Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement
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Peter Weigl
Abstract
We have developed a flexible experimental setup to conduct triplet solvation dynamics (TSD) experiments. The setup is capable of exciting dyes at 355, 320 and 266 nm. Phosphorescence spectra can be recorded up to a 10 ns-resolution usually covering three decades using a grating spectrograph and a CCD camera. In this contribution, we describe the experimental setup as well as first investigations on water-alcohol mixtures, microemulsions and new dyes for TSD, i.e. naphthalene derivates, which take full advantage of this experimental method sensitive to the local environment of the dyes.
Acknowledgments
Financial support of the Deutsche Forschungsgemeinschaft in the framework of the research unit FOR 1583 under grant no BL 1192/1 is gratefully acknowledged.
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©2018 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Preface
- Editorial: Molecules in Prison
- Properties of Hydrogen-Bonded Liquids at Interfaces
- Ab-Initio Molecular Dynamics Simulations and Calculations of Spectroscopic Parameters in Hydrogen-Bonding Liquids in Confinement (Project 8)
- Liquid Water Confined in Cellulose with Variable Interfacial Hydrophilicity
- A Combined Solid-State NMR, Dielectric Spectroscopy and Calorimetric Study of Water in Lowly Hydrated MCM-41 Samples
- Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement
- 2H NMR Studies on Water Dynamics in Functionalized Mesoporous Silica
- 2H NMR Studies on the Dynamics of Pure and Mixed Hydrogen-Bonded Liquids in Confinement
- Water/PEG Mixtures: Phase Behavior, Dynamics and Soft Confinement
- Effects of Cosolvents and Macromolecular Crowding on the Phase Transitions and Temperature-Pressure Stability of Chiral and Racemic Poly-Lysine
- Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions
- Nanoscale Structuring in Confined Geometries using Atomic Layer Deposition: Conformal Coating and Nanocavity Formation
- Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes
- Molecular Dynamics Simulations of Water, Silica, and Aqueous Mixtures in Bulk and Confinement
- Monitoring the Process of Nanocavity Formation on a Monomolecular Level
- Elastin-like Peptide in Confinement: FT-IR and NMR T1 Relaxation Data
Articles in the same Issue
- Frontmatter
- Preface
- Editorial: Molecules in Prison
- Properties of Hydrogen-Bonded Liquids at Interfaces
- Ab-Initio Molecular Dynamics Simulations and Calculations of Spectroscopic Parameters in Hydrogen-Bonding Liquids in Confinement (Project 8)
- Liquid Water Confined in Cellulose with Variable Interfacial Hydrophilicity
- A Combined Solid-State NMR, Dielectric Spectroscopy and Calorimetric Study of Water in Lowly Hydrated MCM-41 Samples
- Triplet Solvation Dynamics of Hydrogen Bonding Liquids in Confinement
- 2H NMR Studies on Water Dynamics in Functionalized Mesoporous Silica
- 2H NMR Studies on the Dynamics of Pure and Mixed Hydrogen-Bonded Liquids in Confinement
- Water/PEG Mixtures: Phase Behavior, Dynamics and Soft Confinement
- Effects of Cosolvents and Macromolecular Crowding on the Phase Transitions and Temperature-Pressure Stability of Chiral and Racemic Poly-Lysine
- Chemically Modified Silica Materials as Model Systems for the Characterization of Water-Surface Interactions
- Nanoscale Structuring in Confined Geometries using Atomic Layer Deposition: Conformal Coating and Nanocavity Formation
- Surface Enhanced DNP Assisted Solid-State NMR of Functionalized SiO2 Coated Polycarbonate Membranes
- Molecular Dynamics Simulations of Water, Silica, and Aqueous Mixtures in Bulk and Confinement
- Monitoring the Process of Nanocavity Formation on a Monomolecular Level
- Elastin-like Peptide in Confinement: FT-IR and NMR T1 Relaxation Data
