Study of CLSI-M44-A Disk Diffusion Method for Determining the Susceptibility of Candida Species against Novel Complexes Derived from Copper Stearate with 2-Amino Benzothiazoles
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N. Mathur
Abstract
The study of binuclear complexes of copper(II) is a very active and highly interesting field due to their significance in bioinorganic chemistry, magneto chemistry, material science, superconductivity and multi electron redox chemistry. Due to the surface-active properties of copper(II) stearate with 2-aminobenzothiazole, the complexes exhibit many applications in agrochemical industries as dispersing agents, foaming and wetting agents. In the present investigation solid complexes of Cu(II) stearate with 2-amino-6-methoxybenzothiazole and 2-amino-6-nitrobenzothiazole have been synthesized and characterized by elemental analysis and their IR, NMR, ESR spectral studies. All the synthesized complexes are coloured and their purity was checked by Thin Layer Chromatography.
Kurzfassung
Das Studium von binuklearen Komplexen aus Kupfer(II) ist ein sehr aktives und hoch interessantes Forschungsfeld wegen seiner Bedeutung für die bioanorganische Chemie, die Magnetochemie, die Materialwissenschaft, Supraleitung und Multielektron-Redoxchemie. Wegen der oberflächenaktiven Eigenschaften von Kupfer(II)-Stearat mit 2-Aminobenzothiazolen besitzen die Komplexe auch Anwendungen in der Agrochemie als Dispergatoren, Schäumer und Benetzer. In dieser Untersuchung wurden die festen Komplexe aus Cu(II)-Stearat mit 2-Amino-6-methoxybenzothiazol und 2-Amino-6-nitrobenzothiazol synthetisiert und durch Elementanalyse charakterisiert. Ihre IR-, NMR und ESR-Spektren wurden gemessen. Alle synthetisierten Komplexe waren farbig und ihre Reinheit wurde mit Hilfe der Dünnschicht-Chromatografie überprüft.
References
1. Raper, E. S.: Coord. Chem. Rev.153 (1996) 199. 10.1016/0010-8545(95)01233-8Suche in Google Scholar
2. Raper, E. S.: Coord. Chem. Rev.165 (1997) 475.Suche in Google Scholar
3. Lobana, T. S., Seema, P. and Castineiras, A.: Polyhedron16 (1997) 4023. 10.1016/S0277-5387(97)00188-5Suche in Google Scholar
4. Aslanidis, P., Hadjikakou, S. K., Karagiannidis, P., Kojic-Prodic, B. and Luic, M.: Polyhedron13 (1994) 3119. 10.1016/S0277-5387(00)83680-3Suche in Google Scholar
5. Povey, D. C., Smith, G. W., Lobana, T. S. and Bhatia, P. K.: Crystallogr. J. Spectrosc. Res.21 (1991) 9. 10.1007/BF01158967Suche in Google Scholar
6. (a) Skoulika, S.: Inorg. Chim. Acta156 (1991) 207. (b) Lobana, T. S., Bhatia, P. K. and Tiekink, E. R. T.,: J. Chem. Soc., Dalton Trans (1989) 749. 10.1016/S0020-1693(00)83016-9Suche in Google Scholar
7. Lobana, T. S., Singh, Randhir, Sandhu, M. K. and Tiekink, E. R. T.: J. Coord. Chem.24 (1991) 29. 10.1080/00958979109409733Suche in Google Scholar
8. Tiekink, E. R. T., LobanaT.S. and Singh, Randhir: J. Crystallogr. Spectrosc. Res.21 (1991) 205. 10.1007/BF01161066Suche in Google Scholar
9. Lobana, T. S., Verma, Renu and Castineiras, A.: Polyhedron17 (1998) 3753. 10.1016/S0277-5387(98)00177-6Suche in Google Scholar
10. Tiekink, E. R. T., Lobana, T. S., Verma, R., and Mahajan, R.: Z. Kristallogr. NCS214 (1999) 513. 10.1524/zkri.1999.214.2.124Suche in Google Scholar
11. Ojha, K. G. and Mathur, N.: Asian J. Chem.4 (1992) 924.Suche in Google Scholar
12. Afroz, Afaq: Ph. D. Thesis, University of Rajasthan, Jaipur, India, (1993).Suche in Google Scholar
13. Smitha, Nair, Garg, S. P. and Sha, Primila: J. Indian Chem. Soc.83 (2006) 31.Suche in Google Scholar
14. Zhang, Pei-Zhi and Jan, Wu: J. Indian Chem. Soc.81 (2004) 501.Suche in Google Scholar
15. Nodiff, E. A. and Hausman, M.: J. Org. Chem.31 (1966) 625. 10.1021/jo01340a526Suche in Google Scholar PubMed
16. Vasundhara, G., Jayshree, G. and Kurup, G.: Bulletin of Environmental Contamination and Toxicology 72, 1122, Springer Verly, New York (2004).Suche in Google Scholar
17. Basset, J., Denney, R. C., Jeffery, G. H. and Medham, J.: Vogel's Text book of Quantitative Inorganic Analysis (4 Ed.)Longman, London (1985).Suche in Google Scholar
18. Nakamoto, K.: Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, New York (1978).Suche in Google Scholar
19. Panda, A. K., Dash, D. C., Mishra and Mahanthy, H.: Indian J. Chem. Soc. A35 (1996) 376.Suche in Google Scholar
20. Silverstein, Bussler and Morrill: Spectrometric Identification of Organic Compounds (5 Ed.) John Wiley and Sons (1991).Suche in Google Scholar
21. Hathaway, J. and Tomlinson, A. A. G.: Coord. Chem. Rev.5 (1970) 143. 10.1016/S0010-8545(00)80135-6Suche in Google Scholar
22. Antosik, N. M. D., Brown, A. A., Connel, Mc. and Porte, A. L.: J. Chem. Soc. A (1969) 545. 10.1039/j19690000545Suche in Google Scholar
23. Boas, J. F., Dunhil, R. H., Pilbrow, J. R., Shrivastava, R. C. and Smith, T. D.: J. Chem. Soc. A (1969) 94. 10.1039/j19690000094Suche in Google Scholar
24. Hathway, B. J.: Essays in Chemistry edited by J. N.Bradley and R. D.Gillard, Academic Press, New York (1971) 61.Suche in Google Scholar
25. National Committee for Clinical Laboratory Standards: Reference Method for Antifungal Disc Diffusion Susceptibility Testing of Yeasts Propose Guideline M44-A. NCCLS, Wayne, PA, USA (2004).Suche in Google Scholar
26. National Committee for Clinical Laboratory Standards: Reference Method for Broth Dilution Antifungal Susceptibility Testing of Yeasts: Approved standard M27-A2, NCCLS, Wayne, PA, USA (2002).Suche in Google Scholar
27. Meis, J., Petrou, M., Bille, J., Ellis, D. and Gibbs, D.: Diagn. Microbiol. Infect. Dis.36 (2000) 215. 10.1016/S0732-8893(99)00152-2Suche in Google Scholar
28. Vandenbossche, I., Vaneechoutte, M., Vandevenne, M., De Baere, T. and Verschraegen, G.: J. Clin. Microbiol.40 (2002) 918. 10.1128/JCM.40.3.918-921.2002Suche in Google Scholar PubMed PubMed Central
29. Wanger, A., Mills, K., Nelson, P. W. and Rex, J. H.: Antimicrob. Agents Chemothessr39 (1995) 2520. 10.1128/AAC.39.11.2520Suche in Google Scholar PubMed PubMed Central
© 2011, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Editorial
- Rückblick auf zwei erfolgreiche Jahre 2009/2010
- Application
- Surface Activity and Adsorption Properties of New Perfluorinated Carbohydrate Surfactants
- Novel Surfactants
- Study of Glycerol Residue as a Carbon Source for Production of Rhamnolipids by Pseudomonas aeruginosa (ATCC 10145)
- Study of CLSI-M44-A Disk Diffusion Method for Determining the Susceptibility of Candida Species against Novel Complexes Derived from Copper Stearate with 2-Amino Benzothiazoles
- European Detergents Conference
- Bicontinuous Microemulsion as Reaction Medium for ω-Transaminase Catalysed Biotransformations
- Physical Chemistry
- SAXS Study on Azithromycin Loaded Nonionic Microemulsions
- Effects of Alkaline Cations on Self-assembly of Cetylpyridinium Surfactants
- Influence of Surfactants on Release of Chlorhexidine from Hydrogels
- Environmental Chemistry
- Influence of Surfactants on the Performance of Calcium Phosphate Scale Inhibitors
- Technical Chemistry
- Preparation and Characterization of a Phosphorous Free and Non-Nitrogen Antiscalant in Industrial Cooling Systems
- Preparation and Characterization of Pillared Derivatives from δ-Layered Sodium Disilicate and their Tribological Properties in Liquid Paraffin
- Synthesis
- An Efficient and Mild Procedure for the Preparation of Aldonic Acids via Oxidation of D-Sucrose by Employing N-Bromophthalimide Oxidant and Micellar System
- Synthesis and Properties of Some N-Acylethylenediamine Triacetic Acid Chelating Surfactants
- Conference and Meeting Report
- Sixth European Detergents Conference Report
- GDCh-Intensive Course Surfactants: Detergents, Cosmetics, Technical Applications
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Editorial
- Rückblick auf zwei erfolgreiche Jahre 2009/2010
- Application
- Surface Activity and Adsorption Properties of New Perfluorinated Carbohydrate Surfactants
- Novel Surfactants
- Study of Glycerol Residue as a Carbon Source for Production of Rhamnolipids by Pseudomonas aeruginosa (ATCC 10145)
- Study of CLSI-M44-A Disk Diffusion Method for Determining the Susceptibility of Candida Species against Novel Complexes Derived from Copper Stearate with 2-Amino Benzothiazoles
- European Detergents Conference
- Bicontinuous Microemulsion as Reaction Medium for ω-Transaminase Catalysed Biotransformations
- Physical Chemistry
- SAXS Study on Azithromycin Loaded Nonionic Microemulsions
- Effects of Alkaline Cations on Self-assembly of Cetylpyridinium Surfactants
- Influence of Surfactants on Release of Chlorhexidine from Hydrogels
- Environmental Chemistry
- Influence of Surfactants on the Performance of Calcium Phosphate Scale Inhibitors
- Technical Chemistry
- Preparation and Characterization of a Phosphorous Free and Non-Nitrogen Antiscalant in Industrial Cooling Systems
- Preparation and Characterization of Pillared Derivatives from δ-Layered Sodium Disilicate and their Tribological Properties in Liquid Paraffin
- Synthesis
- An Efficient and Mild Procedure for the Preparation of Aldonic Acids via Oxidation of D-Sucrose by Employing N-Bromophthalimide Oxidant and Micellar System
- Synthesis and Properties of Some N-Acylethylenediamine Triacetic Acid Chelating Surfactants
- Conference and Meeting Report
- Sixth European Detergents Conference Report
- GDCh-Intensive Course Surfactants: Detergents, Cosmetics, Technical Applications