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Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations

  • Javad Safaei-Ghomi EMAIL logo , Reza Aghagoli and Hossein Shahbazi-Alavi
Published/Copyright: May 1, 2018
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 73 Issue 5

Abstract

An efficient synthesis of hexahydro-4-phenylquinoline-3-carbonitriles is described by the four-component condensation reaction of cyclohexanone, ammonium acetate, malononitrile, and aromatic aldehydes using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations. The reusability of the catalyst and little catalyst loading, excellent yields, short reaction times, using the sonochemical procedure as a green process and an alternative energy source are some benefits of this method.

Keywords: nanocatalyst; nano-Fe3O4; one-pot reaction; quinoline; ultrasonic conditions

Acknowledgement

The authors are grateful to the University of Kashan for supporting this work.

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Supplemental Material:

The online version of this article offers supplementary material (https://doi.org/10.1515/znb-2017-0200).

Received: 2017-11-10
Accepted: 2018-2-25
Published Online: 2018-5-1
Published in Print: 2018-5-24

©2018 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
  4. 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
  5. A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
  6. A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
  7. Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
  8. Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
  9. Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
  10. Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
  11. A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
  12. Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands
  13. Synthesis and characterization of the new tin borate SnB8O11(OH)4
  14. Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
  15. Book Review
  16. Metallo-Drugs: Development and Action of Anticancer Agents
https://doi.org/10.1515/znb-2017-0200
Keywords for this article
nanocatalyst; nano-Fe3O4; one-pot reaction; quinoline; ultrasonic conditions

Articles in the same Issue

  1. Frontmatter
  2. In this Issue
  3. Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
  4. 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
  5. A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
  6. A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
  7. Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
  8. Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
  9. Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
  10. Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
  11. A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
  12. Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands
  13. Synthesis and characterization of the new tin borate SnB8O11(OH)4
  14. Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
  15. Book Review
  16. Metallo-Drugs: Development and Action of Anticancer Agents
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