Startseite Tungsten Sulfide Nanoflakes: Synthesis by Electrospinning and Their Gas Sensing Properties
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Tungsten Sulfide Nanoflakes: Synthesis by Electrospinning and Their Gas Sensing Properties

  • Ke Wang , Wen-Lin Feng EMAIL logo , Xiang Qin , Da-Shen Deng , Xu Feng und Chao Zhang
Veröffentlicht/Copyright: 11. März 2017

Abstract

Tungsten sulfide (WS2) nanoflakes were successfully prepared via electrospinning with polyvinylpyrrolidone (PVP) as organic solvent. In addition, Ag-deposited WS2 (Ag-WS2) was obtained by chemical blending/calcination method. The structure and morphology of as-prepared materials were characterised by powder X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. The XRD result shows that the prepared WS2 has a graphene-like structure with P63/mmc space group symmetry. The SEM illuminates that the sensing samples have nanoflake appearance. Furthermore, heater-type gas sensors were fabricated based on WS2 and Ag-WS2 nanomaterials. The sensing responses of WS2 and Ag-WS2 on the ammonia (NH3), ethanol (C2H5OH), and acetone (C3H6O) were investigated at about 220°C. The results indicate that gas sensor based on WS2 and Ag-WS2 nanoflakes has 60 ppm sensing threshold value for ammonia. One possible gas sensing mechanism of WS2 and Ag-WS2 gas sensors is surface control via charge transfer.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant no. 51574054), the Program for Innovation Team Building at Institutions of Higher Education in Chongqing (Grant no. CXTDX201601030), and the Postgraduate Research Innovation Project of Chongqing (Grant nos. CYS15219, CYS16215).

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Received: 2016-10-4
Accepted: 2017-2-9
Published Online: 2017-3-11
Published in Print: 2017-4-1

©2017 Walter de Gruyter GmbH, Berlin/Boston

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