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Organic-Inorganic Hybrid Material Synthesis by on Line Coupling Twin Screw Extruder with a Microwave Oven

  • S. Jiguet , V. Bounor-Legaré , F. Melis and A. Michel
Published/Copyright: March 3, 2022
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International Polymer Processing
From the journal International Polymer Processing Volume 20 Issue 4

Abstract

A new process for elaborating continuously organic-inorganic hybrid materials by reactive extrusion is presented. This synthesis consists in formulating a copolymer of ethylene and vinyl acetate (EVA)/tetrapropoxysilane (TPOS or Si(OC3H7)4)/catalyst blend by a corotating twin screw extruder followed by two successive reaction steps: on line microwave crosslinking reaction and hydrolysis-condensation reactions leading to a silica network cografted onto the organic matrix.

Extrusion feed rate (Q), temperature, microwave oven power (P), and microwave curing time (tmw) were studied. Crosslinking density was evaluated before and after hydrolysis-condensation reactions and compared with the previous results obtained in static conditions. These materials tailored by an on line process present a permanent elasticity at high temperature (up to 200 °C) and a certain optical transparency. This new approach offers the possibility to synthesize massive samples based on organic-inorganic hybrid material.

V. Bounor-Legaré, Laboratoire des Matériaux Polymères et des Biomatériaux, Bât. ISTIL Université Claude Bernard Lyon 1, UMR CNRS 5627 17, Boulevard Latarjet, 69622 Villeurbanne cedex (France)

Acknowledgements

The authors wish to thank Dr. M. Delmotte from the “Laboratoire de microstructure et mécanique des matériaux” for the time dedicated to dielectric analysis and Pr. Ph. Cassagnau for his fruitful discussions.

  1. You will find the article and additional material by entering the document number IIPP1897 on our website at www.polymer-process.com

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Received: 2004-06-30
Accepted: 2005-06-02
Published Online: 2022-03-03

© 2005 Hanser Publishers, Munich

Articles in the same Issue

  1. Contents
  2. Regular Contributed Articles
  3. An Improvement on Design of Sheet Extrusion Dies
  4. Organic-Inorganic Hybrid Material Synthesis by on Line Coupling Twin Screw Extruder with a Microwave Oven
  5. Water Penetration Stability in Water Assisted Injection Molded Symmetric Ribs
  6. A New Plasticating Model for Amorphous and Semi-crystalline Polymers in Single Screw Extruders
  7. Simultaneous Biaxial Stretching of Polypropylene Resins of Varying Tacticity
  8. Optimization of a Flat Die Including Elongational Viscosity Effects
  9. Experimental Study on Factors Influencing Throughput Rate and Process of Polymer-Mineral Filler Mixing in a Twin Screw Extruder
  10. 3D Finite Element Simulation of Processing of Generalized Newtonian Fluids in Counter-rotating and Tangential TSE and Die Combination
  11. Simulation of Heat Transfer in Laser Transmission Welding
  12. Influence of Power Law and Isothermal Simplification on the Accuracy in Single Screw Extrusion
  13. Melt Intercalation in Montmorillonite/Polystyrene Nanocomposites
  14. Experimental Investigation of the Effect of the Bubble Cone on the Cooling Jets used in the Blown Film Manufacturing Process
  15. Molding of Thin Sheets Using Impact Micro-injection Molding
  16. Rapid communications
  17. Ultrasonic Vibration Hot Embossing
  18. PPS news
  19. PPS news
  20. Seikei-kakou abstracts
  21. Seikei-kakou abstracts
https://doi.org/10.1515/ipp-2005-0062

Articles in the same Issue

  1. Contents
  2. Regular Contributed Articles
  3. An Improvement on Design of Sheet Extrusion Dies
  4. Organic-Inorganic Hybrid Material Synthesis by on Line Coupling Twin Screw Extruder with a Microwave Oven
  5. Water Penetration Stability in Water Assisted Injection Molded Symmetric Ribs
  6. A New Plasticating Model for Amorphous and Semi-crystalline Polymers in Single Screw Extruders
  7. Simultaneous Biaxial Stretching of Polypropylene Resins of Varying Tacticity
  8. Optimization of a Flat Die Including Elongational Viscosity Effects
  9. Experimental Study on Factors Influencing Throughput Rate and Process of Polymer-Mineral Filler Mixing in a Twin Screw Extruder
  10. 3D Finite Element Simulation of Processing of Generalized Newtonian Fluids in Counter-rotating and Tangential TSE and Die Combination
  11. Simulation of Heat Transfer in Laser Transmission Welding
  12. Influence of Power Law and Isothermal Simplification on the Accuracy in Single Screw Extrusion
  13. Melt Intercalation in Montmorillonite/Polystyrene Nanocomposites
  14. Experimental Investigation of the Effect of the Bubble Cone on the Cooling Jets used in the Blown Film Manufacturing Process
  15. Molding of Thin Sheets Using Impact Micro-injection Molding
  16. Rapid communications
  17. Ultrasonic Vibration Hot Embossing
  18. PPS news
  19. PPS news
  20. Seikei-kakou abstracts
  21. Seikei-kakou abstracts
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