Research of Binary Surfactant Mixtures Based on N-Lauroyl Sarcosinate
-
Juan Cui
and Hujun Xu
Abstract
Surface properties of binary surfactant systems of N-lauroyl sarcosinate (LS) with fatty alcohol polyoxyethylene ether (AEO9), dodecyl trimethyl ammonium chloride (DTAC) and dodecyl dimethyl betaine (BS-12) have been investigated in aqueous NaCl (0.1 mol · L−1) solution at (298 ± 0.1) K, respectively. Synergistic parameters of the two components in both mixed micelles and mixed adsorption layers were obtained by calculations. Furthermore, we applied the regular solution theory on the mixed systems when synergism in mixed micelle formation, surface tension reduction efficiency and surface tension effectiveness was researched. The results show that there are synergistic effects in the mixed systems, the surface performances of the mixtures are significantly better than that of any single component in the mixed systems. The result coincides with the relevant theories of the ability of mixed micelle formation, surface tension reduction efficiency and surface tension reduction effectiveness.
Kurzfassung
Die Oberflächeneigenschaften binärer Tensidsysteme aus N-Lauroylsarcosinat (LS) mit Fettalkoholpolyoxyethylenether (AEO9), Dodecyltrimethylammoniumchlorid (DTAC) und Dodecyldimethylbetain (BS-12) wurden in wässriger 0,1 mol · L−1 NaCl-Lösung bei (298 ± 0,1) K untersucht. Die synergistischen Parameter der beiden Komponenten sowohl in den Mischmizellen als auch in den Mischadsorptionsschichten wurden berechnet. Darüber hinaus wandten wir die reguläre Lösungstheorie auf die Mischsysteme an, wenn der Synergismus bei der Bildung von Mischmizellen, die Verringerung der Oberflächenspannung und die Oberflächenspannung untersucht wurden. Die Ergebnisse zeigen, dass synergistische Effekte in den Mischsystemen vorliegen und die Oberflächenleistungen der Mischsysteme signifikant besser sind als die jeder einzelnen Komponente in den Mischsystemen. Das Ergebnis stimmt mit den relevanten Theorien über die Fähigkeit der Mischmizellenbildung, die Verringerung der Oberflächenspannung und die Wirksamkeit der Verringerung der Oberflächenspannung überein.
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© 2018, Carl Hanser Publisher, Munich
Articles in the same Issue
- Contents/Inhalt
- Contents
- Review Article
- Synthesis, Properties and Applications of Anionic Phosphate Ester Surfactants: A Review
- Detergent Ingredients
- Biological Surfactants vs. Polysorbates: Comparison of Their Emulsifier and Surfactant Properties
- Environmental Chemistry
- Green and Efficient Reverse Micellar Extraction and Recovery of Mixed Ionic Dyes from Textile Effluent
- Physical Chemistry
- Thermodynamic and Interfacial Properties of Cationic Gemini Surfactant in the Presence of Alcohols
- Research of Binary Surfactant Mixtures Based on N-Lauroyl Sarcosinate
- Surface and Interfacial Properties of Mono and Didodecyl Diphenyl Ether Disulfonates
- Application
- Adsorption and Surface Properties of Mixtures of Fatty Acid Methyl Ester Ethoxylates and Sodium Dodecylbenzene Sulfonate
- Synthesis
- Synthesis and Interfacial Tensions of Sodium p-Dimethyl Dodecylbenzene Sulfonates
- Synthesis of 4-Hydroxy-4-(4-nitrophenyl)butan-2-one using p-Nitro Benzaldehyde and Acetone in Aqueous Micellar Media using L-Proline
- Novel Surfactants
- Foam and Rheological Properties of a Kind of Extended Surfactants
- Formation of Mixed Micelles of the Environmentally Acceptable Oxy-Diester-Linked Gemini Surfactants with Brij 58
Articles in the same Issue
- Contents/Inhalt
- Contents
- Review Article
- Synthesis, Properties and Applications of Anionic Phosphate Ester Surfactants: A Review
- Detergent Ingredients
- Biological Surfactants vs. Polysorbates: Comparison of Their Emulsifier and Surfactant Properties
- Environmental Chemistry
- Green and Efficient Reverse Micellar Extraction and Recovery of Mixed Ionic Dyes from Textile Effluent
- Physical Chemistry
- Thermodynamic and Interfacial Properties of Cationic Gemini Surfactant in the Presence of Alcohols
- Research of Binary Surfactant Mixtures Based on N-Lauroyl Sarcosinate
- Surface and Interfacial Properties of Mono and Didodecyl Diphenyl Ether Disulfonates
- Application
- Adsorption and Surface Properties of Mixtures of Fatty Acid Methyl Ester Ethoxylates and Sodium Dodecylbenzene Sulfonate
- Synthesis
- Synthesis and Interfacial Tensions of Sodium p-Dimethyl Dodecylbenzene Sulfonates
- Synthesis of 4-Hydroxy-4-(4-nitrophenyl)butan-2-one using p-Nitro Benzaldehyde and Acetone in Aqueous Micellar Media using L-Proline
- Novel Surfactants
- Foam and Rheological Properties of a Kind of Extended Surfactants
- Formation of Mixed Micelles of the Environmentally Acceptable Oxy-Diester-Linked Gemini Surfactants with Brij 58