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Synthesis of BaO/NiO/rGO nanocomposite for supercapacitor application

  • Nallathambi Anisha , Rathinam Yuvakkumar ORCID logo EMAIL logo , Ganesan Ravi , Mariyappan Thambidurai and Dhayalan Velauthapillai
Published/Copyright: June 11, 2024

Abstract

Considering the global energy crisis, alternative energy resources requirement is rising gradually. In light of dwindling energy resources, we turn to renewable alternatives. Storing this energy for future utilization remains a pressing endeavor. The ideal storage device should possess intensified energy density, power density, and cyclic stability. In this study, we have synthesized metal oxide with carbon based material nanocomposite such as BaO/NiO, BaO/NiO/rGO through cost effective co-precipitation method and their comparative performance for supercapacitor application were studied. Various characterizations were taken for the above synthesized material. X-ray diffraction (XRD) study confirmed the material formation and their crystallinity of the nanocomposite. BaO has tetragonal structure which was confirmed through JCPDS card number 26-0178 and NiO has rhombohedral structure which was confirmed through JCPDS card number 89-7390. To study electrochemical behaviour of electrode material and its cyclic stability, cyclic voltammetry (CV), galvanostatic charge–discharge (GCD) and electrochemical impedance spectroscopy (EIS) studies was executed. BaO/NiO/rGO possesses 1072 F/g specific capacitance at 0.3 A/g in aqueous 1 M KOH. The electrochemical action of hybrid device was setup and it revealed 224 F/g at 0.3 A/g within the charging potential of 1.6 V. Capacitive retention of 97.6 % was achieved by asymmetric hybrid supercapacitor even after 5000 cycles at 10 A/g, this shows prepared nanocomposite exceptional cyclic stability in energy storage application.


Corresponding authors: Rathinam Yuvakkumar, Department of Physics, Alagappa University, Karaikudi 630003, Tamil Nadu, India, E-mail:

Funding source: UGC-SAP grant

Funding source: DST-FIST grant

Funding source: DST-PURSE grant

Funding source: RUSA grant

  1. Research ethics: Not applicable.

  2. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: This work was supported by UGC-SAP, DST-FIST, DST-PURSE and RUSA grants.

  5. Data availability: Not applicable.

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Received: 2023-11-29
Accepted: 2024-03-08
Published Online: 2024-06-11
Published in Print: 2025-02-25

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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