Startseite Simultaneous Biaxial Stretching of Polypropylene Resins of Varying Tacticity
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Simultaneous Biaxial Stretching of Polypropylene Resins of Varying Tacticity

Part II: Film Morphology and Properties
  • L. Capt , S. Rettenberger , H. Münstedt und M. R. Kamal
Veröffentlicht/Copyright: 3. März 2022
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
International Polymer Processing
Aus der Zeitschrift International Polymer Processing Band 20 Heft 4

Abstract

The simultaneous biaxial stretching behavior of three Ziegler-Natta-based isotactic polypropylene resins of varying isotacticity was studied using a laboratory film stretcher that simulates closely stretching conditions encountered in the commercial process. The effect of isotacticity on the final morphology and end film properties was associated with the effect of isotacticity on the thermal properties of the resin. The results showed that the degree of undermelting, △Tum = Tm–T, determines the phase composition of the polymer before stretching and the morphology and orientation of the stretched films. The size and orientation of the crystallites in the stretching plane is mostly determined by the degree of undermelting. The elongation at break was correlated with the residual crystallinity of the film before stretching, and the elastic modulus was correlated with the final degree of crystallinity and the density of tie chains.

M. R. Kamal, Department of Chemical Engineering, McGill University, 3610 University St., Montreal, Quebec H3A 2B2 Canada

Acknowledgements

The authors wish to thank the Bavarian Research Foundation, the Natural Sciences and Engineering Research Council of Canada, and Nova Chemicals for financial support. Ludovic Capt is particularly grateful to the Bavarian Research Foundation for the fellowship that made it possible for him to carry out the experimental work at the Institute of Polymer Materials of the University of Erlangen –Nuremberg.

  1. You will find the article and additional material by entering the document number IIPP1904 on our website at www.polymer-process.com

References

1 Elias, M. B., Machado, R., Canevarolo, S. V.: J. Therm. Anal. Cal., 59, p. 143 (2000)10.1023/A:1010187913049Suche in Google Scholar

2 Bartczack, Z., Martuscelli, E.: Polymer 38, p. 4139 (1997)10.1016/S0032-3861(96)00996-2Suche in Google Scholar

3 Karacan, I., Taraiya, A. K., Bower, D. I., Ward, I. M.: Polymer 34, p. 2691 (1993)10.1016/0032-3861(93)90108-MSuche in Google Scholar

4 Jabarin, S. A.: J. Reinforced Plast. Comp. 12, p. 480 (1993)10.1177/073168449301200408Suche in Google Scholar

5 Unwin, A. P., Bower, D. I., Ward, I. M.: Polymer 26, p. 1605 (1985)10.1016/0032-3861(85)90271-XSuche in Google Scholar

6 de Vries, A. J.: Pure and Appl. Chem. 53, p. 1011 (1981)10.1351/pac198153051011Suche in Google Scholar

7 Olley, R. H., Bassett, D. C.: J. Macromol. Sci. – Phys. B 33, p. 209 (1994)10.1080/00222349408248088Suche in Google Scholar

8 Nie, H.-Y., Walzak, M. J., McIntyre, N. S.: Polymer 41, p. 2213 (2000)10.1016/S0032-3861(99)00397-3Suche in Google Scholar

9 Taraiya, A. K., Orchard, G. A. J., Ward, I. M.: J. Appl. Polym. Sci. 41, p. 1659 (1990)10.1002/app.1990.070410725Suche in Google Scholar

10 de Vries, A. J.: Pure & Appl. Chem. 54, p. 647 (1982)10.1351/pac198254030647Suche in Google Scholar

11 Cox, W. W., Bullock, E. K.: Paper resented at Polyolefins X, International Conference, Houston, Texas (1997)Suche in Google Scholar

12 Hanyu, A., Wheat, R.: J. Plast. Film Sheeting 15, p. 109 (1999)10.1177/875608799901500204Suche in Google Scholar

13 Phillips, R. A., Nguyen, T.: J. Appl. Polym. Sci. 80, p. 2400 (2001)10.1002/app.1347Suche in Google Scholar

14 Capt, L., Kamal, M. R., Münstedt, H., Sänze, J., Stopperka, K.: Paper presented at 17th PPS Annual Meeting, Montreal (2001)Suche in Google Scholar

15 Capt, L., Kamal, M. R., Rettenberger, S., Münstedt, H.: Polym. Eng. Sci, 43, p. 1428 (2003)10.1002/pen.10121Suche in Google Scholar

16 Capt, L., Rettenberger, S., Münstedt, H., Kamal, M. R.: Int. Polym. Precess. 20, p. 35 (2005)10.3139/217.1867Suche in Google Scholar

17 Tanaka, H., Okajima, S.: J. Polym. Sci. Polym. Letters, 15, p. 349 (1977)10.1002/pol.1977.130150607Suche in Google Scholar

18 Peterlin, A.: J. Mater. Sci. 6, p. 490 (1971)10.1007/BF00550305Suche in Google Scholar

19 Bowden, P. D., Young, R. J.: J. Mat. Sci. 9, p. 2034 (1974)10.1007/BF00540553Suche in Google Scholar

20 Lin, L., Argon, A. S.: J. Mat. Sci. 29, p. 294 (1994)10.1007/BF01162485Suche in Google Scholar

21 Flory, P. J., Yoon, D. Y.: Nature 272, p. 226 (1978)10.1038/272226a0Suche in Google Scholar

22 Popli, R., Mandelkern, L.: J. Polym. Sci. Polym. Phys. Ed. 25, p. 441 (1987)10.1002/polb.1987.090250301Suche in Google Scholar

23 Fu, Q., Men, Y., Strobl, G.: Polymer 44, p. 1927 (2003)10.1016/S0032-3861(02)00940-0Suche in Google Scholar

24 Hiss, R., Hobeika, S., Lynn, C., Strobl, G.: Macromolecules 32, p. 4390 (1999)10.1021/ma981776bSuche in Google Scholar

25 Men, Y., Rieger, J., Strobl, G.: Phys. Rev. Letters 91, p. 095502 (2003)10.1103/PhysRevLett.91.095502Suche in Google Scholar

26 Paukkeri, R., Lehtinen, A.: Polymer 34, p. 4075 (1993)10.1016/0032-3861(93)90669-2Suche in Google Scholar

27 Cheng, S. Z. D., Janimak, J. J., Zhang, A.-Q., Hsieh, E. T.: Polymer 32, p. 648 (1991)10.1016/0032-3861(91)90477-ZSuche in Google Scholar

28 Rettenberger, S.: Ph.D Thesis, University Erlangen-Nuremberg (2002)Suche in Google Scholar

29 Geiss, D., Hoffman, D.: Prog. Polym. Sci., 15, p. 1 (1990)10.1016/0079-6700(90)90016-TSuche in Google Scholar

30 Scherrer, P.: Nachr. ges. Wiss. Gottingen 2, p. 96 (1918)Suche in Google Scholar

31 Warren, B. E.: J. Appl. Phys. 12, p. 375 (1941)10.1063/1.1712915Suche in Google Scholar

32 Uejo, H., Hoshino, S.: J. Appl. Polym. Sci. 14, p. 317 (1970)10.1002/app.1970.070140206Suche in Google Scholar

33 Capt, L.: Ph.D. Thesis, McGill University (2003)Suche in Google Scholar

34 Galeski, A. in: Polypropylene Structure, Blends and Composites, Karger-Kocsis, J. (Ed.), VCH, Weinheim (1995)Suche in Google Scholar

35 Vittoria, V.: J. Mat. Sci. 27, p. 4350 (1992)10.1007/BF00541565Suche in Google Scholar

36 Poussin, L., Bertin, Y. A., Parisot, J., Brassy, C.: Polymer 39, p. 4261 (1998)10.1016/S0032-3861(97)00437-0Suche in Google Scholar

37 Yan, R. J., Jiang, B.: J. Polym. Sci. Polym. Phys. Ed. 31, p. 1089 (1993)10.1002/polb.1993.090310904Suche in Google Scholar

38 Tanaka, H., Masuko, T., Okajima, S.: J. Appl. Polym. Sci. 17, p. 1715 (1973)10.1002/app.1973.070170606Suche in Google Scholar

39 Magill, J. H., Shankernarayanan, M. J., Sun, D. C., Kojima, M.: Int. Polym. Process. 2, p. 66 (1987)10.3139/217.870066Suche in Google Scholar

40 Saraf, R. F.: Polymer 35, p. 1359 (1994)10.1016/0032-3861(94)90334-4Suche in Google Scholar

41 Sobue, H., Tabata, Y.: J. Appl. Polym. Sci. 2, p. 62 (1959)10.1002/app.1959.070020409Suche in Google Scholar

42 Wilchinsky, Z. W.: J. Appl. Polym. Sci. 7, p. 923 (1963)10.1002/app.1963.070070311Suche in Google Scholar

43 Coulon, G., Castelein, G., Sell, C. G.: Polymer 40, p. 95 (1998)10.1016/S0032-3861(98)00221-3Suche in Google Scholar

44 Aboulfaraj, M., Sell, C. G., Ulrich, B., Dahoun, A.: Polymer 36, p. 731 (1995)10.1016/0032-3861(95)93102-RSuche in Google Scholar

45 Sakai, Y., Miyasaka, K.: Polymer 31, p. 51 (1990)10.1016/0032-3861(90)90348-3Suche in Google Scholar

46 Ward, I. M.: Structure and Properties of Oriented Polymers. Chapman & Hall, London (1997)10.1007/978-94-011-5844-2Suche in Google Scholar

47 Fu, Q., Men, Y., Strobl, G.: Polymer 44, p. 1941 (2003)10.1016/S0032-3861(03)00036-3Suche in Google Scholar

48 Porter, R. S.,Wang, L. H.: J. Macromol. Sci.-Rev. Macromol. Chem. Phys. C 35, p. 63 (1995)10.1080/15321799508014590Suche in Google Scholar

49 Choi, D., White, J. L., in: Polymer Films and Fibers 2002 Montreal (2002)Suche in Google Scholar

50 Hu, W.-G. , Schmidt-Rohr, K.: Acta Polymer 50, p. 271 (1999)10.1002/(SICI)1521-4044(19990801)50:8<271::AID-APOL271>3.0.CO;2-YSuche in Google Scholar

51 Hoffman, J. D., Davis, G. T., Lauritzen, J. J. J., in: Treatise On Solid State Chemistry, Crystalline and Non-crystalline Solids, Hannay, N. B. (Eds.), Plenum Press, New York (1976)Suche in Google Scholar

52 Vries, A. J. d.: Polym. Eng. Sci. 23, p. 241 (1983)10.1002/pen.760230502Suche in Google Scholar

53 Nordmeier, J., Menges, G.: Adv. Polym. Techn. 6, p. 59 (1986)10.1002/adv.1986.060060102Suche in Google Scholar

54 Nadella, H. P., Spruiell, J. E., White, J. L.: J. Appl. Polym. Sci. 22, p. 3121 (1978)10.1002/app.1978.070221108Suche in Google Scholar

55 Kennedy, M. A., Peacock, A. J., Mandelkern, L.: Macromolecules 27, p. 5297 (1994)10.1021/ma00097a009Suche in Google Scholar

56 Ishikawa, M., Ushui, K., Kondo, Y., Hatada, K., Gima, S.: Polymer 37, p. 5375 (1996)10.1016/S0032-3861(96)00364-3Suche in Google Scholar

57 Wang, L., Kamal, M. R., Rey, A. D.: Polym. Eng. Sci. 41, p. 358 (2001)10.1002/pen.10734Suche in Google Scholar

58 Wang, L., Huang, T., Kamal, M.R., Rey, A. D., Teh, J.: Polym Eng Sci. 40, p. 747 (2000)10.1002/pen.11204Suche in Google Scholar
Received: 2004-12-13
Accepted: 2005-07-29
Published Online: 2022-03-03

© 2005 Hanser Publishers, Munich

Artikel in diesem Heft

  1. Contents
  2. Regular Contributed Articles
  3. An Improvement on Design of Sheet Extrusion Dies
  4. Organic-Inorganic Hybrid Material Synthesis by on Line Coupling Twin Screw Extruder with a Microwave Oven
  5. Water Penetration Stability in Water Assisted Injection Molded Symmetric Ribs
  6. A New Plasticating Model for Amorphous and Semi-crystalline Polymers in Single Screw Extruders
  7. Simultaneous Biaxial Stretching of Polypropylene Resins of Varying Tacticity
  8. Optimization of a Flat Die Including Elongational Viscosity Effects
  9. Experimental Study on Factors Influencing Throughput Rate and Process of Polymer-Mineral Filler Mixing in a Twin Screw Extruder
  10. 3D Finite Element Simulation of Processing of Generalized Newtonian Fluids in Counter-rotating and Tangential TSE and Die Combination
  11. Simulation of Heat Transfer in Laser Transmission Welding
  12. Influence of Power Law and Isothermal Simplification on the Accuracy in Single Screw Extrusion
  13. Melt Intercalation in Montmorillonite/Polystyrene Nanocomposites
  14. Experimental Investigation of the Effect of the Bubble Cone on the Cooling Jets used in the Blown Film Manufacturing Process
  15. Molding of Thin Sheets Using Impact Micro-injection Molding
  16. Rapid communications
  17. Ultrasonic Vibration Hot Embossing
  18. PPS news
  19. PPS news
  20. Seikei-kakou abstracts
  21. Seikei-kakou abstracts
https://doi.org/10.1515/ipp-2005-0065

Artikel in diesem Heft

  1. Contents
  2. Regular Contributed Articles
  3. An Improvement on Design of Sheet Extrusion Dies
  4. Organic-Inorganic Hybrid Material Synthesis by on Line Coupling Twin Screw Extruder with a Microwave Oven
  5. Water Penetration Stability in Water Assisted Injection Molded Symmetric Ribs
  6. A New Plasticating Model for Amorphous and Semi-crystalline Polymers in Single Screw Extruders
  7. Simultaneous Biaxial Stretching of Polypropylene Resins of Varying Tacticity
  8. Optimization of a Flat Die Including Elongational Viscosity Effects
  9. Experimental Study on Factors Influencing Throughput Rate and Process of Polymer-Mineral Filler Mixing in a Twin Screw Extruder
  10. 3D Finite Element Simulation of Processing of Generalized Newtonian Fluids in Counter-rotating and Tangential TSE and Die Combination
  11. Simulation of Heat Transfer in Laser Transmission Welding
  12. Influence of Power Law and Isothermal Simplification on the Accuracy in Single Screw Extrusion
  13. Melt Intercalation in Montmorillonite/Polystyrene Nanocomposites
  14. Experimental Investigation of the Effect of the Bubble Cone on the Cooling Jets used in the Blown Film Manufacturing Process
  15. Molding of Thin Sheets Using Impact Micro-injection Molding
  16. Rapid communications
  17. Ultrasonic Vibration Hot Embossing
  18. PPS news
  19. PPS news
  20. Seikei-kakou abstracts
  21. Seikei-kakou abstracts
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 30.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ipp-2005-0065/html
Button zum nach oben scrollen