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Microscopic Evidence for the Correlation of Micellar Structures and Counterion Binding Constant for Flexible Nanoparticle Catalyzed Piperidinolysis of PS− in Colloidal System

  • Khalisanni Khalid , Sharifuddin Md. Zain , Vicit Rizal Eh Suk and M. Niyaz Khan
Published/Copyright: May 8, 2017
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 54 Issue 3

Abstract

The interest to determine the ionization degree of counterion initiates the need to study the relationship between counterion binding constant (RXBr) and the growth of self-assembly micellar structure. This paper discussed the microscopic evidence for the correlation of counterion binding constant values and micellar structure of cationic surfactants in the presence of phenolates and 2-ethyl phenolates ions in flexible nanoparticle (FN)-system of ionized phenyl salicylate-catalyzed piperidinolysis. The sizes of micelles were determined by particle size analysis. Transmission electron microscopy (TEM) results showed a spherical micellar structure for phenolates and 2-ethyl phenolates ions at counterion binding constant values 6.3 ± 1.0 and 24.0 ± 1.1 respectively. A study using a semi-emperical kinetic technique in published article proved that the suggested micellar structures at respective counterion binding constant values corresponded with the present microscopic evidence.

Kurzfassung

Das Interesse, den Ionisationsgrad des Gegenions zu bestimmen, bildete den Ausgangspunkt, die Beziehung zwischen der Gegenionenbindungskonstante (RXBr) und dem Wachstum einer selbst-organisierenden mizellaren Struktur zu untersuchen. In diesem Beitrag wurde der mikroskopische Nachweis für die Korrelation der Gegenionbindungskonstanten und der mizellaren Struktur kationischer Tenside in Gegenwart von Phenolat- und 2-Ethylphenolat-Ionen in einem flexiblen Nanopartikelsystem (FN-System) der ionischen durch Phenylsalicylat katalysierten Piperidinolyse diskutiert. Die Größen der Mizellen wurden durch Partikelgrößenanalyse bestimmt. Die Transmissionselektronenmikroskopie (TEM) zeigte eine kugelige mizellare Struktur für Phenolat- und 2-Ethylphenolat-Ionen bei RXBr von 6,3 ± 1,0 bzw. von 24,0 ± 1,1. Die mittels des hier eingesetzten mikroskopischen Nachweises erhaltenen Gegenionenbindungskonstanten und die sich daraus ergebenden mizellaren Strukturen stimmen mit denen einer bereits veröffentlichten Untersuchung, wo eine semi-empirische kinetische Technik verwendet wurde, überein.

Key words: Counterion binding constant; flexible nanoparticle; spherical micelles
Stichwörter: Gegenionenbindungskonstante; flexible Nanopartikel; sphärische Mizellen
*Correspondence address, Professor Dr. Mohammad Niyaz Khan, Department of Chemistry, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia, Tel: +603-79674163, E-Mail:
**Khalisanni Khalid, Laboratory Management Program, Laboratory and Technical Service Centre, Malaysian Agricultural Research and Development Institute (MARDI), 43400 Serdang, Selangor, Malaysia, Tel.: +603-89437388, E-Mail: ,

Khalisanni Khalid was born in 1985. He is currently on study leave from Malaysian Agricultural Research and Development Institute (MARDI) for his PhD research in micellar catalysis and mechanism at University of Malaya. He is a Bright Sparks scholar. He's also acknowledged and listed in Who's Who in Science and Engineering 2016–2017.

Sharifuddin Md Zain is a Professor in Department of Chemistry, Faculty of Science, University of Malaya. His research interests encompass computational chemistry and chemical education.

Vicit Rizal Eh Suk was born in 1985. He is now taking a doctoral degree in surfactant chemistry at University of Malaya.

Mohammad Niyaz Khan is a Professor in Department of Chemistry, Faculty of Science, University of Malaya. His research interests encompass micellar catalysis and mechanism.

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Received: 2016-07-30
Accepted: 2016-11-16
Published Online: 2017-05-08
Published in Print: 2017-05-15

© 2017, Carl Hanser Publisher, Munich

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  2. Contents
  3. Detergent/Enzymes
  4. Lactobacillus brevis Lipase: Purification, Immobilization onto Magnetic Florosil NPs, Characterization and Application as a Detergent Additive
  5. Study on the Interaction Between Cellulase and Surfactants
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  8. Synergistic Effect of Cationic Surfactants on the Rheological Behavior of Erucyl Amidosulfobetaine
  9. Microscopic Evidence for the Correlation of Micellar Structures and Counterion Binding Constant for Flexible Nanoparticle Catalyzed Piperidinolysis of PS− in Colloidal System
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https://doi.org/10.3139/113.110499
Keywords for this article
Counterion binding constant; flexible nanoparticle; spherical micelles

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Detergent/Enzymes
  4. Lactobacillus brevis Lipase: Purification, Immobilization onto Magnetic Florosil NPs, Characterization and Application as a Detergent Additive
  5. Study on the Interaction Between Cellulase and Surfactants
  6. Physical Chemistry
  7. Study of Ionic Liquid Microemulsions: Ethylammonium Nitrate/TritonX-100/Cyclohexane
  8. Synergistic Effect of Cationic Surfactants on the Rheological Behavior of Erucyl Amidosulfobetaine
  9. Microscopic Evidence for the Correlation of Micellar Structures and Counterion Binding Constant for Flexible Nanoparticle Catalyzed Piperidinolysis of PS− in Colloidal System
  10. Application
  11. Effect of Surface Modification on the Dispersion, Thermal Stability and Crystallization Properties of PET/CaCO3 Nanocomposites
  12. Environmental Chemistry
  13. Inhibition of Calcium Carbonate Scale Using an Environmental Friendly Scale Inhibitor
  14. Novel Surfactants
  15. Study on the Properties of Mixed Micelles of Disodium Salt of 3-({2-[(2-Carboxy-ethyl)-dodecanoyl-amino]-ethyl}-dodecanoyl-amino)-propionic Acid in Solution Systems
  16. Synthesis
  17. Macrocyclic Schiff Base Metal Complexes Derived from Isatin: Structural Activity Relationship and DFT Calculations
  18. Quaternary Ammonium Gemini Surfactants Used in Enhanced Oil Recovery: Synthesis, Properties, and Flooding Experiments
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