Startseite Naturwissenschaften Recyclable magnetically retrievable nanocatalysts for C–heteroatom bond formation reactions
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Recyclable magnetically retrievable nanocatalysts for C–heteroatom bond formation reactions

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Veröffentlicht/Copyright: 13. Mai 2022
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Physical Sciences Reviews
Aus der Zeitschrift Physical Sciences Reviews Band 8 Heft 11

Abstract

During recent years, magnetic separation has proven to be a highly indispensable and sustainable tool for facile separation of catalysts from the reaction medium with the aid of only an external magnetic force that precludes the requirement of energy intensive, solvent based centrifugation or filtration techniques. Extensive research in the area of catalysis has clearly divulged that while designing any catalyst, the foremost features that need to be paid due attention to include high activity, ready recoverability and good reusability. Fortunately, the magnetic nanocatalysts involving a superparamagnetic core material that could comprise of iron oxides such as magnetite, maghemite or hematite or mixed ferrites (CoFe2O4, CuFe2O4) have offered bright prospects of designing the ideal catalysts by proving their efficacy as strong support material that could be further engineered with various tools of nanotechnology and efficiently catalyze various C–heterobond formation reactions. This chapter provides succinct overview of all the approaches utilized for fabricating different types of magnetic nanoparticles and strategies adopted for imparting them durability. The prime forte however remains to exclusively showcase the applications of the various types of magnetic nanocatalysts in C–O, C–N, C–S and miscellaneous (C–Se, C–Te) bond formation reactions which are anticipated to benefit the synthetic community on a broad spectrum by helping them rationalize and analyze the key features that need to be taken into account, while developing these magical nanostructured catalytic systems for boosting the green bond formation reactions/transformations.

Keywords: green bond formation reactions; magnetic nanocatalysts; superparamagnetic core
Corresponding author: Rakesh Kumar Sharma, Green Chemistry Network Centre, Department of Chemistry, University of Delhi, Delhi-110007, India, E-mail:

Funding source: University of Delhi

Funding source: Science and Engineering Research Board

Award Identifier / Grant number: TAR/2021/000201

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: We would like to thank Faculty Research Programme Grant – IoE, University of Delhi for providing the financial assistance. We would also like to thank SERB for providing fund to Dr. Prashant Kumar under the scheme of Teacher Associateship for Research Excellence (TARE) (file number TAR/2021/000201).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/psr-2021-0101).

Received: 2022-02-22
Accepted: 2022-04-09
Published Online: 2022-05-13

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Reviews
  3. Anticancer properties of arylchromenes and arylchromans: an overview
  4. Solid state lithium ion conductors for lithium batteries
  5. Performance and kinetics of a fluidized bed anaerobic reactor treating distillery effluent
  6. Use of biochemical markers for diabetes prevention in the new decade
  7. Antibreast cancer activities of phytochemicals from Anonna muricata using computer-aided drug design (CADD) approach
  8. Alkaline-earth metal(II) complexes of salinomycin – spectral properties and antibacterial activity
  9. Use of heterogeneous catalysis in sustainable biofuel production
  10. Antibacterial, antioxidant and cytotoxic activities of the stem bark of Archidendron jiringa (Jack) I.C. Nielsen
  11. A review of sludge production in South Africa municipal wastewater treatment plants, analysis of handling cost and potential minimization methods
  12. Cu-Catalysed tandem reactions for building poly hetero atom heterocycles-green chemistry tool
  13. Optimizing Cr(VI) adsorption parameters on magnetite (Fe3O4) and manganese doped magnetite (MnxFe(3-x)O4) nanoparticles
  14. Fabaceae: a significant flavonoid source for plant and human health
  15. A novel application of synthesised based squarylium dyes on nylon 6, and silk woven fabrics
  16. Chromatographic characterization of the fusion protein SARS-CoV-2 S protein (RBD)-hFc
  17. Ethnopharmacology, phytochemistry and a new chemotaxonomic marker in Oldenlandia affinis (Roem. & Schult.) DC. Rubiaceae
  18. Extraction, isolation and characterization of secondary metabolites in the leaves of Morinda lucida from Oshiegbe in Ebonyi State
  19. Lead optimisation efforts on a molecular prototype of the immunomodulatory parasitic protein ES-62
  20. Catalytic applications of graphene oxide towards the synthesis of bioactive scaffolds through the formation of carbon–carbon and carbon–heteroatom bonds
  21. Synthesis, characterization, DFT and molecular docking studies of acetone O-((2,5-dichlorophenyl)sulfonyl) oxime
  22. Design of membrane systems
  23. Conceptual design and cost-efficient environmentally Benign synthesis of beta-lactams
  24. Synthesis and characterization of alkaloid derived hydrazones and their metal (II) complexes
  25. The spontaneity of chemical reactions: challenges with handling the concept and its implications
  26. Copper nanoparticles catalyzed carbon–heteroatom bond formation and synthesis of related heterocycles by greener procedures
  27. Tellurium in carbohydrate synthesis
  28. Conformational preferences and intramolecular hydrogen bonding patterns of tetraflavaspidic acid BBBB – a tetrameric acylphloroglucinol
  29. Phytochemical and antioxidant studies of Hibiscus Cannabinus seed oil
  30. Polyaniline mediated heterogeneous catalysis in the preparation of heterocyclic derivatives through carbon–heteroatom bond formations
  31. A comparison of two digestion methods and heavy metals determination in sediments
  32. Synthesis, properties and catalysis of quantum dots in C–C and C-heteroatom bond formations
  33. Recyclable magnetically retrievable nanocatalysts for C–heteroatom bond formation reactions
  34. Small molecules as next generation biofilm inhibitors and anti-infective agents
  35. Toxicity of tellurium and its compounds
  36. Biodegradable polycaprolactone (PCL) based polymer and composites
  37. Quality of poultry meat- the practical issues and knowledge based solutions
https://doi.org/10.1515/psr-2021-0101
Schlagwörter für diesen Artikel
green bond formation reactions; magnetic nanocatalysts; superparamagnetic core

Artikel in diesem Heft

  1. Frontmatter
  2. Reviews
  3. Anticancer properties of arylchromenes and arylchromans: an overview
  4. Solid state lithium ion conductors for lithium batteries
  5. Performance and kinetics of a fluidized bed anaerobic reactor treating distillery effluent
  6. Use of biochemical markers for diabetes prevention in the new decade
  7. Antibreast cancer activities of phytochemicals from Anonna muricata using computer-aided drug design (CADD) approach
  8. Alkaline-earth metal(II) complexes of salinomycin – spectral properties and antibacterial activity
  9. Use of heterogeneous catalysis in sustainable biofuel production
  10. Antibacterial, antioxidant and cytotoxic activities of the stem bark of Archidendron jiringa (Jack) I.C. Nielsen
  11. A review of sludge production in South Africa municipal wastewater treatment plants, analysis of handling cost and potential minimization methods
  12. Cu-Catalysed tandem reactions for building poly hetero atom heterocycles-green chemistry tool
  13. Optimizing Cr(VI) adsorption parameters on magnetite (Fe3O4) and manganese doped magnetite (MnxFe(3-x)O4) nanoparticles
  14. Fabaceae: a significant flavonoid source for plant and human health
  15. A novel application of synthesised based squarylium dyes on nylon 6, and silk woven fabrics
  16. Chromatographic characterization of the fusion protein SARS-CoV-2 S protein (RBD)-hFc
  17. Ethnopharmacology, phytochemistry and a new chemotaxonomic marker in Oldenlandia affinis (Roem. & Schult.) DC. Rubiaceae
  18. Extraction, isolation and characterization of secondary metabolites in the leaves of Morinda lucida from Oshiegbe in Ebonyi State
  19. Lead optimisation efforts on a molecular prototype of the immunomodulatory parasitic protein ES-62
  20. Catalytic applications of graphene oxide towards the synthesis of bioactive scaffolds through the formation of carbon–carbon and carbon–heteroatom bonds
  21. Synthesis, characterization, DFT and molecular docking studies of acetone O-((2,5-dichlorophenyl)sulfonyl) oxime
  22. Design of membrane systems
  23. Conceptual design and cost-efficient environmentally Benign synthesis of beta-lactams
  24. Synthesis and characterization of alkaloid derived hydrazones and their metal (II) complexes
  25. The spontaneity of chemical reactions: challenges with handling the concept and its implications
  26. Copper nanoparticles catalyzed carbon–heteroatom bond formation and synthesis of related heterocycles by greener procedures
  27. Tellurium in carbohydrate synthesis
  28. Conformational preferences and intramolecular hydrogen bonding patterns of tetraflavaspidic acid BBBB – a tetrameric acylphloroglucinol
  29. Phytochemical and antioxidant studies of Hibiscus Cannabinus seed oil
  30. Polyaniline mediated heterogeneous catalysis in the preparation of heterocyclic derivatives through carbon–heteroatom bond formations
  31. A comparison of two digestion methods and heavy metals determination in sediments
  32. Synthesis, properties and catalysis of quantum dots in C–C and C-heteroatom bond formations
  33. Recyclable magnetically retrievable nanocatalysts for C–heteroatom bond formation reactions
  34. Small molecules as next generation biofilm inhibitors and anti-infective agents
  35. Toxicity of tellurium and its compounds
  36. Biodegradable polycaprolactone (PCL) based polymer and composites
  37. Quality of poultry meat- the practical issues and knowledge based solutions
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