A New Plasticating Model for Amorphous and Semi-crystalline Polymers in Single Screw Extruders
-
G. Zitzenbacher
Abstract
Polymeric thermoplastic materials can be subdivided in amorphous and semi-crystalline ones. In contrast to semi-crystalline polymers amorphous thermoplastic materials have no defined phase transition and hence no melt enthalpy. The glass transition region describes the change of the material behaviour from the state of a rubber like to an under-cooled fluid (glassy state). Setting the melt enthalpy in the Stefan-Neumann problem zero gives no valid results for the solid bed profile. Thus this condition is unsuitable for describing the plasticating process of amorphous polymers.
In this paper a new model for the plastication of amorphous and semi-crystalline polymers in single screw extruders is presented. Therefore a new calculation method for the determination of the moving velocity between the glassy solid bed and the softened film region on the barrel surface is developed. The whole enthalpy to heat up the polymer on a critical flow temperature in the screw channel is considered.
-
YYou will find the article and additional material by entering the document number IIPP0089 on our website at www.polymer-process.com
References
1 Maddock, B. H.: SPE-ANTEC Tech. Papers 15, p. 383 (1959)10.1002/phbl.19590150813Suche in Google Scholar
2 Tadmor, Z.: Poly. Eng. Sci. 6, p 185 (1966)10.1002/pen.760060303Suche in Google Scholar
3 Tadmor, Z., Duvdevani, I. J., Klein, I.: Poly. Eng. Sci. 7, p. 198 (1967)10.1002/pen.760070313Suche in Google Scholar
4 Tadmor, Z., Klein, I.: Engineering Principles of Plasticating Extrusion. Van Nostrand Reinhold, New York (1970)Suche in Google Scholar
5 Donovan, R. C.: Poly. Eng. Sci. 11, p. 247 (1971)10.1002/pen.760110313Suche in Google Scholar
6 Kacir, L., Tadmor, Z.: Poly. Eng. Sci. 12, p. 387 (1972)10.1002/pen.760120511Suche in Google Scholar
7 Lindt, J. T.: Poly. Eng. Sci. 16, p. 284 (1976)10.1002/pen.760160411Suche in Google Scholar
8 Fenner, R. T.: Principles of Polymer Processing. MacMillan, London (1979)10.1007/978-1-349-16234-5Suche in Google Scholar
9 Cox, A. P. D., Fenner, R. T.: Poly. Eng. Sci. 20, p. 562 (1980)10.1002/pen.760200809Suche in Google Scholar
10 Mount, E. M., Watson, J. G., Chung, C. I.: Poly. Eng. Sci. 22, p. 729 (1982)10.1002/pen.760221202Suche in Google Scholar
11 Kuo, S. H., Chung, C. I.: Poly. Eng. Sci. 7, p. 448 (1989)10.1002/pen.760290704Suche in Google Scholar
12 Rauwendaal, C.: Poly. Eng. Sci. 22, p. 729 (1982)10.1002/pen.760221202Suche in Google Scholar
13 Fukase, H. et al.: Poly. Eng. Sci. 22, p. 578 (1982)10.1002/pen.760220910Suche in Google Scholar
14 Elbirli, B. et al.: Poly. Eng. Sci. 24, p. 988 (1984)10.1002/pen.760241208Suche in Google Scholar
15 Lindt, J. T., Elbirli, B.: Poly. Eng. Sci. 25, p. 412 (1985)10.1002/pen.760250706Suche in Google Scholar
16 Pearson, J. R. A.: Mechanics of Polymer Processing. Elsevier, London New York (1985)Suche in Google Scholar
17 Potente, H.: Verfahrenstechnische Auslegung von Plastifizier- und Schmelzeaggregaten. Handbook for “1. Kunststofftechnischen Seminar”. University Paderborn (1986)Suche in Google Scholar
18 Potente, H.: Int. Poly. Process. 6, p. 297 (1991)10.3139/217.910297Suche in Google Scholar
19 Schöppner, V.: Thesis, University Paderborn (1995)Suche in Google Scholar
20 Binder, W.: Thesis, University of Leoben (1999)Suche in Google Scholar
21 Han, C. D., Lee, K. Y., Wheeler, N. C.: Poly. Eng. Sci. 36, p. 1360 (1996)10.1002/pen.10531Suche in Google Scholar
22 Sundstrom, D. W., Lo, J. R.: Poly. Eng. Sci. 18, p. 422 (1978)10.1002/pen.760180515Suche in Google Scholar
23 Tadmor, Z., Gogos, C. G.: Principles of Polymer Processing. John Wiley & Sons, New York (1979)Suche in Google Scholar
© 2005 Hanser Publishers, Munich
Artikel in diesem Heft
- Contents
- Regular Contributed Articles
- An Improvement on Design of Sheet Extrusion Dies
- Organic-Inorganic Hybrid Material Synthesis by on Line Coupling Twin Screw Extruder with a Microwave Oven
- Water Penetration Stability in Water Assisted Injection Molded Symmetric Ribs
- A New Plasticating Model for Amorphous and Semi-crystalline Polymers in Single Screw Extruders
- Simultaneous Biaxial Stretching of Polypropylene Resins of Varying Tacticity
- Optimization of a Flat Die Including Elongational Viscosity Effects
- Experimental Study on Factors Influencing Throughput Rate and Process of Polymer-Mineral Filler Mixing in a Twin Screw Extruder
- 3D Finite Element Simulation of Processing of Generalized Newtonian Fluids in Counter-rotating and Tangential TSE and Die Combination
- Simulation of Heat Transfer in Laser Transmission Welding
- Influence of Power Law and Isothermal Simplification on the Accuracy in Single Screw Extrusion
- Melt Intercalation in Montmorillonite/Polystyrene Nanocomposites
- Experimental Investigation of the Effect of the Bubble Cone on the Cooling Jets used in the Blown Film Manufacturing Process
- Molding of Thin Sheets Using Impact Micro-injection Molding
- Rapid communications
- Ultrasonic Vibration Hot Embossing
- PPS news
- PPS news
- Seikei-kakou abstracts
- Seikei-kakou abstracts
Artikel in diesem Heft
- Contents
- Regular Contributed Articles
- An Improvement on Design of Sheet Extrusion Dies
- Organic-Inorganic Hybrid Material Synthesis by on Line Coupling Twin Screw Extruder with a Microwave Oven
- Water Penetration Stability in Water Assisted Injection Molded Symmetric Ribs
- A New Plasticating Model for Amorphous and Semi-crystalline Polymers in Single Screw Extruders
- Simultaneous Biaxial Stretching of Polypropylene Resins of Varying Tacticity
- Optimization of a Flat Die Including Elongational Viscosity Effects
- Experimental Study on Factors Influencing Throughput Rate and Process of Polymer-Mineral Filler Mixing in a Twin Screw Extruder
- 3D Finite Element Simulation of Processing of Generalized Newtonian Fluids in Counter-rotating and Tangential TSE and Die Combination
- Simulation of Heat Transfer in Laser Transmission Welding
- Influence of Power Law and Isothermal Simplification on the Accuracy in Single Screw Extrusion
- Melt Intercalation in Montmorillonite/Polystyrene Nanocomposites
- Experimental Investigation of the Effect of the Bubble Cone on the Cooling Jets used in the Blown Film Manufacturing Process
- Molding of Thin Sheets Using Impact Micro-injection Molding
- Rapid communications
- Ultrasonic Vibration Hot Embossing
- PPS news
- PPS news
- Seikei-kakou abstracts
- Seikei-kakou abstracts