Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
-
Arnd Vogler
and
Michael Bodensteiner
Abstract
The binuclear complex Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6 has been prepared and characterized including the crystal structure. This complex shows, dependent on the conditions, three emissions, which originate from the quinolinolate IL excited state (fluorescence and phosphorescence) and from a Re(I) to 4,4′-bipyridine MLCT state (phosphorescence).
References
[1] A. Vogler, Inorg. Chem. Commun. 2017, 84, 131.10.1016/j.inoche.2017.08.016Search in Google Scholar
[2] R. Czerwieniec, A. Kapturkiewicz, R. Anulewicz-Ostrowska, J. Nowacki, J. Chem. Soc. Dalton Trans.2001, 2756.10.1039/b101357mSearch in Google Scholar
[3] CrysAlisPro Software System, Rigaku Oxford Diffraction, Chalgrove, Oxfordshire (U. K.) 2015.Search in Google Scholar
[4] O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Crystallogr. 2009, 42, 339.10.1107/S0021889808042726Search in Google Scholar
[5] G. M. Sheldrick, Acta Crystallogr. 2015, A71, 3.10.1107/S2053273314026370Search in Google Scholar
[6] G. M. Sheldrick, Acta Crystallogr. 2015, C71, 3.Search in Google Scholar
[7] G. J. Stor, F. Hartl, J. W. M. van Outersterp, D. J. Stufkens, Organometallics1994, 14, 1115.10.1021/om00003a013Search in Google Scholar
[8] R. Ballardini, G. Varani, M. T. Indelli, F. Scandola, Inorg. Chem. 1986, 25, 3858.10.1021/ic00242a006Search in Google Scholar
[9] H. Kunkely, A. Vogler, Inorg. Chem. Commun. 2000, 3, 645.10.1016/S1387-7003(00)00149-0Search in Google Scholar
[10] H. Kunkely, A. Vogler, J. Photochem. Photobiol. A: Chem.2001, 144, 69.10.1016/S1010-6030(01)00468-3Search in Google Scholar
[11] A. Vogler, Inorg. Chem. Commun. 2014, 45, 82.10.1016/j.inoche.2014.04.013Search in Google Scholar
[12] F. E. Lytle, D. R. Storey, M. E. Juricich, Spectrochim. Acta1973, 29 A, 1357.10.1016/0584-8539(73)80199-0Search in Google Scholar
[13] H. Kunkely, A. Vogler, Chem. Phys. Lett. 1999, 304, 187.10.1016/S0009-2614(99)00309-7Search in Google Scholar
[14] H. Kunkely, A. Vogler, Inorg. Chem. Commun. 2003, 6, 1335.10.1016/j.inoche.2003.07.004Search in Google Scholar
[15] H. Kunkely, A. Vogler, Inorg. Chim. Acta2009, 362, 196.10.1016/j.ica.2008.03.084Search in Google Scholar
[16] A. Vogler, Inorg. Chem. Commun. 2017, 82, 31.10.1016/j.inoche.2017.05.007Search in Google Scholar
[17] P. J. Giordano, M. S. Wrighton, J. Am. Chem. Soc. 1979, 101, 2888.10.1021/ja00505a016Search in Google Scholar
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Articles in the same Issue
- Frontmatter
- In this Issue
- Synthesis of hexahydro-4-phenylquinoline-3-carbonitriles using Fe3O4@SiO2-SO3H nanoparticles as a superior and retrievable heterogeneous catalyst under ultrasonic irradiations
- 2-Naphthol-pyrazole conjugates as substrates in the Mannich reaction
- A heterotrimetallic Ni(II)–Dy(III) bis(salamo)-based complex: synthesis, structure and fluorescent property
- A highly effective and mild protocol for the production of 1-thioamidoalkyl-2-naphthols using 1,3-disulfonic acid imidazolium trifluoroacetate as a dual-functional catalyst
- Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation
- Triclinic conformational polymorph of N,N,N′,N′-tetrakis(2-cyanoethyl)-1,2-ethylenediamine (TCED)
- Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability
- Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6
- A dinuclear molybdenum(VI) complex with a triaminoguanidine ligand: synthesis and structure of [Mo2O4(OH2)(DMF)(HtBu6L)]·3DMF ([H6tBu6L]Cl=tris(3,5-di-tert-butyl-2-hydroxybenzylidene)-triaminoguanidinium chloride)
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- Strukturen zweier Salze des Bis(thioharnstoff)gold(I)-Kations
- Book Review
- Metallo-Drugs: Development and Action of Anticancer Agents
