Two series of rare earth metal-rich ternary aluminium transition metallides – RE6Co2Al (RE=Sc, Y, Nd, Sm, Gd–Tm, Lu) and RE6Ni2.25Al0.75 (RE=Y, Gd–Tm, Lu)
-
Frank Stegemann
Abstract
The rare earth metal-rich cobalt and nickel aluminium compounds with the general compositions RE6Co2Al (RE=Sc, Y, Nd, Sm, Gd–Tm, Lu) and RE6Ni2.25Al0.75 (RE=Y, Gd–Tm, Lu) have been synthesised from the elements by arc-melting, followed by annealing. Single-crystal X-ray diffraction experiments on Y6Co2.02(1)Al0.98(1) (Ho6Co2Ga type; Immm; a=944.1(2), b=952.4(2), c=999.0(2) pm; wR2=0.0452, 1123 F2 values, 35 variables) and Y6Ni2.26(1)Al0.74(1) (Ho6Co2Ga type; Immm; a=938.30(5), b=959.45(5), c=996.05(6) pm; wR2=0.0499, 1131 F2 values, 35 variables) revealed that the compounds form solid solutions according to the general formula RE6(Co/Ni)2+xAl1−x with different homogeneity ranges. The compounds of the Ni series can be obtained in X-ray pure form only with the nominal composition RE6Ni2.25Al0.75. A significant increase of the U22 component of the anisotropic displacement parameters of the Co/Ni2 atoms (4g site) was observed that requires a description of the structure with a split-position model at RT. Further investigations by low temperature (90 K) single-crystal X-ray diffraction experiments of Y6Co2.02(1)Al0.98(1) showed a significant decrease of U22. Magnetic measurements were conducted on the X-ray pure members of the RE6Co2Al (RE=Y, Dy–Tm, Lu) series. Antiferromagnetic ordering was observed for the members with unpaired f electrons with Néel temperatures up to TN=48.0(1) K and two spin reorientations for Dy6Co2Al.
Dedicated to: Professor Werner Uhl on the occasion of his 65th birthday.
Acknowledgments
We thank Dr. Rolf-Dieter Hoffmann and Dipl.-Ing. Jutta Kösters for the collection of the single-crystal intensity data.
References
[1] F. Tappe, C. Schwickert, S. Linsinger, R. Pöttgen, Monatsh. Chem.2011, 142, 1087.10.1007/s00706-011-0622-3Suche in Google Scholar
[2] S. Engelbert, O. Janka, Intermetallics2018, 96, 84.10.1016/j.intermet.2018.02.016Suche in Google Scholar
[3] C. Benndorf, H. Eckert, O. Janka, Dalton Trans.2017, 46, 1083.10.1039/C6DT04314CSuche in Google Scholar
[4] Y. Verbovytskyy, K. Łątka, J. Przewoźnik, V. Kinzhybalo, J. Alloys Compd.2018, 758, 122.10.1016/j.jallcom.2018.05.123Suche in Google Scholar
[5] N. Nasri, M. Pasturel, V. Dorcet, B. Belgacem, R. Ben Hassen, O. Tougait, J. Alloys Compd.2015, 650, 528.10.1016/j.jallcom.2015.07.277Suche in Google Scholar
[6] R. E. Gladyshevskii, Y. N. Grin, Y. P. Yarmolyuk, Dopov. Akad. Nauk Ukr. RSR, Ser. A1983, 2, 67.Suche in Google Scholar
[7] O. M. Sichevich, L. P. Komarovskaya, Y. N. Grin, Y. P. Yarmolyuk, R. V. Skolozdra, Ukr. Fiz. Zh.1984, 29, 1342.Suche in Google Scholar
[8] M. Demchyna, B. Belan, M. Manyako, L. Akselrud, A. Gagor, M. Dzevenko, Y. Kalychak, Intermetallics2013, 37, 22.10.1016/j.intermet.2013.01.010Suche in Google Scholar
[9] M. Dzevenko, A. Hamyk, Y. Tyvanchuk, Y. Kalychak, Cent. Eur. J. Chem.2013, 11, 604.10.2478/s11532-012-0195-ySuche in Google Scholar
[10] Y. M. Kalychak, V. I. Zaremba, P. Y. Zavalij, Z. Kristallogr.1993, 208, 380.Suche in Google Scholar
[11] Y. M. Kalychak, J. Alloys Compd.1999, 291, 80.10.1016/S0925-8388(99)00290-XSuche in Google Scholar
[12] Y. B. Tyvanchuk, M. Lukachuk, R. Pöttgen, A. Szytula, Y. M. Kalychak, Z. Naturforsch.2015, 70b, 665.10.1515/znb-2015-0075Suche in Google Scholar
[13] R. I. Zaremba, Y. M. Kalychak, U. Ch. Rodewald, R. Pöttgen, V. I. Zaremba, Z. Naturforsch.2006, 61b, 942.10.1515/znb-2006-0803Suche in Google Scholar
[14] O. E. Koretskaya, L. A. Mykhayliv, V. A. Sadov, R. V. Skolozdra, Visn. Lviv. Derzh. Univ., Ser. Khim.1988, 29, 34.Suche in Google Scholar
[15] L. D. Gulay, M. Wolcyrz, J. Alloys Compd.2001, 315, 164.10.1016/S0925-8388(00)01281-0Suche in Google Scholar
[16] F. Canepa, M. Napoletano, M. L. Fornasini, F. Merlo, J. Alloys Compd.2002, 345, 42.10.1016/S0925-8388(02)00395-XSuche in Google Scholar
[17] A. V. Morozkin, A. V. Garshev, A. V. Knotko, V. O. Yapaskurt, Y. Mozharivskyj, F. Yuan, J. Yao, R. Nirmala, S. Quezado, S. K. Malik, J. Solid State Chem.2018, 261, 62.10.1016/j.jssc.2018.02.009Suche in Google Scholar
[18] E. V. Murashova, A. I. Tursina, N. G. Bukhanko, S. N. Nesterenko, Z. Kurenbaeva, Y. D. Seropegin, H. Noël, M. Potel, T. Roisnel, D. Kaczorowski, Mater. Res. Bull.2010, 45, 993.10.1016/j.materresbull.2010.04.006Suche in Google Scholar
[19] F. Stegemann, O. Janka, Dalton Trans.2016, 45, 13863.10.1039/C6DT02649DSuche in Google Scholar PubMed
[20] H. Fu, M. X. Wang, Q. Zheng, D. B. Luo, B. H. Teng, J. Appl. Phys.2012, 112, 103916.10.1063/1.4766899Suche in Google Scholar
[21] E. V. Murashova, A. I. Tursina, Z. Kurenbaeva, H. Noël, Y. D. Seropegin, Chem. Mater. Alloys2010, 3, 101.10.30970/cma3.0126Suche in Google Scholar
[22] S. Linsinger, M. Eul, W. Hermes, R.-D. Hoffmann, R. Pöttgen, Z. Naturforsch.2009, 64b, 1345.10.1515/znb-2009-11-1214Suche in Google Scholar
[23] S. Stein, S. F. Matar, L. Heletta, R. Pöttgen, Solid State Sci.2018, 82, 70.10.1016/j.solidstatesciences.2018.03.020Suche in Google Scholar
[24] K. Klepp, E. Parthé, Acta Crystallogr.1981, 37b, 1500.10.1107/S0567740881006444Suche in Google Scholar
[25] F. Tappe, U. Ch. Rodewald, R.-D. Hoffmann, R. Pöttgen, Z. Naturforsch.2011, 66b, 559.10.1515/znb-2011-0602Suche in Google Scholar
[26] A. Mehta, J. D. Corbett, J. Solid State Chem.2008, 181, 871.10.1016/j.jssc.2008.01.034Suche in Google Scholar
[27] F. Meng, C. Magliocchi, T. Hughbanks, J. Alloys Compd.2003, 358, 98.10.1016/S0925-8388(03)00456-0Suche in Google Scholar
[28] P. A. Maggard, J. D. Corbett, J. Am. Chem. Soc.2000, 122, 10740.10.1021/ja002875jSuche in Google Scholar
[29] F. Meng, T. Hughbanks, Inorg. Chem.2001, 40, 2482.10.1021/ic010009hSuche in Google Scholar
[30] S. Gupta, J. D. Corbett, Dalton Trans.2010, 39, 6074.10.1039/c000650pSuche in Google Scholar
[31] R. Pöttgen, T. Gulden, A. Simon, GIT Labor-Fachzeitschrift1999, 43, 133.Suche in Google Scholar
[32] D. Kußmann, R.-D. Hoffmann, R. Pöttgen, Z. Anorg. Allg. Chem.1998, 624, 1727.10.1002/(SICI)1521-3749(1998110)624:11<1727::AID-ZAAC1727>3.0.CO;2-0Suche in Google Scholar
[33] Pilatus 100K-S Detector System, Technical Specification and Operating Procedure (version 1.7), Dectris, Baden 2011.Suche in Google Scholar
[34] P. J. Becker, P. Coppens, Acta Crystallogr.1974, A30, 148.10.1107/S0567739474000349Suche in Google Scholar
[35] V. Petříček, M. Dušek, L. Palatinus, Jana2006, The Crystallographic Computing System, Institute of Physics, Academy of Sciences of the Czech Republic, Prague (Czech Republic) 2006.Suche in Google Scholar
[36] V. Petříček, M. Dušek, L. Palatinus, Z. Kristallogr.2014, 229, 345.10.1515/zkri-2014-1737Suche in Google Scholar
[37] B. J. Beaudry, A. H. Daane, Met. Soc. AIME1960, 218, 854.Suche in Google Scholar
[38] F. H. Spedding, A. H. Daane, K. W. Herrmann, Acta Crystallogr.1956, 9, 559.10.1107/S0365110X5600156XSuche in Google Scholar
[39] J. Emsley, The Elements, Clarendon Press, Oxford University Press, Oxford, New York, 1998.Suche in Google Scholar
[40] A. W. Hull, Phys. Rev.1919, 14, 540.Suche in Google Scholar
[41] J. M. Moreau, E. Parthé, D. Paccard, Acta Crystallogr.1975, B31, 747.10.1107/S0567740875003731Suche in Google Scholar
[42] J. M. Moreau, D. Paccard, E. Parthé, Acta Crystallogr.1976, B32, 496.10.1107/S0567740876003312Suche in Google Scholar
[43] A. W. Hull, Phys. Rev.1917, 10, 661.10.1103/PhysRev.10.661Suche in Google Scholar
[44] J. Le Roy, J.-M. Moreau, D. Paccard, E. Parthé, Acta Crystallogr.1977, B33, 3406.10.1107/S0567740877011091Suche in Google Scholar
[45] F. Stegemann, C. Benndorf, T. Bartsch, R. S. Touzani, M. Bartsch, H. Zacharias, B. P. T. Fokwa, H. Eckert, O. Janka, Inorg. Chem.2015, 54, 10785.10.1021/acs.inorgchem.5b01842Suche in Google Scholar
[46] F. Eustermann, S. Gausebeck, C. Dosche, M. Haensch, G. Wittstock, O. Janka, Crystals2018, 8, 169.10.3390/cryst8040169Suche in Google Scholar
[47] F. Stegemann, C. Benndorf, Y. Zhang, M. Bartsch, H. Zacharias, B. P. T. Fokwa, H. Eckert, O. Janka, Inorg. Chem.2017, 56, 1919.10.1021/acs.inorgchem.6b02480Suche in Google Scholar
[48] C. Benndorf, F. Stegemann, S. Seidel, L. Schubert, M. Bartsch, H. Zacharias, B. Mausolf, F. Haarmann, H. Eckert, R. Pöttgen, O. Janka, Chem. Eur. J.2017, 23, 4187.10.1002/chem.201605838Suche in Google Scholar
[49] F. Stegemann, C. Benndorf, Y. Zhang, M. Bartsch, H. Zacharias, B. P. T. Fokwa, H. Eckert, O. Janka, Z. Anorg. Allg. Chem.2017, 643, 1379.10.1002/zaac.201700103Suche in Google Scholar
[50] E. O. Wollan, W. C. Koehler, Phys. Rev.1955, 100, 545.10.1103/PhysRev.100.545Suche in Google Scholar
[51] D. Gignoux, D. Schmitt, J. Alloys Compd.1995, 225, 423.10.1016/0925-8388(94)07046-6Suche in Google Scholar
[52] A. R. Ball, D. Gignoux, D. Schmitt, F. Y. Zhang, M. Reehuis, J. Magn. Magn. Mater.1992, 110, 343.10.1016/0304-8853(92)90221-9Suche in Google Scholar
[53] N. Iwata, K. Honda, T. Shigeoka, Y. Hashimoto, H. Fujii, J. Magn. Magn. Mater.1990, 90–91, 63.10.1016/S0304-8853(10)80022-8Suche in Google Scholar
[54] R. Kraft, T. Fickenscher, G. Kotzyba, R.-D. Hoffmann, R. Pöttgen, Intermetallics2003, 11, 111.10.1016/S0966-9795(02)00189-9Suche in Google Scholar
©2018 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Preface
- Congratulations to Bernt Krebs
- Structural and IR-spectroscopic characterization of pyridinium acesulfamate, a monoclinic twin
- Cationic tri(ferrocenecarbonitrile)silver(I)
- Ternary indides RE3T2In4 (RE=Dy–Tm; T=Pd, Ir)
- Mixing SbIII and GeIV occupancy in the polyoxovanadate {V14E8} archetype
- Biolabeling with cobaltocinium tags
- Formation of di- and polynuclear Mn(II) thiocyanate pyrazole complexes in solution and in the solid state
- Hydrothermal synthesis and structure determination of a new calcium iron ruthenium hydrogarnet
- 7-Methyl-6-furylpurine forms dinuclear metal complexes with N3,N9 coordination
- Structural and magnetic investigations of the pseudo-ternary RE2TAl3 series (RE=Sc, Y, La–Nd, Sm, Gd–Lu; T=Ru, Rh, Ir) – size dependent formation of two different structure types
- A new stacking variant of Na2Pt(OH)6
- Alkali chalcogenido ortho manganates(II) A6MnQ4 (A=Rb, Cs; Q=S, Se, Te)
- Studie über den Einfluss des Fluorierungsgrades an einem tetradentaten C^N*N^C-Luminophor auf die photophysikalischen Eigenschaften seiner Platin(II)-Komplexe und deren Aggregation
- Hydrothermal growth mechanism of SnO2 nanorods in aqueous HCl
- Preface
- Congratulations to Werner Uhl
- The stannides REIr2Sn4 (RE=La, Ce, Pr, Nd, Sm)
- 1H-[1,2,4]Triazolo[4,3-a]pyridin-4-ium and 3H-[1,2,4]triazolo[4,3-a]quinolin-10-ium derivatives as new intercalating agents for DNA
- Functionalization of 1,3-diphosphacyclobutadiene cobalt complexes via Si–P bond insertion
- A new aspect of the “pseudo water” concept of bis(trimethylsilyl)carbodiimide – “pseudohydrates” of aluminum
- (NH4)InB8O14 – a high-pressure borate combining BO3 groups with corner- and edge-sharing BO4 tetrahedra
- Two series of rare earth metal-rich ternary aluminium transition metallides – RE6Co2Al (RE=Sc, Y, Nd, Sm, Gd–Tm, Lu) and RE6Ni2.25Al0.75 (RE=Y, Gd–Tm, Lu)
- Alkylaluminum, -gallium, -magnesium, and -zinc monophenolates with bulky substituents
- Note
- Synthesis and crystal structure of the copper silylamide cluster compound [Cu9{MesSi(NPh)3}2 (PhCO2)3]
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Preface
- Congratulations to Bernt Krebs
- Structural and IR-spectroscopic characterization of pyridinium acesulfamate, a monoclinic twin
- Cationic tri(ferrocenecarbonitrile)silver(I)
- Ternary indides RE3T2In4 (RE=Dy–Tm; T=Pd, Ir)
- Mixing SbIII and GeIV occupancy in the polyoxovanadate {V14E8} archetype
- Biolabeling with cobaltocinium tags
- Formation of di- and polynuclear Mn(II) thiocyanate pyrazole complexes in solution and in the solid state
- Hydrothermal synthesis and structure determination of a new calcium iron ruthenium hydrogarnet
- 7-Methyl-6-furylpurine forms dinuclear metal complexes with N3,N9 coordination
- Structural and magnetic investigations of the pseudo-ternary RE2TAl3 series (RE=Sc, Y, La–Nd, Sm, Gd–Lu; T=Ru, Rh, Ir) – size dependent formation of two different structure types
- A new stacking variant of Na2Pt(OH)6
- Alkali chalcogenido ortho manganates(II) A6MnQ4 (A=Rb, Cs; Q=S, Se, Te)
- Studie über den Einfluss des Fluorierungsgrades an einem tetradentaten C^N*N^C-Luminophor auf die photophysikalischen Eigenschaften seiner Platin(II)-Komplexe und deren Aggregation
- Hydrothermal growth mechanism of SnO2 nanorods in aqueous HCl
- Preface
- Congratulations to Werner Uhl
- The stannides REIr2Sn4 (RE=La, Ce, Pr, Nd, Sm)
- 1H-[1,2,4]Triazolo[4,3-a]pyridin-4-ium and 3H-[1,2,4]triazolo[4,3-a]quinolin-10-ium derivatives as new intercalating agents for DNA
- Functionalization of 1,3-diphosphacyclobutadiene cobalt complexes via Si–P bond insertion
- A new aspect of the “pseudo water” concept of bis(trimethylsilyl)carbodiimide – “pseudohydrates” of aluminum
- (NH4)InB8O14 – a high-pressure borate combining BO3 groups with corner- and edge-sharing BO4 tetrahedra
- Two series of rare earth metal-rich ternary aluminium transition metallides – RE6Co2Al (RE=Sc, Y, Nd, Sm, Gd–Tm, Lu) and RE6Ni2.25Al0.75 (RE=Y, Gd–Tm, Lu)
- Alkylaluminum, -gallium, -magnesium, and -zinc monophenolates with bulky substituents
- Note
- Synthesis and crystal structure of the copper silylamide cluster compound [Cu9{MesSi(NPh)3}2 (PhCO2)3]
