Startseite Naturwissenschaften Development of methods for the preparation of radiopure 82Se sources for the SuperNEMO neutrinoless double-beta decay experiment
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Development of methods for the preparation of radiopure 82Se sources for the SuperNEMO neutrinoless double-beta decay experiment

  • Alimardon V. Rakhimov EMAIL logo , A. S. Barabash , A. Basharina-Freshville , S. Blot , M. Bongrand , Ch. Bourgeois , D. Breton , R. Breier , E. Birdsall , V. B. Brudanin , H. Burešova , J. Busto , S. Calvez , M. Cascella , C. Cerna , J. P. Cesar , E. Chauveau , A. Chopra , G. Claverie , S. De Capua , F. Delalee , D. Duchesneau , V. G. Egorov , G. Eurin , J. J. Evans , L. Fajt , D. V. Filosofov , R. Flack , X. Garrido , H. Gomez , B. Guillon , P. Guzowski , R. Hodák , K. Holý , A. Huber , C. Hugon , A. Jeremie , S. Jullian , D. V. Karaivanov , M. Kauer , A. A. Klimenko , O. I. Kochetov , S. I. Konovalov , V. Kovalenko , K. Lang , Y. Lemière , T. Le Noblet , Z. Liptak , X. R. Liu , P. Loaiza , G. Lutter , J. Maalmi , M. Macko , F. Mamedov , C. Marquet , F. Mauger , A. Minotti , A. A. Mirsagatova , N. A. Mirzayev , I. Moreau , B. Morgan , J. Mott , I. B. Nemchenok , M. Nomachi , F. Nova , H. Ohsumi , G. Oliviero , R. B. Pahlka , J. R. Pater , V. Palušová , F. Perrot , F. Piquemal , P. Povinec , P. Pridal , Y. A. Ramachers , A. Rebii , A. Remoto , B. Richards , J. S. Ricol , E. Rukhadze , N. I. Rukhadze , R. Saakyan , I. I. Sadikov , R. Salazar , X. Sarazin , J. Sedgbeer , Yu. A. Shitov , F. Šimkovic , L. Simard , A. Smetana , K. Smolek , A. A. Smolnikov , S. Snow , S. Söldner-Rembold , B. Soulé , M. Špavorova , I. Štekl , F. A. Tashimova , J. Thomas , V. Timkin , S. Torre , Vl. I. Tretyak , V. I. Tretyak , V. I. Umatov , C. Vilela , V. Vorobel , G. Warot , D. Waters , M. Zampaolo und A. Žukauskas
Veröffentlicht/Copyright: 15. Juni 2019
Radiochimica Acta
Aus der Zeitschrift Radiochimica Acta Band 108 Heft 2

Abstract

A radiochemical method for producing 82Se sources with an ultra-low level of contamination of natural radionuclides (40K, decay products of 232Th and 238U) has been developed based on cation-exchange chromatographic purification with reverse removal of impurities. It includes chromatographic separation (purification), reduction, conditioning (which includes decantation, centrifugation, washing, grinding, and drying), and 82Se foil production. The conditioning stage, during which highly dispersed elemental selenium is obtained by the reduction of purified selenious acid (H2SeO3) with sulfur dioxide (SO2) represents the crucial step in the preparation of radiopure 82Se samples. The natural selenium (600 g) was first produced in this procedure in order to refine the method. The technique developed was then used to produce 2.5 kg of radiopure enriched selenium (82Se). The produced 82Se samples were wrapped in polyethylene (12 μm thick) and radionuclides present in the sample were analyzed with the BiPo-3 detector. The radiopurity of the plastic materials (chromatographic column material and polypropylene chemical vessels), which were used at all stages, was determined by instrumental neutron activation analysis. The radiopurity of the 82Se foils was checked by measurements with the BiPo-3 spectrometer, which confirmed the high purity of the final product. The measured contamination level for 208Tl was 8–54 μBq/kg, and for 214Bi the detection limit of 600 μBq/kg has been reached.

Keywords: Selenium-82; ion exchange chromatography; purification; mass spectrometry; neutron activation analysis; SuperNEMO; LSM Modane

Acknowledgments

We acknowledge support by the staff of the Modane Underground Laboratory and by the MEYS of the Czech Republic (grant number EF16_013/0001733), APVV in Slovakia, CNRS/IN2P3 and Labex Enigmass (A. Remoto) in France, RFBR in Russia (Project No. 16-52-16018 NCNIL a and No. 19-52-16002 NCNIL a), STFC in the UK and NSF in the USA.

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Received: 2019-03-04
Accepted: 2019-05-16
Published Online: 2019-06-15
Published in Print: 2020-01-28

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Development of methods for the preparation of radiopure 82Se sources for the SuperNEMO neutrinoless double-beta decay experiment
  3. Determination of 210Po in low-level wild bilberries reference material for quality control assurance in environmental analysis using extraction chromatography and α-particle spectroscopy
  4. Chemical effects of nuclear transformations and possible formation of unknown derivatives with N-phenylquinazolinium structure
  5. An approach for the efficient immobilization of 79Se using Fe-OOH modified GMZ bentonite
  6. Kinetics and mechanism of the advanced oxidation process of Cr(III) to Cr(VI) by SO4−˙ free radicals in slightly acidic simulated atmospheric water
  7. Preparation of novel nano composite materials from biomass waste and their sorptive characteristics for certain radionuclides
  8. Effect of maleic anhydride content on physico-mechanical properties of γ-irradiated waste polypropylene/corn husk fibers bio-composites
  9. Precise volume fraction measurement for three-phase flow meter using 137Cs gamma source and one detector
https://doi.org/10.1515/ract-2019-3129
Schlagwörter für diesen Artikel
Selenium-82; ion exchange chromatography; purification; mass spectrometry; neutron activation analysis; SuperNEMO; LSM Modane

Artikel in diesem Heft

  1. Frontmatter
  2. Development of methods for the preparation of radiopure 82Se sources for the SuperNEMO neutrinoless double-beta decay experiment
  3. Determination of 210Po in low-level wild bilberries reference material for quality control assurance in environmental analysis using extraction chromatography and α-particle spectroscopy
  4. Chemical effects of nuclear transformations and possible formation of unknown derivatives with N-phenylquinazolinium structure
  5. An approach for the efficient immobilization of 79Se using Fe-OOH modified GMZ bentonite
  6. Kinetics and mechanism of the advanced oxidation process of Cr(III) to Cr(VI) by SO4−˙ free radicals in slightly acidic simulated atmospheric water
  7. Preparation of novel nano composite materials from biomass waste and their sorptive characteristics for certain radionuclides
  8. Effect of maleic anhydride content on physico-mechanical properties of γ-irradiated waste polypropylene/corn husk fibers bio-composites
  9. Precise volume fraction measurement for three-phase flow meter using 137Cs gamma source and one detector
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