Startseite A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)

  • Si-Meng Wu , Xin Chen , Zhifeng Xin , Ai-Quan Jia und Qian-Feng Zhang EMAIL logo
Veröffentlicht/Copyright: 1. Mai 2018
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen Erkunden Sie dieses Fachgebiet
Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 73 Heft 5

Abstract

Interaction of (NH4)6Mo7O24·4H2O with tris-(3,5-di-tert-butyl-2-hydroxy-benzylidene)triaminoguanidinium chloride [H6tBu6L]Cl in DMF-H2O resulted in isolation of a neutral dinuclear Mo(VI) complex [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF. The C3-symmetric-type ligand HtBu6L is coordinated to two cis-{MoO2}2+ moieties via phenolic-oxygen, guanidine nitrogen and azomethine nitrogen atoms, and the remaining sixth coordination sites of the molybdenum centers are occupied by the oxygen atoms from the solvent molecules.

Keywords: crystal structure; molybdenum(VI); synthesis; triaminoguanidine

Acknowledgment

The support of this work by the Natural Science Foundation of China (21471003) is gratefully acknowledged.

References

[1] I. M. Müller, R. Robson, Angew. Chem. Int. Ed. 2000, 39, 4357.10.1002/1521-3773(20001201)39:23<4357::AID-ANIE4357>3.0.CO;2-0Suche in Google Scholar

[2] I. M. Oppel (née Müller), K. Föcker, Angew. Chem. Int. Ed. 2008, 47, 402.10.1002/anie.200703789Suche in Google Scholar

[3] E. T. Spielberg, A. Gilb, D. Plaul, D. Geibig, D. Hornig, D. Schuch, A. Buchholz, A. Ardavan, W. Plass, Inorg. Chem. 2015, 54, 32.10.1021/ic503095tSuche in Google Scholar

[4] M. L. Abraham, A. C. Schulze, A. Korthaus, I. M. Oppel, Dalton Trans.2013, 42, 16066.10.1039/c3dt51490kSuche in Google Scholar

[5] I. M. Müller, D. Möller, K. Föcker, Chem. Eur. J.2005, 11, 3318.10.1002/chem.200401260Suche in Google Scholar

[6] I. M. Müller, S. Spillmann, H. Franck, R. Pietschnig, Chem. Eur. J.2004, 10, 2207.10.1002/chem.200305564Suche in Google Scholar

[7] A. Zharkouskaya, A. Buchholz, W. Plass, Eur. J. Inorg. Chem.2005, 4875.10.1002/ejic.200500652Suche in Google Scholar

[8] A. Zharkouskaya, H. Görls, G. Vaughan, W. Plass, Inorg. Chem. Commun.2005, 8, 1145.10.1016/j.inoche.2005.09.025Suche in Google Scholar

[9] I. M. Müller, D. Möller, Eur. J. Inorg. Chem. 2005, 257.10.1002/ejic.200400526Suche in Google Scholar

[10] T.-T. Qian, Y.-J. Cui, Z. Xin, A.-Q. Jia, Q.-F. Zhang, Z. Naturforsch. 2017, 72b, 475.10.1515/znb-2017-0002Suche in Google Scholar

[11] Smart and Saint+ for Windows NT (version 6.02a), Bruker AXS Inc., Madison, WI (USA) 1998.Suche in Google Scholar

[12] G. M. Sheldrick, Sadabs, University of Göttingen, Göttingen (Germany) 1996.Suche in Google Scholar

[13] G. M. Sheldrick, Shelxtl (version 5.1), Software Reference Manual, Bruker AXS Inc., Madison, WI (USA) 1997.Suche in Google Scholar

[14] G. M. Sheldrick, Acta Crystallogr.2008, A64, 112.10.1107/S0108767307043930Suche in Google Scholar

[15] R. Takjoo, M. Ahmadi, A. Akbari, H. A. Rudbari, F. Nicolo, J. Coord. Chem.2012, 65, 3403.10.1080/00958972.2012.709935Suche in Google Scholar

[16] M. Ghorbanloo, R. Bikas, G. Makcki, Inorg. Chim. Acta2016, 445, 8.10.1016/j.ica.2016.02.018Suche in Google Scholar

[17] K. Nakajima, K. Yokoyama, T. Kano, M. Kojima, Inorg. Chim. Acta1998, 282, 209.10.1016/S0020-1693(98)00243-6Suche in Google Scholar

[18] P. Neves, S. Gago, S. S. Balula, A. D. Lopes, A. A. Valente, L. Cunha-Silva, F. A. A. Paz, M. Pillinger, J. Rocha, C. M. Silva, I. S. Gonҫalves, Inorg. Chem.2011, 50, 3490.10.1021/ic102456zSuche in Google Scholar PubMed

[19] C. Bustos, O. Burckhardt, R. Schrebler, D. Carrillo, A. M. Arif, A. H. Cowley, C. W. Nunn, Inorg. Chem.1990, 29, 3996.10.1021/ic00345a017Suche in Google Scholar

[20] V. Vrdoljak, M. Cindric, D. Milic, D. Matkovic-Calogovic, P. Novak, B. Kamenar, Polyhedron2005, 24, 1717.10.1016/j.poly.2005.05.002Suche in Google Scholar

[21] K. Gopi, N. Thirupathi, M. Nethaji, Organometallics2011, 30, 572.10.1021/om1009445Suche in Google Scholar

Received: 2018-2-19
Accepted: 2018-3-30
Published Online: 2018-5-1
Published in Print: 2018-5-24

©2018 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
  4. 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
  5. A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
  6. A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
  7. Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
  8. Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
  9. Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
  10. Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
  11. A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
  12. Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands
  13. Synthesis and characterization of the new tin borate SnB8O11(OH)4
  14. Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
  15. Book Review
  16. Metallo-Drugs: Development and Action of Anticancer Agents
https://doi.org/10.1515/znb-2018-0044
Schlagwörter für diesen Artikel
crystal structure; molybdenum(VI); synthesis; triaminoguanidine

Artikel in diesem Heft

  1. Frontmatter
  2. In this Issue
  3. Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
  4. 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
  5. A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
  6. A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
  7. Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
  8. Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
  9. Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
  10. Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
  11. A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
  12. Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands
  13. Synthesis and characterization of the new tin borate SnB8O11(OH)4
  14. Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
  15. Book Review
  16. Metallo-Drugs: Development and Action of Anticancer Agents
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 25.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/znb-2018-0044/html
Button zum nach oben scrollen