Study on the Properties of Mixed Micelles of Disodium Salt of 3-({2-[(2-Carboxy-ethyl)-dodecanoyl-amino]-ethyl}-dodecanoyl-amino)-propionic Acid in Solution Systems
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Kai Xu
Abstract
This study focuses on the properties of mixed micelles of di-sodium salt of 3-({2-[(2-Carboxy-ethyl)-dodecanoyl-amino]-ethyl}-dodecanoyl-amino)-propionic acid (symbolized as DLMC) in solution systems (DLMC/DTAB and DLMC/AEO6). The micro-polarity of the mixed micelles was determined by the fluorospectrophotometer. When the concentration is above CMC, the micellar micro-polarity and the aggregation number (Nm) of the mixed micelles were measured by a steady state fluorescence quenching method. The average hydrodynamic radius (Rh) of the mixed micelles was studied by means of dynamic light scattering. The results show that the micro-polarity of micelle nucleus decreases obviously with increasing concentration. The aggregation number of DLMC mixed systems is smaller than that of single surfactants. The difference of the proportion of the two surfactants has little effect on the aggregation number of mixed systems. It is easy to generate molecular aggregates with lower curvature from DLMC than the corresponding monomeric surfactant (DTAB), and DLMC can generate huge linear micelles at low concentrations when mixed with other surfactants.
Kurzfassung
Diese Studie konzentriert sich auf die Eigenschaften von Mischmizellen des Di-Natriumsalzes der 3-({2-[(2-Carboxy-ethyl)-dodecanoyl-amino]-ethyl}-dodecanoyl-amino)-propionsäure (DLMC) in Lösungen (DLMC/DTAB und DLMC/AEO6). Die Mikropolarität der Mischmizellen wurde durch ein Fluorospektrophotometer bestimmt. Wenn die Konzentration über der CMC liegt, wurden die mizellare Mikropolarität und die Aggregationszahl (Nm) der Mischmizellen durch Fluoreszenzlöschverfahren im stationären Zustand gemessen. Der mittlere hydrodynamische mizellare Radius (Rh) der Mischmizellen wurde mittels dynamischer Lichtstreuung untersucht. Die Ergebnisse zeigen, dass die Mikropolarität des Mizellenkerns deutlich mit zunehmender Konzentration abnimmt. Die Aggregationszahl der DLMC-Mischsystemene ist kleiner als die der einzelnen Tenside. Die Differenz des Anteils der beiden Tenside hat wenig Einfluss auf die Aggregationszahl der Mischsysteme. Es ist leicht, molekulare Aggregate mit geringerer Krümmung aus DLMC zu erzeugen als aus dem entsprechenden monomeren Tensid DTAB. DLMC kann riesige lineare Mizellen bei geringen Konzentrationen erzeugen, wenn es mit anderen Tensiden gemischt ist.
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© 2017, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Detergent/Enzymes
- Lactobacillus brevis Lipase: Purification, Immobilization onto Magnetic Florosil NPs, Characterization and Application as a Detergent Additive
- Study on the Interaction Between Cellulase and Surfactants
- Physical Chemistry
- Study of Ionic Liquid Microemulsions: Ethylammonium Nitrate/TritonX-100/Cyclohexane
- Synergistic Effect of Cationic Surfactants on the Rheological Behavior of Erucyl Amidosulfobetaine
- Microscopic Evidence for the Correlation of Micellar Structures and Counterion Binding Constant for Flexible Nanoparticle Catalyzed Piperidinolysis of PS− in Colloidal System
- Application
- Effect of Surface Modification on the Dispersion, Thermal Stability and Crystallization Properties of PET/CaCO3 Nanocomposites
- Environmental Chemistry
- Inhibition of Calcium Carbonate Scale Using an Environmental Friendly Scale Inhibitor
- Novel Surfactants
- Study on the Properties of Mixed Micelles of Disodium Salt of 3-({2-[(2-Carboxy-ethyl)-dodecanoyl-amino]-ethyl}-dodecanoyl-amino)-propionic Acid in Solution Systems
- Synthesis
- Macrocyclic Schiff Base Metal Complexes Derived from Isatin: Structural Activity Relationship and DFT Calculations
- Quaternary Ammonium Gemini Surfactants Used in Enhanced Oil Recovery: Synthesis, Properties, and Flooding Experiments
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Detergent/Enzymes
- Lactobacillus brevis Lipase: Purification, Immobilization onto Magnetic Florosil NPs, Characterization and Application as a Detergent Additive
- Study on the Interaction Between Cellulase and Surfactants
- Physical Chemistry
- Study of Ionic Liquid Microemulsions: Ethylammonium Nitrate/TritonX-100/Cyclohexane
- Synergistic Effect of Cationic Surfactants on the Rheological Behavior of Erucyl Amidosulfobetaine
- Microscopic Evidence for the Correlation of Micellar Structures and Counterion Binding Constant for Flexible Nanoparticle Catalyzed Piperidinolysis of PS− in Colloidal System
- Application
- Effect of Surface Modification on the Dispersion, Thermal Stability and Crystallization Properties of PET/CaCO3 Nanocomposites
- Environmental Chemistry
- Inhibition of Calcium Carbonate Scale Using an Environmental Friendly Scale Inhibitor
- Novel Surfactants
- Study on the Properties of Mixed Micelles of Disodium Salt of 3-({2-[(2-Carboxy-ethyl)-dodecanoyl-amino]-ethyl}-dodecanoyl-amino)-propionic Acid in Solution Systems
- Synthesis
- Macrocyclic Schiff Base Metal Complexes Derived from Isatin: Structural Activity Relationship and DFT Calculations
- Quaternary Ammonium Gemini Surfactants Used in Enhanced Oil Recovery: Synthesis, Properties, and Flooding Experiments
