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Water/PEG Mixtures: Phase Behavior, Dynamics and Soft Confinement

  • Björn Kuttich EMAIL logo , Alexander Matt , Andreas Weber , Ann-Kathrin Grefe , Laura Vietze und Bernd Stühn
Veröffentlicht/Copyright: 8. Dezember 2017
Zeitschrift für Physikalische Chemie
Aus der Zeitschrift Zeitschrift für Physikalische Chemie Band 232 Heft 7-8

Abstract

Polyethylene glycol is water soluble and forms an eutectic system with water. The eutectic temperature is −19 °C for M=1500 g mol−1 and increases with molecular weight. The dielectric relaxation spectrum of the mixtures exhibits a strong loss maximum in ϵ″ (ω) similar to pure water. Relaxation time increases with the addition of PEG. Activation energies exhibit a maximum of 0.35 eV at molar fraction χp≈0.2. This compares well with results on ethanol water mixtures. Adding PEG molecules to nanoscopic water droplets of inverse microemulsions has only small impact on the bending modulus κ of a non-ionic microemulsion. In AOT based microemulsions an increase or decrease of κ is found in dependence on the size of the droplets. This is in accordance with the variation of the dynamic percolation transition in the same systems.

Keywords: confinement; dielectric spectroscopy; microemulsion; NSE; SANS; SAXS; water/PEG

Acknowledgement

Financial support by the “Deutsche Forschungsgemeinschaft” DFG through the “DFG-Forschergruppe 1583” by Project no. STU191/6-1 is thankfully acknowledged. For the performance of neutron scattering measurements we are very grateful to Oxana Ivanova and the Jülich Centre of Neutron Research (JCNS) at the Heinz Maier-Leibnitz Zentrum (MLZ), Garching, Germany as well as Isabelle Grillo and Peter Falus and the Institut Laue-Langevin, Grenoble, France.

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Supplementary Material:

The online version of this article offers supplementary material (https://doi.org/10.1515/zpch-2017-1018).

Received: 2017-08-09
Accepted: 2017-11-17
Published Online: 2017-12-08
Published in Print: 2018-07-26

©2018 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Preface
  3. Editorial: Molecules in Prison
  4. Properties of Hydrogen-Bonded Liquids at Interfaces
  5. Ab-Initio Molecular Dynamics Simulations and Calculations of Spectroscopic Parameters in Hydrogen-Bonding Liquids in Confinement (Project 8)
  6. Liquid Water Confined in Cellulose with Variable Interfacial Hydrophilicity
  7. A Combined Solid-State NMR, Dielectric Spectroscopy and Calorimetric Study of Water in Lowly Hydrated MCM-41 Samples
  8. Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement
  9. 2H NMR Studies on Water Dynamics in Functionalized Mesoporous Silica
  10. 2H NMR Studies on the Dynamics of Pure and Mixed Hydrogen-Bonded Liquids in Confinement
  11. Water/PEG Mixtures: Phase Behavior, Dynamics and Soft Confinement
  12. Effects of Cosolvents and Macromolecular Crowding on the Phase Transitions and Temperature-Pressure Stability of Chiral and Racemic Poly-Lysine
  13. Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions
  14. Nanoscale Structuring in Confined Geometries using Atomic Layer Deposition: Conformal Coating and Nanocavity Formation
  15. Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes
  16. Molecular Dynamics Simulations of Water, Silica, and Aqueous Mixtures in Bulk and Confinement
  17. Monitoring the Process of Nanocavity Formation on a Monomolecular Level
  18. Elastin-like Peptide in Confinement: FT-IR and NMR T1 Relaxation Data
https://doi.org/10.1515/zpch-2017-1018
Schlagwörter für diesen Artikel
confinement; dielectric spectroscopy; microemulsion; NSE; SANS; SAXS; water/PEG

Artikel in diesem Heft

  1. Frontmatter
  2. Preface
  3. Editorial: Molecules in Prison
  4. Properties of Hydrogen-Bonded Liquids at Interfaces
  5. Ab-Initio Molecular Dynamics Simulations and Calculations of Spectroscopic Parameters in Hydrogen-Bonding Liquids in Confinement (Project 8)
  6. Liquid Water Confined in Cellulose with Variable Interfacial Hydrophilicity
  7. A Combined Solid-State NMR, Dielectric Spectroscopy and Calorimetric Study of Water in Lowly Hydrated MCM-41 Samples
  8. Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement
  9. 2H NMR Studies on Water Dynamics in Functionalized Mesoporous Silica
  10. 2H NMR Studies on the Dynamics of Pure and Mixed Hydrogen-Bonded Liquids in Confinement
  11. Water/PEG Mixtures: Phase Behavior, Dynamics and Soft Confinement
  12. Effects of Cosolvents and Macromolecular Crowding on the Phase Transitions and Temperature-Pressure Stability of Chiral and Racemic Poly-Lysine
  13. Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions
  14. Nanoscale Structuring in Confined Geometries using Atomic Layer Deposition: Conformal Coating and Nanocavity Formation
  15. Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes
  16. Molecular Dynamics Simulations of Water, Silica, and Aqueous Mixtures in Bulk and Confinement
  17. Monitoring the Process of Nanocavity Formation on a Monomolecular Level
  18. Elastin-like Peptide in Confinement: FT-IR and NMR T1 Relaxation Data
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