Startseite Effects of Alkaline Cations on Self-assembly of Cetylpyridinium Surfactants
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Effects of Alkaline Cations on Self-assembly of Cetylpyridinium Surfactants

  • W. Müller , Ch. Déjugnat , O. Diat und Th. Zemb
Veröffentlicht/Copyright: 5. April 2013
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 48 Heft 1

Abstract

Here we study the influence of alkaline cations on the self-assembly of cetylpyridinium chloride and cetylpyridinium nitrate. It is known that the anionic counterions have a strong influence on the solubility and self-assembly properties of cationic surfactants. However, in this paper we will show that monovalent cations have also an influence which is weaker but detectable. Scattering techniques (X-Ray, light) were used to obtain structural information about the aggregation as a function of the temperature and the ionic strength. The results are interpreted in terms of ion pair adsorption at the micellar interface, depending on the ionic strength.

Kurzfassung

In diesem Beitrag studieren wir die Einflüsse von Alkalikationen auf die Mizellisierung von Cetylpyridiniumchlorid und -nitrat. Es ist bekannt, dass anionische Gegenionen die Löslichkeit und Selbstaggregation kationischer Tenside maßgeblich beeinflussen, jedoch gibt es einen schwachen, aber messbaren Einfluss von monovalenten Kationen, auf welchen in diesem Artikel genauer eingegangen werden soll. Streutechniken (Licht, Röntgen) wurden angewandt, um strukturelle Informationen zur Selbstaggregation in Abhängigkeit von Temperatur und Ionenstärke zu erhalten. Die Ergebnisse werden hinsichtlich der Adsorption von Ionenpaaren an der mizellaren Grenzfläche ausgewertet.

Key words:: Cetylpyridinium; cationic surfactants; Hofmeister series; Krafft temperature; ionic extraction
Stichwörter:: Cetylpyridinium; kationische Tenside; Hofmeister-Serie; Krafft-Temperatur; Ionenextraktion
∗ Dr. Olivier Diat, UMR 5257 – Institut de Chimie Séparative de Marcoule, Bat. 426 – CEA Marcoule, 30207 Bagnols-sur-Cèze CEDEX, France, Tel.: +(33)466339209, Fax: +(33)466337611. E-Mail:

Wolfram Müller studied chemistry at the University of Regensburg (GERMANY) where he obtained his master degree. He is currently Ph.D. student at the Institute of Separation Chemistry of Marcoule (FRANCE) and working on models systems for the study of liquid-solid extraction for separating metal cations by amphiphiles.

Christophe Déjugnat obtained his Ph.D. in 2001 from the University of Toulouse III (FRANCE), working on chiral self-assemblies. He completed his postdoctoral work at the Max Planck Institute of Colloids and Interfaces (Potsdam, GERMANY), before joining the ICSM in 2006 as a CNRS permanent scientist to work on ion separation using self-assembled systems. He recently joined the IMRCP laboratory in Toulouse to study labile peptide-based surfactants.

Olivier Diat obtained his Ph.D. in 1992 from the University of Bordeaux 1, working on the rheology of lyotropic liquid crystal phases. He worked 7 years at the ESRF on the high brilliance beamline ID2 and then obtained a permanent position as a researcher in CEA-Grenoble, working on proton exchange membrane for fuel cell application. Since 2007, he is scientist at ICSM responsible of the “scattering” team as well as the “ions at interfaces” laboratory.

Thomas Zemb obtained his Ph.D. in1985 from the University of Paris 11, he is Professor at the INSTN (FRANCE), and he is senior scientist, has received the Humboldt-Gay Lussac 2009 award and is currently manager of the ICSM.

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Received: 2010-07-05
Published Online: 2013-04-05
Published in Print: 2011-01-01

© 2011, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Editorial
  6. Rückblick auf zwei erfolgreiche Jahre 2009/2010
  7. Application
  8. Surface Activity and Adsorption Properties of New Perfluorinated Carbohydrate Surfactants
  9. Novel Surfactants
  10. Study of Glycerol Residue as a Carbon Source for Production of Rhamnolipids by Pseudomonas aeruginosa (ATCC 10145)
  11. Study of CLSI-M44-A Disk Diffusion Method for Determining the Susceptibility of Candida Species against Novel Complexes Derived from Copper Stearate with 2-Amino Benzothiazoles
  12. European Detergents Conference
  13. Bicontinuous Microemulsion as Reaction Medium for ω-Transaminase Catalysed Biotransformations
  14. Physical Chemistry
  15. SAXS Study on Azithromycin Loaded Nonionic Microemulsions
  16. Effects of Alkaline Cations on Self-assembly of Cetylpyridinium Surfactants
  17. Influence of Surfactants on Release of Chlorhexidine from Hydrogels
  18. Environmental Chemistry
  19. Influence of Surfactants on the Performance of Calcium Phosphate Scale Inhibitors
  20. Technical Chemistry
  21. Preparation and Characterization of a Phosphorous Free and Non-Nitrogen Antiscalant in Industrial Cooling Systems
  22. Preparation and Characterization of Pillared Derivatives from δ-Layered Sodium Disilicate and their Tribological Properties in Liquid Paraffin
  23. Synthesis
  24. An Efficient and Mild Procedure for the Preparation of Aldonic Acids via Oxidation of D-Sucrose by Employing N-Bromophthalimide Oxidant and Micellar System
  25. Synthesis and Properties of Some N-Acylethylenediamine Triacetic Acid Chelating Surfactants
  26. Conference and Meeting Report
  27. Sixth European Detergents Conference Report
  28. GDCh-Intensive Course Surfactants: Detergents, Cosmetics, Technical Applications
https://doi.org/10.3139/113.110102
Schlagwörter für diesen Artikel
Cetylpyridinium; cationic surfactants; Hofmeister series; Krafft temperature; ionic extraction

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Editorial
  6. Rückblick auf zwei erfolgreiche Jahre 2009/2010
  7. Application
  8. Surface Activity and Adsorption Properties of New Perfluorinated Carbohydrate Surfactants
  9. Novel Surfactants
  10. Study of Glycerol Residue as a Carbon Source for Production of Rhamnolipids by Pseudomonas aeruginosa (ATCC 10145)
  11. Study of CLSI-M44-A Disk Diffusion Method for Determining the Susceptibility of Candida Species against Novel Complexes Derived from Copper Stearate with 2-Amino Benzothiazoles
  12. European Detergents Conference
  13. Bicontinuous Microemulsion as Reaction Medium for ω-Transaminase Catalysed Biotransformations
  14. Physical Chemistry
  15. SAXS Study on Azithromycin Loaded Nonionic Microemulsions
  16. Effects of Alkaline Cations on Self-assembly of Cetylpyridinium Surfactants
  17. Influence of Surfactants on Release of Chlorhexidine from Hydrogels
  18. Environmental Chemistry
  19. Influence of Surfactants on the Performance of Calcium Phosphate Scale Inhibitors
  20. Technical Chemistry
  21. Preparation and Characterization of a Phosphorous Free and Non-Nitrogen Antiscalant in Industrial Cooling Systems
  22. Preparation and Characterization of Pillared Derivatives from δ-Layered Sodium Disilicate and their Tribological Properties in Liquid Paraffin
  23. Synthesis
  24. An Efficient and Mild Procedure for the Preparation of Aldonic Acids via Oxidation of D-Sucrose by Employing N-Bromophthalimide Oxidant and Micellar System
  25. Synthesis and Properties of Some N-Acylethylenediamine Triacetic Acid Chelating Surfactants
  26. Conference and Meeting Report
  27. Sixth European Detergents Conference Report
  28. GDCh-Intensive Course Surfactants: Detergents, Cosmetics, Technical Applications
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