Microstructure and phase composition in a die cast Mg–Nd alloy containing Zn and Zr
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Galit Atiya
, Menachem Bamberger and Alexander Katsman
Abstract
The microstructure of the as-cast Mg-3.1Nd-0.45Zr-0.25Zn (wt.%) alloy was investigated. It consists of α-Mg matrix, a divorced intergranular phase and small Zr-containing particles. Scanning electron microscopy equipped with energy dispersive spectroscopy analysis on transmission electron microscopy samples was carried out in order to eliminate the Mg matrix contribution to the quantitative analysis results and to reveal the intergranular phase composition which was found to be Mg12–xZnxNd (x ∼ 0.31) (space group I4/mmm) with a bct crystal structure. The lattice parameters (a = 1.029 nm and c = 0.591 nm) were found using X-ray diffraction with the least squares refinement technique. The combination of different characterization techniques indicates that Mg atoms are substituted by Zn atoms without a change in the crystal structure.
Refrences
[1]T.J.Pike, B.Noble: J. Less Common Metals, 30 (1973) 63–74. 10.1016/0022-5088(73)90007-6Search in Google Scholar
[2]J.F.Nie, B.C.Muddle: Acta Mater.48 (2000) 1691–1703. 10.1016/S1359-6454(00)00013-6Search in Google Scholar
[3]L.L.Rokhlin: Magnesium alloys containing rare earth metals, Tailor&Francis, London and New York (2003).10.1201/9781482265163Search in Google Scholar
[4]A.A.Luo: Inter. Mater. Rev.49 (2004) 13–30. 10.1179/095066004225010497Search in Google Scholar
[5]S.Xue, Y.S.Sun, T.B.Zhu: Zhuzao/Foundry, 54 (9) (2005) 888–891.Search in Google Scholar
[6]Z.Yang, J.P.Li, J.X.Zhang, G.W.Lorimer, J.Robson: Acta Metal. Sin.21 (21) (2008) 313–328. 10.1016/S1006-7191(08)60054-XSearch in Google Scholar
[7]M.M.Avedesian, H.Baker: Magnesium and Magnesium alloys, ASM International, ASTM speciality handbook (1999).Search in Google Scholar
[8]K.Zheng, J.Dong, X.Zeng, W.Ding: in M. O.Pekguleryuz, N. R.Neelameggham, R.S.Beals, E. A.Nyberg (Eds.), Magnesium Technology, Proc. TMS, New Orleans, Louisiana, USA (2008) 355–360.Search in Google Scholar
[9]R.Wilson, C.J.Bettles, B.C.Muddle, J.F.Nie: Mater. Sci. Forum419–422 (2003) 267–272.10.4028/www.scientific.net/MSF.419-422.267Search in Google Scholar
[10]F.Peng-huai, Li-mingPeng, Hai-yanJiang, Jian-weiChang, Chun-quanZhai: Mat. Sci. Eng. A, 486 (2008) 183–192.10.1016/j.msea.2007.08.064Search in Google Scholar
[11]P.Fu, L.Peng, H.Jiang: Mater. Sci. Forum546–549 (2007) 97–100.10.4028/www.scientific.net/MSF.546-549.97Search in Google Scholar
[12]Z.Hildebrand, M.Quian, D.St.John, M.Frost: in Alan A.Luo (Ed.), Magnesium Technology, Proc. TMS, Charlotte, North Carolina, USA (2004) 241–245.Search in Google Scholar
[13]L.R.Gill, G.W.Lorimer, P.Lyon: Adv. Eng. Mater.9 (2007) 784–792. 10.1002/adem.200700158Search in Google Scholar
[14]M.Podosek, G.W.Lorimer: Arch. Metall.45 (2000) 47–55.Search in Google Scholar
[15]V.D.Scott, G.Love, S.J.BReed: Quantitative Electron-Probe Microanalysis, 2nd ed., Ellis Horwood, New York (1995).Search in Google Scholar
[16]International centre for diffraction data. (2011). PDF 04-003-6490.Search in Google Scholar
[17]H.Okamoto: J. Phase Equilibria12 (1991) 249–250. 10.1007/BF02645728Search in Google Scholar
[18]V.V.Kinzhibalo, A.T.Tyvanchuk, E.V.Melnik: Stable and Metastable Phase Equilibria in Metallic Systems, Nauka, Moscow, USSR (1985) 70–74.Search in Google Scholar
[19]H.Y.Qi, G.X.Huang, H.Bo, G.L.Xu, L.B.Liu, Z.P.Jin: J. Alloys Comp.509 (509) (2011) 3274–3281. 10.1016/j.jallcom.2010.07.056Search in Google Scholar
[20]G.Atiya, M.Bamberger, A.Katsman: in W. H.Sillekens, S. R.Agnew, N.R.Neelameggham, S.N.Mathaudhu (Eds.), Magnesium Technology, Proc. TMS, San-Diego, California, USA (2011) 249–253.Search in Google Scholar
[21]A.Rakowska, M.Socjusz-Podosek, L.Liyynska, R.Ciach: Mikroc. Acta139 (139) (2002) 145–148.Search in Google Scholar
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Articles in the same Issue
- Contents
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- Original Contributions
- Phase equilibria in the Gd–Ni binary and Mg–Ni–Gd ternary systems
- Thermodynamics of dilute binary solid solutions using the cluster variation method
- Thermal stability of coherent Pd/TiAl interfaces studied from first-principles calculations and experiments
- Electropulsing-induced phase transformations and their effects on the single point diamond turning of a tempered alloy AZ91
- Study of the mechanism of ductile-regime grinding of SiCp/Al composites using finite element simulation
- Investigations on laser welding of magnesium alloys
- Investigation of the surface of a laser-treated cast iron cylinder bore
- Solidification behaviour of an AA5754 Al alloy ingot cast with high impurity content
- Study of the structural evolution of crystalline zinc oxide films prepared by PLD
- Effects of sintering temperature on pore characterization and strength of porous cordierite–mullite ceramics by a pore-forming in-situ technique
- Sol–gel synthesis of Eu3+, Tb3+ co-doped Y2O3 scintillating nanopowders
- Morphological study of SiC coating developed on 2D carbon composites using MTS precursor in a hot-wall vertical reactor
- Self-assembling behavior and corrosion inhibition properties of TDPA films on differently structured surfaces of 2024 and 1060 aluminum alloys
- Photocatalytic activity of MnWO4 powder in highly effective hydrogen generation from H2O and H2O2
- Rheology and microstructure of polymer-modified asphalt nanocomposites
- Short Communications
- Microstructure and phase composition in a die cast Mg–Nd alloy containing Zn and Zr
- DGM News
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