Synthesis and characterization of the new tin borate SnB8O11(OH)4
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Sandra Schönegger
Abstract
A new tin(II) borate with the composition SnB8O11(OH)4 was synthesized by a simple hydrothermal process. It crystallizes in the centrosymmetric monoclinic space group P21/n (no. 14) with the lattice parameters a=790.1(1), b=1402.2(2), c=994.8(1) pm, and β=90.40(5)° (Z=4). The new compound SnB8O11(OH)4 is isotypic to PbB8O11(OH)4 and isostructural to BaB8O11(OH)4. The borate layers are built up from fundamental building blocks (FBBs) with the composition [B8O11(OH)4]2−. Four of these FBBs form a nine-membered ring wherein the Sn2+ cations are located. These boron-oxygen layers are further connected by O–H···O hydrogen bond interactions. The characterization of SnB8O11(OH)4 is based on single-crystal X-ray diffraction data, vibrational spectroscopy, DFT calculations, and thermoanalytical investigations including high temperature powder XRD.
Acknowledgement
We are very thankful to the Institute for Construction and Materials Science at the University of Innsbruck for granting us access to the devices for the thermoanalytical measurements.
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©2018 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
- 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
- A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
- A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
- Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
- Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
- Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
- Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
- A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
- Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands
- Synthesis and characterization of the new tin borate SnB8O11(OH)4
- Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
- Book Review
- Metallo-Drugs: Development and Action of Anticancer Agents
Artikel in diesem Heft
- Frontmatter
- In this Issue
- Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
- 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
- A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
- A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
- Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
- Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
- Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
- Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
- A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
- Syntheses and crystal structures of ruthenium complexes with bidentate salicylaldiminato and dithiophosphato ligands
- Synthesis and characterization of the new tin borate SnB8O11(OH)4
- Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
- Book Review
- Metallo-Drugs: Development and Action of Anticancer Agents
