties of materials, H. J.Bunge (Ed.), DGM Informationsgesellschaft, Verlag, Heidelberg (1988) 189.Suche in Google Scholar

[15] O’M.Bockris, G.A.Razumney: Fundamentals aspects of ElectrocrystallizationPlenum Press, New York (1967).10.1007/978-1-4684-0697-9Suche in Google Scholar

[16] R.Kaur, N.K.Verma, S.K.Chakarvarti: J. Mater. Sci.42 (2007) 3588. 10.1007/s10853-006-0182-9Suche in Google Scholar

[17] D.Josell, B.Baker, C.Witt, D.Wheeler, T.P.Moffat: J. Electrochem. Soc.149 (2002) C637. 10.1149/1.1517583Suche in Google Scholar

[18] V. A.Vas'ko, I.Tabakovic, S.C.Riemer, M.T.Kief: Microelectronics Eng.75 (2004) 71. 10.1016/j.mee.2003.10.008Suche in Google Scholar

[19] M.Hayase, M.Taketani, K.Aizawa, T.Hatsuzawa, K.Hayabusa: Electrochem. Solid-State Lett.5 (2002) C98. 10.1149/1.1507942Suche in Google Scholar

[20] S.C.Chang, J.M.Shieh, K.C.Lin, B.T.Dai, T.C.Wang, C.F.Chen, M.S.Feng, Y.H.Li, C.P.Lu: J. Vac. Sci. Technol. B20 (2002) 1311. 10.1116/1.1486231Suche in Google Scholar

[21] W.P.Dow, H.H.Chen: Circuit World30 (2004) 33. 10.1108/03056120410520597Suche in Google Scholar

[22] X.Ye, M.De Bonte, J.P.Celis, J.R.Roos: J. Electrochem. Soc.139 (1992) 1592. 10.1149/1.2069461Suche in Google Scholar

[23] H.Jennings, F.E.Rizzo: Metall. Trans.4 (1973) 921. 10.1007/BF02645590Suche in Google Scholar

[24] V.I.Lakshmanan, D.J.Mackinnon, J.M.Brannen: J. Appl. Electrochem., 7 (1977) 81. 10.1007/BF00615534Suche in Google Scholar

[25] L.Bonou, M.Eyraud, R.Denoyel, Y.Massiani: Electrochemica Acta47 (2002) 4139. 10.1016/S0013-4686(02)00356-0Suche in Google Scholar

[26] W.Paik, M.A.Genshaw, J.O.’M.Bockris: J. Phys. Rew.74 (1970) 4266.Suche in Google Scholar

[27] L.Vracar, D.M.Drazic: J. Electroanal. Chem.339 (1992) 269. 10.1016/0022-0728(92)80457-FSuche in Google Scholar

[28] B.Bozzini, C.Mele, L.D’Urzo, V.Romanello: J. Mater. Sci. Mater. Electron.17 (2006) 915. 10.1007/s10854-006-0044-xSuche in Google Scholar

[29] T.C.Franklin: Surf. Coat. Technol.30 (1987) 415. 10.1016/0257-8972(87)90133-2Suche in Google Scholar

[30] T.C.Franklin: Plat. Surf. Finish.4 (1994) 62.Suche in Google Scholar

[31] A.Reitzle, F.U.Renner, T.L.Lee, J.Zegenhagen, D.M.Kolb: Surf. Sci.576 (1–3) (2005) 19.10.1016/j.susc.2004.11.038Suche in Google Scholar

Received: 2011-8-8
Accepted: 2012-7-24
Published Online: 2013-08-17
Published in Print: 2013-02-15

© 2013, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Structure of composites consolidated from ball milled 7475 aluminum alloy and ZrO2 powders
  5. Isothermal section of the Al-Tb-V ternary system at 773 K
  6. Development of an atomic mobility database for disordered and ordered fcc phases in multicomponent Al alloys: focusing on binary systems
  7. Effect of additive and current density on microstructure and texture characteristics of copper electrodeposits
  8. Magnetic properties and microwave absorption properties of carbon fibers coated with FeCo alloy
  9. Effects of BN content on the structural and mechanical properties of a-SiBN ceramics
  10. Structural and relaxor characteristics of Ca0.18Sr0.226Ba0.594Nb2O6
  11. Study on the dielectric properties of CaCu3Ti4O12 ceramics using the one-dimensional Ising model
  12. Erosion wear performance of a surface diffusion alloyed coating on pure magnesium
  13. Evaluation of the quality of cladding deposited on continuous steel casting rolls
  14. Investigating the machinability of austempered ductile irons with dual matrix structures
  15. Simple preperation of CuO nanoparticles and submicron spheres via ultrasonic spray pyrolysis (USP)
  16. Fabrication of transparent Nd:YAG ceramic by vacuum sintering with CaF2 additive
  17. Synthesis and characterization of new Bi2FeNiO6 material using a citric acid assisted gel combustion technique
  18. Processing and characterization of up-converting Er3+ doped (Lu0.5Y0.5)2O3 nanophosphor
  19. People
  20. People
  21. DGM News
  22. DGM News
https://doi.org/10.3139/146.110848
Schlagwörter für diesen Artikel
Copper; Plating; Scanning electron microscopy; Atomic force microscopy

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Structure of composites consolidated from ball milled 7475 aluminum alloy and ZrO2 powders
  5. Isothermal section of the Al-Tb-V ternary system at 773 K
  6. Development of an atomic mobility database for disordered and ordered fcc phases in multicomponent Al alloys: focusing on binary systems
  7. Effect of additive and current density on microstructure and texture characteristics of copper electrodeposits
  8. Magnetic properties and microwave absorption properties of carbon fibers coated with FeCo alloy
  9. Effects of BN content on the structural and mechanical properties of a-SiBN ceramics
  10. Structural and relaxor characteristics of Ca0.18Sr0.226Ba0.594Nb2O6
  11. Study on the dielectric properties of CaCu3Ti4O12 ceramics using the one-dimensional Ising model
  12. Erosion wear performance of a surface diffusion alloyed coating on pure magnesium
  13. Evaluation of the quality of cladding deposited on continuous steel casting rolls
  14. Investigating the machinability of austempered ductile irons with dual matrix structures
  15. Simple preperation of CuO nanoparticles and submicron spheres via ultrasonic spray pyrolysis (USP)
  16. Fabrication of transparent Nd:YAG ceramic by vacuum sintering with CaF2 additive
  17. Synthesis and characterization of new Bi2FeNiO6 material using a citric acid assisted gel combustion technique
  18. Processing and characterization of up-converting Er3+ doped (Lu0.5Y0.5)2O3 nanophosphor
  19. People
  20. People
  21. DGM News
  22. DGM News
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