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Thermodynamic assessment of the Mn–Ni–O system

  • Lina Kjellqvist and Malin Selleby
Published/Copyright: May 31, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 101 Issue 10

Abstract

Experimental data on thermodynamic properties and phase relations of the ternary Mn–Ni–O system were reviewed, and by use of the CALPHAD method, a consistent set of model parameters was optimised. The solid oxide phases were modelled using the compound energy formalism. The model allows representation of non-stoichiometry and solid solution in the phases. The distribution of cations between different lattice sites in the two spinel phases is also modelled. The liquid phase is described using the ionic two-sublattice model. The same model is used both for the metallic and the oxide liquid. Good agreement between calculated and experimental values is achieved.

Keywords: Thermodynamic modelling; CALPHAD; Mn–Ni–O system
* Correspondence address, Lina Kjellqvist, Thermo-Calc Software, Norra Stationsgatan 93, Plan 5, SE-11364 Stockholm, Sweden. Tel.: +46 8 410 578 13Fax: +46 8 673 3781. E-mail:

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Received: 2009-8-21
Accepted: 2010-7-30
Published Online: 2013-05-31
Published in Print: 2010-10-01

© 2010, Carl Hanser Verlag, München

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  1. Contents
  2. Contents
  3. Editorial
  4. Editorial October 2010
  5. History
  6. Interactions between dislocations and interfaces – consequences for metal and ceramic plasticity
  7. Deformation mechanisms in yttria-stabilized cubic zirconia single crystals
  8. Basic
  9. Superplasticity in nanocrystalline ceramics: pure grain boundary phenomena or not?
  10. Thermodynamic assessment of the Mn–Ni–O system
  11. Assessment of niobium segregation energy in migrating ferrite/austenite phase interfaces
  12. In-situ synthesis and characterization of Al2O3 nanostructured whiskers in Ti–Al intermetallic matrix composites
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  19. Influence of volume fraction of martensite on the work hardening behaviour of two dual-phase steels with high and low silicon contents
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https://doi.org/10.3139/146.110412
Keywords for this article
Thermodynamic modelling; CALPHAD; Mn–Ni–O system

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. Editorial October 2010
  5. History
  6. Interactions between dislocations and interfaces – consequences for metal and ceramic plasticity
  7. Deformation mechanisms in yttria-stabilized cubic zirconia single crystals
  8. Basic
  9. Superplasticity in nanocrystalline ceramics: pure grain boundary phenomena or not?
  10. Thermodynamic assessment of the Mn–Ni–O system
  11. Assessment of niobium segregation energy in migrating ferrite/austenite phase interfaces
  12. In-situ synthesis and characterization of Al2O3 nanostructured whiskers in Ti–Al intermetallic matrix composites
  13. Texture, structure and properties of Ni-based binary alloy tapes for HTS substrates
  14. Microstructure, texture, grain boundary characteristics and mechanical properties of a cold rolled and annealed ferrite–bainite dual phase steel
  15. Applied
  16. Microstructure and mechanical properties of differently extruded AZ31 magnesium alloy
  17. The role of talc in preparing steatite slurries suitable for spray-drying
  18. Preparation and evaluation of chitosan-gelatin composite scaffolds modified with chondroitin-6-sulphate
  19. Influence of volume fraction of martensite on the work hardening behaviour of two dual-phase steels with high and low silicon contents
  20. Controlled synthesis of prussian blue nanoparticles based on polymyxin B/sodium bis(2-ethylhexyl)sulfosuccinate/water/isooctane reverse microemulsion for glucose biosensors
  21. The melting diagram of the Ti–Dy–Sn system below 40 at.% Sn
  22. Preparation and photocatalytic properties of TiO2 film produced via spin coating
  23. DGM News
  24. Personal
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