Home Physical Sciences Green and Efficient Reverse Micellar Extraction and Recovery of Mixed Ionic Dyes from Textile Effluent
Article
Licensed
Unlicensed Requires Authentication

Green and Efficient Reverse Micellar Extraction and Recovery of Mixed Ionic Dyes from Textile Effluent

  • Narinderjit Kaur , Sangeeta Sharma and Ekta Khosla
Published/Copyright: July 11, 2018
Become an author with De Gruyter Brill
Author Information
Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 55 Issue 4

Abstract

Colored effluents discharged from textile and other industries pose a major threat to the environment. These effluents must be decolorized before discharging into the main streams. The present study explores a solvent extraction method for selective removal of dye from a cationic and anionic dye mixture by treating the dye mixture with reverse micelles of anionic and cationic surfactants in a stepwise manner. The effect of different parameters such as surfactant and dye concentration was also investigated. It has been found that the percentage extraction of dyes increased with increasing surfactant concentration and decreasing dye concentration. UV-visible absorption spectra were analyzed to evaluate the state of the dyes in bulk water before and after extraction with reverse micelles. The dyes were recovered successively by backward extraction and then reused. Their K/S values were also measured.

Kurzfassung

Farbige Abwässer, die aus der Textil- und anderen Industrien stammen, stellen eine große Gefahr für die Umwelt dar. Diese Abwässer müssen vor dem Einleiten in die Hauptströme entfärbt werden. Die vorliegende Arbeit untersucht ein Lösungsmittelextraktionsverfahren zur selektiven Entfernung von Farbstoffen aus einer kationischen und anionischen Farbstoffmischung durch schrittweise Behandlung der Farbstoffmischung mit inversen Mizellen aus anionischen und kationischen Tensiden. Der Einfluss verschiedener Parameter wie die Tensid- und Farbstoffkonzentration wurde ebenfalls untersucht. Es wurde festgestellt, dass die Extraktion von Farbstoffen in Prozent mit zunehmender Tensidkonzentration und abnehmender Farbstoffkonzentration zunahm. UV-Vis-Absorptionsspektren wurden analysiert, um den Zustand der Farbstoffe in der wässerigen Bulkphase vor und nach der Extraktion mit den inversen Mizellen zu bestimmen. Die Farbstoffe wurden nacheinander durch Rückextraktion gewonnen und dann wiederverwendet. Ihre K/S-Werte wurden ebenfalls gemessen.

Key words: Reverse micelles; cationic surfactant; anionic surfactant; solvent extraction; acid dyes
Stichwörter: Umkehrmizellen; kationisches Tensid; anionisches Tensid; Lösungsmittelextraktion; saure Farbstoffe
*Correspondence address, Dr. Ekta Khosla, Department of Chemistry, Hans Raj Mahila Maha Vidyalaya, Jalandhar, Punjab, India, E-Mail:

Mrs. Narinderjit KaurAssistant Professor in Chemistry, KMV, Jalandhar Research scholar, IKGPTU, Kapurthala Publications = 5 Book Published = 1

Dr. Sangeeta Sharma Associate Professor in Chemistry, Shaheed Bhagat Singh State Technical Campus, Ferozepur Publications = 30 Book Published = 1

Dr. Ekta Khosla Associate Professor in Chemistry, HMV, Jalandhar Publications = 40 Book Published = 9

References

1. Houk, V. S.: The genotoxicity of industrial wastes and effluents: a review, Mutation Research/Reviews in Genetic Toxicology.277 (2) (1992) 91–138. 10.1016/0165-1110(92)90001-PSearch in Google Scholar

2. Kant, R.: Textile dyeing industry an environmental hazard, Natural science.4 (1) (2012) 22–26. 10.4236/ns.2012.41004Search in Google Scholar

3. Mathur, N. and Bhatnagar, P.: Mutagenicity assessment of textile dyes from Sanganer (Rajasthan), Journal of Environmental Biology.28 (1) (2007) 123–126. 17717998Search in Google Scholar

4. Robinson, T., McMullan, G., Marchant, R. and Nigam, P.: Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative, Bioresource technology.77 (3) (2001) 247–255. 10.1016/S0960-8524(00)00080-8Search in Google Scholar

5. Xu, X. R., Li, H. B., Wang, W. H. and Gu, J. D.: Decolorization of dyes and textile wastewater by potassium permanganate, Chemosphere.59 (6) (2005) 893–898. 15811419 10.1016/j.chemosphere.2004.11.013Search in Google Scholar

6. Khraisheh, M. A. M., Al-Ghouti, M. A., Allen, S. J. and Ahmad, M. N.: Effect of OH and silanol groups in the removal of dyes from aqueous solution using diatomite, Water Research.39 (5) (2005) 922–932. 15743639 10.1016/j.watres.2004.12.008Search in Google Scholar

7. Golob, V., Vinder, A. and Simonič, M.: Efficiency of the coagulation/flocculation method for the treatment of dyebath effluents. Dyes and pigments67 (2) (2005) 93–97. 10.1016/j.dyepig.2004.11.003Search in Google Scholar

8. Bes-Pia, A., Mendoza-Roca, J. A., Alcaina-Miranda, M. I., Iborra-Clar, A. and Iborra-Clar, M. I.: Combination of physico-chemical treatment and nanofiltration to reuse wastewater of a printing, dyeing and finishing textile industry, Desalination.157 (1–3) (2003) 73–80. 10.1016/S0011-9164(03)00385-0Search in Google Scholar

9. Georgiou, D., Aivazidis, A., Hatiras, J. and Gimouhopoulos, K.: Treatment of cotton textile wastewater using limeandferroussulfate, Water Research.37 (9) (2003) 2248–2250. 10.1016/S0043-1354(02)00481-5Search in Google Scholar

10. Pandit, P. and Basu, S.: Removal of organic dyes from water by liquid–liquid extraction using reverse micelles, J Colloid Interface Sci.245 (1) (2002) 208–214. 16290352 10.1006/jcis.2001.7939Search in Google Scholar PubMed

11. Majhi, S., Sharma, Y. C. and Upadhyay, S. N.: Reverse micelles for the removal of dyes from aqueous solutions, Environ Technol.30 (9) (2009) 879–884. 19803326 10.1080/09593330902926489Search in Google Scholar PubMed

12. Pandit, P. and Basu, S.: Dye and solvent recovery in solvent extraction using reverse micelles for the removal of ionic dyes, Ind Eng Chemistry Research.43 (24) (2004) 7861–7864. 10.1021/ie0402160Search in Google Scholar

13. Pandit, P. and Basu, S.: Removal of ionic dyes from water by solvent extraction using reverse micelles, Environ Sci Technol.38 (8) (2004) 2435–2442. 15116851 10.1021/es030573mSearch in Google Scholar PubMed

14. Ueda, A. C., de Oliveira, L. H., Hioka, N. and Aznar, M.: Liquid– Liquid Extraction of Basic Yellow 28, Basic Blue 41, and Basic Red 46 Dyes from Aqueous Solutions with Reverse Micelles, Journal of Chemical & Engineering Data.56 (3) (2011) 652–657. 10.1021/je1008558Search in Google Scholar

15. Lee, D. W., Hong, W. H. and Hwang, K. Y.: Removal of an organic dye from water using a predispersed solvent extraction, Separation Sci Technol.35 (12) (2000) 1951–1962. 10.1081/SS-100100629Search in Google Scholar

16. Patil, S. and Agrawal, M. A.: Interactions between Dyes and Cetyl-trimethyl Ammonium Bromide, Tenside Surfactants Detergents.48 (3) (2011) 228–231. 10.3139/113.110126Search in Google Scholar

17. Pathania, D. and Sharma, S.: Effect of Surfactants and Electrolyte on Removal and Recovery of Basic Dye by Using FicusCarica Cellulosic Fibers as Biosorbent, Tenside Surfactants Detergents.49 (4) (2012) 306–314.10.3139/113.110196Search in Google Scholar

18. Ali, A., Uzair, S. and Farooq, U.Interactions of Cationic, Anionic and Nonionic Surfactants with Cresol Red Dye in Aqueous Solutions, Conductometric, Tensiometric, and Spectroscopic Studies, Tenside Surfactants Detergents. 54 (4) (2017) 342–352. 10.3139/113.110509Search in Google Scholar

Received: 2018-02-22
Accepted: 2018-04-05
Published Online: 2018-07-11
Published in Print: 2018-07-16

© 2018, Carl Hanser Publisher, Munich

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Review Article
  4. Synthesis, Properties and Applications of Anionic Phosphate Ester Surfactants: A Review
  5. Detergent Ingredients
  6. Biological Surfactants vs. Polysorbates: Comparison of Their Emulsifier and Surfactant Properties
  7. Environmental Chemistry
  8. Green and Efficient Reverse Micellar Extraction and Recovery of Mixed Ionic Dyes from Textile Effluent
  9. Physical Chemistry
  10. Thermodynamic and Interfacial Properties of Cationic Gemini Surfactant in the Presence of Alcohols
  11. Research of Binary Surfactant Mixtures Based on N-Lauroyl Sarcosinate
  12. Surface and Interfacial Properties of Mono and Didodecyl Diphenyl Ether Disulfonates
  13. Application
  14. Adsorption and Surface Properties of Mixtures of Fatty Acid Methyl Ester Ethoxylates and Sodium Dodecylbenzene Sulfonate
  15. Synthesis
  16. Synthesis and Interfacial Tensions of Sodium p-Dimethyl Dodecylbenzene Sulfonates
  17. Synthesis of 4-Hydroxy-4-(4-nitrophenyl)butan-2-one using p-Nitro Benzaldehyde and Acetone in Aqueous Micellar Media using L-Proline
  18. Novel Surfactants
  19. Foam and Rheological Properties of a Kind of Extended Surfactants
  20. Formation of Mixed Micelles of the Environmentally Acceptable Oxy-Diester-Linked Gemini Surfactants with Brij 58
https://doi.org/10.3139/113.110572
Keywords for this article
Reverse micelles; cationic surfactant; anionic surfactant; solvent extraction; acid dyes

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Review Article
  4. Synthesis, Properties and Applications of Anionic Phosphate Ester Surfactants: A Review
  5. Detergent Ingredients
  6. Biological Surfactants vs. Polysorbates: Comparison of Their Emulsifier and Surfactant Properties
  7. Environmental Chemistry
  8. Green and Efficient Reverse Micellar Extraction and Recovery of Mixed Ionic Dyes from Textile Effluent
  9. Physical Chemistry
  10. Thermodynamic and Interfacial Properties of Cationic Gemini Surfactant in the Presence of Alcohols
  11. Research of Binary Surfactant Mixtures Based on N-Lauroyl Sarcosinate
  12. Surface and Interfacial Properties of Mono and Didodecyl Diphenyl Ether Disulfonates
  13. Application
  14. Adsorption and Surface Properties of Mixtures of Fatty Acid Methyl Ester Ethoxylates and Sodium Dodecylbenzene Sulfonate
  15. Synthesis
  16. Synthesis and Interfacial Tensions of Sodium p-Dimethyl Dodecylbenzene Sulfonates
  17. Synthesis of 4-Hydroxy-4-(4-nitrophenyl)butan-2-one using p-Nitro Benzaldehyde and Acetone in Aqueous Micellar Media using L-Proline
  18. Novel Surfactants
  19. Foam and Rheological Properties of a Kind of Extended Surfactants
  20. Formation of Mixed Micelles of the Environmentally Acceptable Oxy-Diester-Linked Gemini Surfactants with Brij 58
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 6.12.2025 from https://www.degruyterbrill.com/document/doi/10.3139/113.110572/html
Scroll to top button