Startseite Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
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Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source

  • Matthias Hämmer ORCID logo und Henning A. Höppe ORCID logo EMAIL logo
Veröffentlicht/Copyright: 11. Dezember 2018
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 74 Heft 1

Abstract

Crystalline orthorhombic rare earth carbonate hydroxides Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) were synthesised as phase pure powders via a simple hydrothermal reaction. CO2 from air acted as natural carbonate source and cetyltrimethylammonium bromide was added as templating agent to an aqueous rare earth nitrate solution. Single-crystal X-ray structure determination was performed on La[CO3][OH] (Pnma, a=7.4106(5), b=5.0502(3), c=8.5901(6) Å, 563 independent reflections, 38 refined parameters, wR2=0.037), Pr[CO3][OH] (Pnma, a=7.2755(4), b=4.9918(3), c=8.5207(5) Å, 744 independent reflections, 38 refined parameters, wR2=0.04), Eu[CO3][OH] (Pnma, a=7.1040(4), b=4.8940(3), c=8.4577(5) Å, 1649 independent reflections, 38 refined parameters, wR2=0.05) and Gd[CO3][OH] (Pnma, a=7.069(7), b=4.874(5), c=8.464(9) Å, 431 independent reflections, 38 refined parameters, wR2=0.051). These findings are supported by powder XRD, infrared spectroscopy, UV/Vis spectroscopy and, for Pr[CO3][OH] and Eu[CO3][OH], by measurements of the non-linear optical properties. Thermal analysis could demonstrate the possible use of the Ln[CO3][OH] phases as precursors for rare earth carbonate dioxides Ln2[CO3]O2 and rare earth oxides Ln2O3. The decomposition products inherit the precursor’s morphology. The lattice parameters of Pr2[CO3]O2 were refined from high-temperature powder XRD data.

Keywords: carbonate; crystal structure; hydroxides; lanthanide; precursor

Dedicated to: Professor Wolfgang Bensch on the Occasion of his 65th birthday.

Acknowledgements

The authors would like to thank R. Ettlinger (Universität Augsburg) for the EDX/SEM measurements and L. Bayarjargal (Universität Frankfurt) for testing our powder samples for non-linear optical SHG activity.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/znb-2018-0170).

Received: 2018-08-15
Accepted: 2018-10-26
Published Online: 2018-12-11
Published in Print: 2019-01-26

©2019 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Preface
  4. Congratulations to Professor Wolfgang Bensch on the occasion of his 65th birthday
  5. Orthorhombic sulfur from Cap Garonne, Mine du Pradet
  6. An unprecedented structural phase transition in struvite-type compounds: dimorphism of KMgAsO4(H2O)6
  7. ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGa
  8. Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
  9. Crystal structure of the high-temperature form of the trisulfide Cs2S3 and the (3+1)D modulated structure of the telluride K37Te28
  10. Synthesis, crystal structure and properties of Cd(NCS)2 coordination compounds with two different Cd coordination modes
  11. Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
  12. The role of synthesis conditions for structural defects and lattice strain in β-TaON and their effect on photo- and photoelectrocatalysis
  13. Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
  14. Electronic and magnetic properties of the 2H-NbS2 intercalated by 3d transition metal atoms
  15. CsTb3STe4 und CsTb5S2Te6: Zwei pseudo-ternäre Caesium-Terbium-Chalkogenide mit geordneten S2−- und Te2−-Anionen
  16. Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
  17. Crystal structures and FT-IR spectra of three N,N-dicyclohexylmethylammonium halides C13H26N+X− (X = Cl, Br, I)
  18. Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides RE14T3Al3 (RE = Y, Gd–Tm, Lu; T = Co, Ni)
  19. Modulated vacancy ordering in SrGe6−x (x≈0.45)
  20. Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis
https://doi.org/10.1515/znb-2018-0170
Schlagwörter für diesen Artikel
carbonate; crystal structure; hydroxides; lanthanide; precursor

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Preface
  4. Congratulations to Professor Wolfgang Bensch on the occasion of his 65th birthday
  5. Orthorhombic sulfur from Cap Garonne, Mine du Pradet
  6. An unprecedented structural phase transition in struvite-type compounds: dimorphism of KMgAsO4(H2O)6
  7. ZrNiAl-type gallides with pronounced metal-metal bonding, and the dimorphism of ScPdGa
  8. Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni3[CH(SO3)3]2(NMP)8}
  9. Crystal structure of the high-temperature form of the trisulfide Cs2S3 and the (3+1)D modulated structure of the telluride K37Te28
  10. Synthesis, crystal structure and properties of Cd(NCS)2 coordination compounds with two different Cd coordination modes
  11. Crystalline orthorhombic Ln[CO3][OH] (Ln=La, Pr, Nd, Sm, Eu, Gd) compounds hydrothermally synthesised with CO2 from air as carbonate source
  12. The role of synthesis conditions for structural defects and lattice strain in β-TaON and their effect on photo- and photoelectrocatalysis
  13. Determination of the charge of Al13 Keggin oligocations intercalated into synthetic hectorite
  14. Electronic and magnetic properties of the 2H-NbS2 intercalated by 3d transition metal atoms
  15. CsTb3STe4 und CsTb5S2Te6: Zwei pseudo-ternäre Caesium-Terbium-Chalkogenide mit geordneten S2−- und Te2−-Anionen
  16. Synthesis, molecular, and crystal structures of 3d transition metal cyanocyclopentadienides [M(MeOH)n(H2O)4–n{C5(CN)4X}2] (M=Mn, Fe, Co, Ni, Cu, Zn; X=H, CN, NH2, NO2)
  17. Crystal structures and FT-IR spectra of three N,N-dicyclohexylmethylammonium halides C13H26N+X− (X = Cl, Br, I)
  18. Crystal structure and magnetic properties of the ternary rare earth metal-rich transition metallides RE14T3Al3 (RE = Y, Gd–Tm, Lu; T = Co, Ni)
  19. Modulated vacancy ordering in SrGe6−x (x≈0.45)
  20. Monitoring the solvation process and stability of Eu2+ in an ionic liquid by in situ luminescence analysis
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